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Re:Electronic Structure of LK-99 by bluecoconut on Tuesday August 01, 2023 @09:31PM (#36965812)
I got my PhD studying band structure of high-tc superconductors (experimentalist, ARPES). These Cu d-d interactions right at the fermi energy give me huge hope. Feels very familiar to other superconductors (re: all the cuprates). (Note: I specifically worked in a lab that was measuring a lot of the d-wave character / gap-energies of various superconductors)

All in all, I'm now much more bullish on LK-99 being real superconductivity after seeing multiple different labs compute similar band structures. The video of multiple directions of magnet showing some levitation also inspires a lot of hope.

Re:Electronic Structure of LK-99 by SamPatt on Tuesday August 01, 2023 @09:40PM (#36965880)
Thanks for your input.

What would you need to see to say "I am 100% convinced this is / isn't real"?

And how long would you expect it will be before that occurs?

Re:Electronic Structure of LK-99 by RandomBK on Tuesday August 01, 2023 @09:44PM (#36965917)
I'm not a scientist, but personally I expect I'll have two "wow, this is really happening" moments:

(1) When there's peer-reviewed replication from a group of reputable labs.

(2) When I see the classic superconductor-on-magnetic-track demo, but without liquid nitrogen.

Re:Electronic Structure of LK-99 by fragmede on Tuesday August 01, 2023 @11:05PM (#36966499)
Re:Electronic Structure of LK-99 by DeIonizedPlasma on Wednesday August 02, 2023 @10:58AM (#36971788)
The nitter video could literally be a piece of iron, even a ferromagnetic object will turn like that under the presence of a magnet. It certainly isn't proof that the thing they have there is NOT a superconductor, but you can't use that video as evidence of anything.
Re:Electronic Structure of LK-99 by cthalupa on Wednesday August 02, 2023 @11:40AM (#36972399)
Iron and ferromagnetic objects would not react that way. The key to this showing diamagnetism is the fact that the same points are repelled in the same way regardless of the orientation of the magnet. If it was ferromagnetic, you could have it stand up on it's tip in one polarity and stand up on another portion of the object in the other polarity, but you couldn't make it stand up on it's tip both times.
Re:Electronic Structure of LK-99 by bluecoconut on Tuesday August 01, 2023 @10:16PM (#36966151)
I'd probably approach 90% confidence with ~2-3 different measurements from different labs showing similar stories. Select from the grab bag of possible experiments that could all collaborate and provide consistency in their stories: specifically things like measuring the critical current, critical magnetic field, high quality electrical resistance in various ways (lots of transport), STM measurements of gaps, ARPES measurements of gaps, XRD showing crystal structures are what we expect that matches the DFT, a study on the domain sizes/effects (since this is relying on a substition at the right place, necessarily I suspect that there will be domain effects / "doping" style things... so how those play out in terms of purity and quality of results will be interesting). There will be a lot to study and characterize, and every extra measurement that is consistent rapidly increases that confidence. I'd say I'd get to "100%" (as close as someone could be) after ~10-20 papers across many different labs and measurements. I'd hope we'd get there in ~3-6 months.

What I'm actually even slightly more excited about is "what comes next" -- not the market part, but the "fast follow science". For instance, in the few years after LCBO and LSCO were found (TC~30K) we quickly found YBCO and BSCCO (Tc~130K). I would expect that we'll find a whole class of these materials with substitution tricks that possibly work, and there will be a whole slew of options for "going to market" with the technology. The door this opens is what is more exciting than the specifics of LK-99 itself in my opinion.

Estimating times, after the fast follow science (0.5-2 years optimistically?) we will hopefully have the actual "we're all convinced this is real, and the technology can start to be applied in real devices". Specifically, after everyone is pretty clear on a lot of the material properties and ways to reproducibly make high-quality crystals, so consistency is clear on measurements... then begins the cycles on how to manufacture high enough quality material at scale that it can actually be applied. (specifically, these materials (assuming they're like YCBO/BSCCO) are superconducting crystals that have grains, alignment issues, are physically brittle, have homogeneity issues, etc.) While each solvable, these are all real engineering and material challenges that increase cost to manufacture, and all of this will probably take time before we suddenly get wide-scale products that use this (this is all assuming it's real, haha, there's still plenty of reason to be skeptical).

Re:Electronic Structure of LK-99 by xorbax on Tuesday August 01, 2023 @11:03PM (#36966488)
I think a funded and forward-thinking lab with enough postdocs would be trying to grind out a version replacing lead with gold, per the DFT calculations

Few will remember the million replications, but whoever describes a novel version - even if it's no better - will find themselves on equal footing for helping to understand what's happening

Re:Electronic Structure of LK-99 by SamPatt on Tuesday August 01, 2023 @11:23PM (#36966604)
Thanks for your thoughts!
Re:Electronic Structure of LK-99 by JKCalhoun on Tuesday August 01, 2023 @10:24PM (#36966219)
Waiting for Applied Science (the YouTuber) to make some in his lab.
Re:Electronic Structure of LK-99 by eco on Tuesday August 01, 2023 @10:31PM (#36966276)
I think he might be working on it. On Twitter he teased a homemade device for making very fine powder for, say, superconductors.

Here's his video of making YBCO for anyone that hasn't seen it: https://www.youtube.com/watch?v=sLFaa6RPJIU

Re:Electronic Structure of LK-99 by anigbrowl on Tuesday August 01, 2023 @09:34PM (#36965841)
So happy to hear this. I've been hoping for some sort of breakthrough ever since I first encountered footage of magnets falling through Cu tubes at an extremely leisurely pace.
Re:Electronic Structure of LK-99 by redrobein on Tuesday August 01, 2023 @09:44PM (#36965926)
Any conductive material for the tube will have a similar effect. It isn't specific to copper.

The moving magnet induces a current in the tube which in turn creates the magnetic field that interacts with the magnet.

Re:Electronic Structure of LK-99 by soligern on Tuesday August 01, 2023 @09:46PM (#36965942)
Eddy currents
Re:Electronic Structure of LK-99 by sjcsjc on Wednesday August 02, 2023 @10:32AM (#36971442)
“Eddies,” said Ford, “in the space-time continuum.”

“Ah,” nodded Arthur, “is he? Is he?”

Re:Electronic Structure of LK-99 by TheSpiceIsLife on Wednesday August 02, 2023 @02:31AM (#36967685)
Not any conductive material, obviously won’t work won’t work, nor magnetic steel / stainless steel alloys.
Re:Electronic Structure of LK-99 by TheSpiceIsLife on Wednesday August 02, 2023 @04:28AM (#36968424)
I meant: obviously iron won’t work.
Re:Electronic Structure of LK-99 by fodkodrasz on Wednesday August 02, 2023 @10:16AM (#36971221)
Could you elaborate why iron pipes wouldn't work?
Re:Electronic Structure of LK-99 by andrewflnr on Wednesday August 02, 2023 @10:51AM (#36971700)
The magnet would try to stick to the side of the pipe through "normal" magnetism.
Re:Electronic Structure of LK-99 by fodkodrasz on Thursday August 03, 2023 @03:35PM (#36990663)
I see, thanks!
Re:Electronic Structure of LK-99 by dekhn on Tuesday August 01, 2023 @09:54PM (#36965995)
If you haven't seen it, levitating frogs are also quite wonderful. https://slate.com/business/2014/05/nobel-prize-in-physics-an...

An Ig Nobel AND a Nobel. That's quite the achievement.

Re:Electronic Structure of LK-99 by cpeterso on Tuesday August 01, 2023 @11:15PM (#36966556)
That article was a great story! Thanks for sharing.
Re:Electronic Structure of LK-99 by jpmattia on Tuesday August 01, 2023 @10:13PM (#36966126)
> These Cu d-d interactions right at the fermi energy give me huge hope. Feels very familiar to other superconductors (re: all the cuprates).

As someone who is versed in semiconductor band structures but not superconductor band structures: What is it about Cu d-d interactions that causes the superconductivity?

Degenerate energies in semiconductors don't give rise to electron pairing, so I'm a bit out to sea with the proposed mechanism here.

Re:Electronic Structure of LK-99 by bluecoconut on Tuesday August 01, 2023 @10:33PM (#36966284)
To be honest, this is a hunch thing more than a I can teach and explain it thing. To me it's just "a lot of the same stories" that are told about cuprates, and less of a "I can explain the mechanism".

Roughly, one of the "properties" that shows up with these materials is that the 3d orbitals of coper atoms are involved in forming the bands near the fermi level. Couple that with the fun story of Cu electron configuration being [Ar] 3d^10 4s^1, which suggests that spin-effects are "at play" with these electrons near their filling levels. Combine that with the spin-character properties of cuprate paring (eg. s-wave vs. d-wave superconductors, (d-wave for BSCCO for instance)). All together it lends itself to a nice spin-orbit coupled band "setup" at the fermi energy that I have a hunch somehow backs the underlying mechanism of these d-wave superconductors. Fully admit, there's some leaps there in the raw logic -- if I could fully explain it I probably would still be in the field, haha.

I'll note: I've been out of the field for ~8 years, but a quick google search led to some more recent papers [1][2] working through plausible explanations based on some of these copper d orbital shenanigans.

[1] https://www.scirp.org/journal/paperinformation.aspx?paperid=... [2] https://arxiv.org/abs/2105.11664 (d-p, but includes the Cu d-orbital and also specifically states "We also show that the effect of the nearest-neighbor d-d Coulomb interaction Vdd is actually quite important for the stability of superconductivity and phase competition.")

Re:Electronic Structure of LK-99 by jpmattia on Tuesday August 01, 2023 @10:48PM (#36966395)
> To me it's just "a lot of the same stories" that are told about cuprates, and less of a "I can explain the mechanism".

Fair enough, and thanks for the readout. I realized after posting I essentially demanded an explanation as to why the cuprates are high-Tc, which is probably it's own Nobel prize.

Re:Electronic Structure of LK-99 by mensetmanusman on Wednesday August 02, 2023 @09:15AM (#36970450)
The internet is one of those places where if you are wrong, someone might well write a Nobel-worthy response just to win the argument.

https://www.wired.com/story/how-an-anonymous-4chan-post-help...

Re:Electronic Structure of LK-99 by cynusx on Wednesday August 02, 2023 @01:48PM (#36974293)
Nice one, reading that post makes me wonder if the proof could be furthered when considering parallels from compression algorithms.

Compression algorithms detect recurring blocks and remove them with a special symbol and I think the shortest path would be uncompressable with compression algorithms.

Re:Electronic Structure of LK-99 by loxias on Tuesday August 01, 2023 @10:51PM (#36966418)
> To be honest, this is a hunch thing more than a I can teach and explain it thing...

Chiming in, not just you. :) I very briefly studied materials science a few decades ago and I'm 0% surprised that a potential breakthrough involves, of course, cuprates.

Re:Electronic Structure of LK-99 by m3kw9 on Tuesday August 01, 2023 @10:55PM (#36966442)
Very cool explanation, I didn’t understand a word you said
Re:Electronic Structure of LK-99 by faraggi on Wednesday August 02, 2023 @01:09AM (#36967170)
Any plans on going back to your field with these discoveries?
Re:Electronic Structure of LK-99 by overnight5349 on Wednesday August 02, 2023 @06:23PM (#36978580)
I really wish I'd went into physics in school. This all sounds deeply fascinating, but I just barely understand the top level of what you're explaining.
Re:Electronic Structure of LK-99 by Baeocystin on Tuesday August 01, 2023 @10:40PM (#36966331)
Serious question- I saw the original video, where once they stopped waving the magnet around and held it near the sheet of LK-99, it looked to me like it stayed at a specific standoff distance, with no decay.

Assuming no videographic trickery, what else could it be, other than the Meissner effect?

Re:Electronic Structure of LK-99 by oceanghost on Tuesday August 01, 2023 @11:22PM (#36966596)
A diamagnetic material.

"In simple terms, diamagnetic materials are substances that are usually repelled by a magnetic field. Electrons in an atom revolve around the nucleus, and thus possess orbital angular momentum. The resultant magnetic momentum in an atom of the diamagnetic material is zero."

Re:Electronic Structure of LK-99 by Baeocystin on Tuesday August 01, 2023 @11:33PM (#36966662)
Am I correct in my understanding that being capable of self-levitation would be an unusually strong example of the diamagnetic effect?
Re:Electronic Structure of LK-99 by lucubratory on Wednesday August 02, 2023 @12:16AM (#36966889)
Yes, if this material is diamagnetic without being a superconductor it is by far the strongest such material we've ever found. 15x stronger than pyrolitic graphite.
Re:Electronic Structure of LK-99 by tavavex on Wednesday August 02, 2023 @12:21AM (#36966916)
From what I heard, it would. This kind of diamagnetism would be strong enough to be potentially interesting in other applications and research, if it turns out not to be a superconductor.
Re:Electronic Structure of LK-99 by nine_k on Wednesday August 02, 2023 @01:49AM (#36967387)
Would still be useful for maglev, I assume?
Re:Electronic Structure of LK-99 by ajnin on Wednesday August 02, 2023 @06:54AM (#36969220)
Not over a single dipole magnet. The "shape" of the field wouldn't make it stable, you'd need to add other magnets or a piece of string to stabilise. As I understand stable levitation over a dipole magnet is indicative of flux pinning which is a property exclusive to type II superconductors.
Re:Electronic Structure of LK-99 by whatshisface on Wednesday August 02, 2023 @03:21AM (#36967997)
I think ChatGPT wrote that because it is nonsense.
Re:Electronic Structure of LK-99 by oceanghost on Wednesday August 02, 2023 @07:44PM (#36979451)
It came from here... correct or incorrect.

https://byjus.com/jee/diamagnetic-materials/

Re:Electronic Structure of LK-99 by oxfordmale on Wednesday August 02, 2023 @05:21AM (#36968723)
The Meissner effect requires a temperature transition in the diamagnetic behaviour. As you increase the temperature, you would expect a sharp drop with the material falling back on the magnet, and then levitating again once the temperature drops.
Re:Electronic Structure of LK-99 by jacquesm on Wednesday August 02, 2023 @10:14AM (#36971188)
Yes, if you know the upper boundary for the temperature up to which the material stays superconducting. But that's a bit of a problem: this material is claimed to be superconducting to very high temperatures. It just could be that it isn't all that easy to reach a temperature where this stuff stops being superconducting. In fact I see no particular reason in physics why it would have to stay below the temperature at which the material disintegrates. So maybe that part of the effects is simply a reflection of the fact that these superconductors that work well below zero are in fact exactly there because they require a cold environment and once you find one that doesn't that whole aspect goes away, it could stay diamagnetic all the way up to its melting point.
Re:Electronic Structure of LK-99 by jurgenaut23 on Wednesday August 02, 2023 @01:56AM (#36967439)
Beyond the raw scientific excitement, can you explain how this would affect mankind (positively and, of course, perhaps negatively)?
Re:Electronic Structure of LK-99 by xvector on Wednesday August 02, 2023 @02:07AM (#36967526)
Re:Electronic Structure of LK-99 by itsoktocry on Wednesday August 02, 2023 @08:07AM (#36969723)
"1970: Superconducting trains to go from New York to LA in 20 minutes!"

50+ years later the US has how many high speed trains, of any kind?

Re:Electronic Structure of LK-99 by kuschku on Wednesday August 02, 2023 @09:39AM (#36970730)
Well, Shanghai has some, Japan is building some, and if this discovery is real, Germany might as well revive their Transrapid project (which built the shanghai one).
Re:Electronic Structure of LK-99 by marcosdumay on Wednesday August 02, 2023 @11:50AM (#36972544)
I guess that's partially missing the point. The main benefit of a superconducting maglev is that it's cheaper to build than a on-rails high-speed train. Specially on problematic terrain (what I understand includes every possible East/West route on the US).
Re:Electronic Structure of LK-99 by u320 on Wednesday August 02, 2023 @11:53AM (#36972596)
Why would it be cheaper? The actual rails is a pretty small part of constructing high speed rail, isn't it? Especially on problematic terrain.
Re:Electronic Structure of LK-99 by xvector on Wednesday August 02, 2023 @02:29PM (#36974913)
Energy usage and passenger bandwidth could be a reason
Re:Electronic Structure of LK-99 by marcosdumay on Wednesday August 02, 2023 @02:43PM (#36975133)
Because maglev trains can make stronger curves and climb steeper hills.
Re:Electronic Structure of LK-99 by irthomasthomas on Wednesday August 02, 2023 @03:08AM (#36967905)
I think we're being trolled. Or trawled. Not sure which, yet. But the mention of Salvatore Cezar Pais in the patent should be enough to put this to bed for serious folks.

https://news.ycombinator.com/item?id=36967333

In case you aren't familiar with the man's work, here are some highlights of his discoveries over the last decade:

Conditional possibility of spacecraft propulsion at superluminal speeds

High frequency gravitational waves-induced propulsion

Piezoelectricity-induced room temperature superconductor

Craft using an inertial mass reduction device

On the Existence of the Superforce–the possible fundamental Force of Unification

https://scholar.google.com/scholar?hl=en&as_sdt=7%2C39&q=Sal...

I can't wait for my cheap antigrav FTL iron man suit to arrive next year.

Re:Electronic Structure of LK-99 by dcgudeman on Wednesday August 02, 2023 @03:55AM (#36968198)
I wonder why more people aren't talking about this
Re:Electronic Structure of LK-99 by nwoli on Wednesday August 02, 2023 @03:59AM (#36968220)
A lot of wishful thinking around these corners
Re:Electronic Structure of LK-99 by yreg on Wednesday August 02, 2023 @07:24AM (#36969398)
Because it's irrelevant. Patents are supposed to mention other prior patents. Whether those are rubbish or not.
Re:Electronic Structure of LK-99 by nwoli on Wednesday August 02, 2023 @03:58AM (#36968217)
Would be pretty funny if this guy actually published a breakthrough that worked all of a sudden
Re:Electronic Structure of LK-99 by varjag on Wednesday August 02, 2023 @04:11AM (#36968301)
I wouldn't read too much into this. You have to address prior art when it is found in patent examination as a part of application process, no matter how bogus it is.
Re:Electronic Structure of LK-99 by martinclayton on Wednesday August 02, 2023 @04:11AM (#36968308)
It looks like the citation of the Pais patent was added by the examiner, rather than by the applicants. Does that make any difference in your view?
Re:Electronic Structure of LK-99 by dasudasu on Wednesday August 02, 2023 @07:58AM (#36969634)
Cited patents are added by the examiner. Source: I have several parents.
Re:Electronic Structure of LK-99 by kitd on Wednesday August 02, 2023 @08:07AM (#36969730)
Source: I have several parents

Ahem :)

Though it may depend on what the patents are for!

Re:Electronic Structure of LK-99 by jjk166 on Wednesday August 02, 2023 @10:15AM (#36971202)
If something is prior art, you need to include it, regardless of the source. Even fictional descriptions of technologies can be prior art. For example, Samsung used 2001 A Space Odyssey as prior art to invalidate Apple's patent on ipad-like tablets.
Re:Electronic Structure of LK-99 by bl_valance on Wednesday August 02, 2023 @01:06PM (#36973666)
I thought the inclusion of Pais' patents was more along the lines of, here is a patent related to our work, rather than we sourced tech from it.
Re:Electronic Structure of LK-99 by weinzierl on Wednesday August 02, 2023 @03:53AM (#36968182)
This is probably a very stupid question, but why is simply measuring resistance not enough to conclusively prove that it is a superconductor. I mean, isn't zero resistance the defining property?
Re:Electronic Structure of LK-99 by OJFord on Wednesday August 02, 2023 @04:34AM (#36968468)
I think if it was actually zero it would be? The issue I think is impurity/defects in the manufactured samples, so there's non-superconducting bits in addition to the allegedly superconducting bits.
Re:Electronic Structure of LK-99 by vrotaru on Wednesday August 02, 2023 @04:06AM (#36968269)
Well, I guess, that are islands of superconductivity and normal conductivity in the same sample.

This gives a low resistance and diamagnetism which is used as proxy to real superconductivity.

I may be wrong though.

Re:Electronic Structure of LK-99 by rvnx on Wednesday August 02, 2023 @05:15AM (#36968693)
Just guessing: I would say not enough because the sample is extremely small and there is chance that the electrons jump from each sides of the probes, skipping the sample ? (like a short-circuit) + the fact that the probes themselves are not superconductor, so there is a natural accepted tolerance in the measures (claimed to be due to the probes)
Re:Electronic Structure of LK-99 by mianos on Wednesday August 02, 2023 @07:49AM (#36969567)
If the video is to be believed, the samples shown are huge compared to a, trivial to make, pulled or cut platinum wire probe. You could just put it on a plate in an SPM and measure it.

So many questions. I assume this is all possible but they are focussing on one thing at a time to duplicate the results, if possible.

Re:Electronic Structure of LK-99 by baq on Wednesday August 02, 2023 @07:22AM (#36969386)
Measuring zero resistance turns out to be quite difficult because your measuring apparatus tends to have some resistance in itself.

Perhaps heating it up while it levitates would be a better idea. Put the magnet in an oven together with the sample and bake?

Re:Electronic Structure of LK-99 by marcosdumay on Wednesday August 02, 2023 @11:42AM (#36972433)
Magnets have an annoying tendency to stop working when they are heated.

And it's ridiculous that I'm saying that on the context of testing a superconductor. But well, here we are.

Re:Electronic Structure of LK-99 by archontes on Wednesday August 02, 2023 @01:27PM (#36973969)
You could always use an electromagnet.
Re:Electronic Structure of LK-99 by jacquesm on Wednesday August 02, 2023 @01:28PM (#36973990)
A superconducting one?
Re:Electronic Structure of LK-99 by archontes on Thursday August 03, 2023 @12:51PM (#36988358)
No, we're talking about verifying superconductivity using a traditional magnet at an elevated temperature.
Re:Electronic Structure of LK-99 by marcosdumay on Wednesday August 02, 2023 @02:47PM (#36975196)
Yes, but that's quite a bit of extra complication on an experiment of some material that was announced into the world last Friday.

I do expect people to fully characterize it eventually.

Re:Electronic Structure of LK-99 by jacquesm on Wednesday August 02, 2023 @01:28PM (#36973985)
Indeed, that statement would have been really funny just a few weeks ago. Now you're going to have to wonder whether the magnet or the superconductor will fail first.

Neo magnet fabrication is fascinating by the way, the somewhat magnetized blanks are not all that impressive from a magnetic field strength point of view, but then you zap them with a strong enough field and they then suddenly are the best thing since sliced bread.

This technique was first developed for 'regular' ceramic magnets.

https://idealmagnetsolutions.com/knowledge-base/how-neodymiu...

An uncoated magnet will oxidize very fast, so you always have to ensure that the coating on any magnets you use is perfect or the magnet will surely fail.

Re:Electronic Structure of LK-99 by mensetmanusman on Wednesday August 02, 2023 @09:23AM (#36970554)
Because materials interfaces create weird effects.

You would use metals as your leads and create Josephson-junctions-like interfaces.

Basically the abrupt change in electron mobility across materials can cause knock on effects that dominate what you are trying to measure.

Interfacial engineering is one term in materials science that implements best practices for dealing with such challenges.

Re:Electronic Structure of LK-99 by MrBuddyCasino on Wednesday August 02, 2023 @04:37AM (#36968486)
This is probably the most stupid question to ask, but while were are still trying to confirm superconductivity instead of understanding its precise mechanism of operation, why the focus on levitation on band structure to confirm the news instead of just "yep this chunk has actually zero Ohms"?
Re:Electronic Structure of LK-99 by pjc50 on Wednesday August 02, 2023 @04:41AM (#36968505)
"zero ohms" is very tricky to measure because of contact resistance: your probes aren't superconducting, and the thin contact surface between your probes and the metal itself isn't superconducting either.

Whereas the Meissner effect is unique to superconductors. It just has to be distinguished from diamagnetism, and there are materials which are strongly diamagnetic but not superconductors.

Re:Electronic Structure of LK-99 by cyberax on Wednesday August 02, 2023 @12:01PM (#36972709)
Build a loop out of a superconductor, induce a current in it, and then measure the resulting magnetic field after a couple of minutes.

If the field is still there, then you have a superconductor.

Re:Electronic Structure of LK-99 by jacquesm on Wednesday August 02, 2023 @01:38PM (#36974158)
Because the levitation thing works with tiny fragments too whereas the 'zero Ohms' measurement only works when you have enough of it to form a long enough wire of it that you could tell the difference between 0 and 0.000001. Measuring very small resistances is usually done by letting a known current run through them and then to measure the voltage across the sample using known resistance leads. For a superconductor that has a tiny available sample which is already conductive even if it is not superconducting is fraught with error and may well give you the wrong answer due to a tiny measuring error.

But the Meisner effect is a unique signature of a diamagnetic material and will provide you some evidence even if the sample is tiny. So I understand why they have not yet resorted to other measurements, if there is no Meisner effect you don't need to continue with the hard work of trying to make a wire (which may well be a serious challenge for this stuff, the yield will have to come up significantly before that's a real possibility).