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Re:How Plastics Are Poisoning Us by Retric on Wednesday June 28, 2023 @07:46AM (#36505074)
Teflon Aka Polytetrafluoroethylene cookware represents a health hazard. The stuff contains a great deal of Florine and breaks down at 300C, but that’s not purely binary instead it becomes increasingly unstable as your approach the temperature. Further no manufacturing process is perfect, I wouldn’t therefore assume eating significant quantities would be safe.

That said, it’s generally used as a coating rather than a structural element so there’s less of it in the environment.

Re:How Plastics Are Poisoning Us by taneq on Wednesday June 28, 2023 @08:38AM (#36505505)
Does it contain Fluorine (a dangerous halogen gas) or does it contain Fluoride (the ion of that gas, commonly added to toothpaste and drinking water).
Re:How Plastics Are Poisoning Us by deelowe on Wednesday June 28, 2023 @08:42AM (#36505556)
Flourine...
Re:How Plastics Are Poisoning Us by oasisbob on Wednesday June 28, 2023 @09:30AM (#36506183)
"Fluorine" is also the terminology used for covalently bonded Fl moieties, not just difluorine, the gas.

Fluoride is the ion, but if you want to get pedantic, you're not adding the ion to toothpaste and drinking water - you're adding another fluorine compound which is dissociating in solution.

Ie, when you salt your food, you're not tossing in Cl- ions directly.

Re:How Plastics Are Poisoning Us by jansan on Wednesday June 28, 2023 @08:34AM (#36505464)
Is "Florine" the same as "Flourine", and isn't that what they give children so they get healtheir teeth? I am a bit confused here to be honest.
Re:How Plastics Are Poisoning Us by iso1631 on Wednesday June 28, 2023 @08:35AM (#36505485)
You're thinking of fluoride
Re:How Plastics Are Poisoning Us by oezi on Wednesday June 28, 2023 @09:02AM (#36505794)
I understand that Teflon might be a hazard in pans but feel like it reduces the amount of burned food in contrast to steel/iron pans so much for me that I hope it is a net gain.

(sorry in advance for all who want to suggest iron skillets. I can't make them work in daily use.)

Re:How Plastics Are Poisoning Us by grimgoldgo on Wednesday June 28, 2023 @09:42AM (#36506329)
If you are regularly burning food in steel or iron pans, maybe it's time to understand why? I cook in exclusively iron and steel cookware and I cannot remember the last time something got burned (excepting when I deliberately charred something.)
Re:How Plastics Are Poisoning Us by hirundo on Wednesday June 28, 2023 @12:23PM (#36508723)
Please don't take your skill in this for granted. It's a gift. I've been using cast iron pans sporadically for four decades, following all of the common advice, and failing magnificently every time. I still use one occasionally to put a crust on a steak ... and then use a small piece of chainmail[1] to defeat the klingons.

It's not that I don't believe you. It just doesn't work that way in my pan on my stove with my food at my skill level, at all. I gave up and buy nonstick pans and replace them every other year or so.

[1] https://www.amazon.com/dp/B0087UYR1S

Re:How Plastics Are Poisoning Us by abathur on Wednesday June 28, 2023 @01:14PM (#36509460)
I don't cook enough (and never steak) for you to assign me much weight, but FWIW I've had a (lighter, spun) cast iron skillet for 8ish years. I followed a seasoning procedure available online that involves (IIRC) 3 rounds of applying thin coats of flaxseed oil and leaving it in an oven at a fairly high temp.

This process went fine, but I always had to baby the pan (had to be very careful cleaning it with said chainmail, very careful with what/how I cooked in it) and had to re-do the initial seasoning several times when it got too troublesome.

This process would leave the pan at a dark brown, and for a while I blamed this on not removing rust well enough before seasoning or not babying it well enough for it to build up to a ~normal black coat.

At some point during the early pandemic I tired of this. I decided to do something similar on the stovetop where I could observe/iterate better. Apply a coat, wait for it to stop smoking, and repeat until it was black. (plus a few for good luck; I didn't keep track; this took maybe dozens of rounds?)

I've had a much better time since then. The most ~babying I've done is applying a few fresh coats if I don't use it for a while or water doesn't bead when I rinse it.

Re:How Plastics Are Poisoning Us by sgtnoodle on Wednesday June 28, 2023 @03:50PM (#36511665)
Yeah, when my cast iron skillet starts to act up I'll just lightly scrub it with dish soap and a brillo pad, dry it, then add a very light coating of oil and heat it up on the stove until it smokes. You want some ventilation of course. Then, it's restored to easy fried egg condition.
Re:How Plastics Are Poisoning Us by angelbar on Wednesday June 28, 2023 @08:53PM (#36514944)
No oven needed... only some ventilation in kitchen if you cant take it...
Re:How Plastics Are Poisoning Us by grimgoldgo on Thursday June 29, 2023 @10:29AM (#36520826)
Consider a different oil. Flax makes a very pretty but very brittle seasoning. Canola works great IME.
Re:How Plastics Are Poisoning Us by red-iron-pine on Wednesday June 28, 2023 @01:33PM (#36509757)
Same. it's an art form sometimes, and i've cooked the same dish and had it come out great... and then the next time get charred like a mofo.

I suspect it has to do with electric vs gas and being able to get and maintain a stable temp with gas. But that could just be a poor craftsman blaming his tools.

Re:How Plastics Are Poisoning Us by earthling8118 on Wednesday June 28, 2023 @02:32PM (#36510575)
I would probably give up on cooking if I had to buy a new set of pans every year. That sounds entirely ridiculous. It's seriously not some special gift to be able to cook on a carbon steel, stainless steel, or cast iron pan. I've even trained people who have never cooked before in a single cooking session. Were they perfect right away? Nope. But it isn't that difficult and learned quickly after a few solo attempts
Re:How Plastics Are Poisoning Us by hirundo on Wednesday June 28, 2023 @02:53PM (#36510857)
I cook 99 out of 100 of my meals, and 9 out of 10 meals I cook in a small counter-top air-fryer. The whole gadget costs less than a good pan. That 10th meal is probably eggs in a non-stick pan, so that pan lasts years longer now.

I bought a nice new range right before I discovered the air-fryer, and it now functions mostly as a device for holding up the air-fryer.

Re:How Plastics Are Poisoning Us by asoneth on Wednesday June 28, 2023 @02:59PM (#36510961)
I've taught people to juggle or even (barely) ride a unicycle after a lesson or two. That doesn't mean those aren't difficult skills to acquire.

Plus, many people who are learning do not have the privilege of an experienced teacher. Relying on instructions, videos, and trial & error takes more time and energy for most people. I agree with you that it's worth the effort though.

Re:How Plastics Are Poisoning Us by oezi on Wednesday June 28, 2023 @12:55PM (#36509188)
I guess that it is due to the heat source (ceran cook top) and being used to using too little oil (with a teflon pan I use less than a teaspoon in most cases).
Re:How Plastics Are Poisoning Us by asoneth on Wednesday June 28, 2023 @01:55PM (#36510095)
I have been learning how to season, cook with, and clean cast iron. As someone who did not grow up using it it’s definitely not intuitive. The other challenge is that I either have to lock it away or teach everyone else in the household how to care for it. At various points in my life I’ve had coatings ruined by roommates, partners, guests, and housekeepers who did things that seemed perfectly sensible like letting it soak in soapy water.

It's similar to how my partner has a stainless steel pan that I avoid using because I have not had the bandwidth to internalize the right ratio of heat, time, and oil to cook things on it without burning/sticking, whereas they have no issue with it. It's a good reminder not to take internalized skill for granted.

Re:How Plastics Are Poisoning Us by yulker on Wednesday June 28, 2023 @02:06PM (#36510256)
Soapy water won't break down the molecularly bonded fat and iron on your cast iron. If you mistake leftover grease for seasoning, then sure, soapy water will get rid of it.

The trick to not sticking on steel pan is just preheating it properly. A drop of water should dance on a properly heated steel pan and things won't stick. Just let it get hot enough.

Re:How Plastics Are Poisoning Us by asoneth on Wednesday June 28, 2023 @02:45PM (#36510742)
> Soapy water won't break down the molecularly bonded fat and iron on your cast iron.

In that case I'm not sure what the exact mechanism was. But I know that after others have used/cleaned a seemingly well-seasoned pan I've had to deal with chips, flakes, and/or rust and had to go back through the whole annoying seasoning process. And of course it's entirely possible that despite carefully following instructions that I've done the seasoning wrong -- chemistry is the only class I ever flunked.

> A drop of water should dance on a properly heated steel pan and things won't stick.

My partner made a similar recommendation. It sounds trivially easy but for whatever reason I have not managed to make it work. Given that cast iron (generally) works fine for me I've had minimal motivation to learn the idiosyncrasies of another material, though I would like to give it another shot at some point.

Re:How Plastics Are Poisoning Us by deanCommie on Friday June 30, 2023 @11:41AM (#36536981)
It's gaslighting by the cast iron/stainless steel crowd, pure and simple.

I've talked to multiple experienced and home chefs about this disconnect and they've admitted two things:

1) cooking on a screaming hot pan is possible of course. It's how all professional kitchens work. But it's way harder! You have to pay close attention & the timing for error is very small. Cooking at lower heat on Teflon lets you make more adjustments.

2) After doing everything perfectly, and seasoning perfectly, for the same heat you ABSOLUTELY still need more of some oil or butter on a cast iron or stainless steel then you would for an equivalent Teflon pan. This is non-negotiable.

Re:How Plastics Are Poisoning Us by xerox13ster on Thursday June 29, 2023 @02:45AM (#36517194)
you can season stainless steel just like you season cast iron, it just requires more coats to hold and will need to be repeated more often. I've seasoned my skillets and frying pans. I'd never bother with my sauce pans bc they get acidic stuff like vinegar for poached eggs, tomato sauce, or fruit, but they're steel anyway so I can just scrub them with wire wool.
Re:How Plastics Are Poisoning Us by rngname22 on Wednesday June 28, 2023 @10:14AM (#36506815)
This is a bit like saying asbestos may be a hazard in walls but I just can't seem to get the knack for not lighting my house on fire :(

I say that partially as a joke but also it does sort of sound a bit absurd, in the sense that your cooking techniques are just sort of wrong if you are repeatedly burning food to your non-non-stick pan. You need an oil or fat on your pan to provide a buffer or to bathe the food in liquid.

Re:How Plastics Are Poisoning Us by oezi on Wednesday June 28, 2023 @01:00PM (#36509274)
I guess this is the main reason. I am not used to use a lot of fat while preparing food.

Again this might be a balancing act of the negative effects of teflon consumption and consuming too much fat via oil.

Re:How Plastics Are Poisoning Us by deanCommie on Friday June 30, 2023 @11:45AM (#36537062)
You just perfectly illustrated why people keep disagreeing about this.

You can cook a lot of things on a "non stick" telfon pan without an oil or fat.

You can cook far fewer things on a "non stick" cast iron without an oil or fat.

But the cast iron crowd will gaslight the rest of us, and claim that we are just seasoning it wrong but otherwise it is indistinguishable and only superior.

It's like manual transmission.

Re:How Plastics Are Poisoning Us by xeromal on Wednesday June 28, 2023 @11:27AM (#36507886)
It becomes more of a fat hazard after this but if you use the proper amount of oil, you can make it impossible to burn food into your pan. lol.
Re:How Plastics Are Poisoning Us by oezi on Wednesday June 28, 2023 @01:02PM (#36509289)
Certainly true. So lets expand the hazard triangle to Fat VS Teflon VS Acrylamide.
Re:How Plastics Are Poisoning Us by assbuttbuttass on Wednesday June 28, 2023 @11:40AM (#36508090)
There are some great ceramic non-stick pans available these days.
Re:How Plastics Are Poisoning Us by oezi on Wednesday June 28, 2023 @01:03PM (#36509303)
Tried one and failed miserably.
Re:How Plastics Are Poisoning Us by deathanatos on Wednesday June 28, 2023 @03:28PM (#36511381)
… which are non-stick because they're coated.

Now, I do think some of them are coming coated in silicone-based coatings. The consensus I get asking "are these carcinogenic?" is "probably not?"

But the other problem is determining what a particular pan is coated with: I have not seen a single manufacturer label their pan with anything more informative than that it is coated in "magic science stuff".

Re:How Plastics Are Poisoning Us by SapporoChris on Wednesday June 28, 2023 @09:13AM (#36505945)
300 C is typically the highest setting on a stovetop. I never go above medium when using Teflon cookware. I've not used a cooking thermometer yet, but https://homebli.com/stove-top-temperature-knobs-what-the-num... gives a good general guide line under a section labelled Stove Top Numbers to Degrees.

Also, I only use 'plastic' utensils with the pan. The result, not a single scratch on the pan. The surface looks brand new, I've been using it over a year.

Re:How Plastics Are Poisoning Us by blueprint on Wednesday June 28, 2023 @09:48AM (#36506418)
i love eating melted threads of plastic from my utensils too. my favorite part is when my elderly mum gets a neurodegenerative disease after years of using scratched teflon pans

maybe consider bamboo or wood or yknow silicone instead lol what is so appealing about plastic utensils?

i wonder if you're trolling?

Re:How Plastics Are Poisoning Us by tomjakubowski on Wednesday June 28, 2023 @10:02AM (#36506627)
I would guess GP meant silicone tools, silicone being a kind of plastic.
Re:How Plastics Are Poisoning Us by blueprint on Wednesday June 28, 2023 @10:26AM (#36506988)
I realize thay, but IMO they should have been more specific then. 99.9% of people dont realize plastic utensils that arent designed specifically for high temperature heat resistance are, yknow, super unhealthy and ending up in their body

imagine if i had not included silicone. your counterargument only serves to try to justify op's ambiguity

but who am i kidding? this is HN. you probably only care about feeling superior ;)

Re:How Plastics Are Poisoning Us by hombre_fatal on Wednesday June 28, 2023 @10:50AM (#36507297)
So, they should have been more specific so you don’t get worked up and come in guns blazing with epic sarcasm and no charity. Let’s hope they learned their lesson.
Re:How Plastics Are Poisoning Us by blueprint on Wednesday June 28, 2023 @12:59PM (#36509258)
they should have been more specific because "just use plastic" is terrible advice. there are many types of plastic and most things called plastic utensils are not silicone. okay..? "just use bamboo" however is not easily capable of becoming terrible advice because there arent many types of bamboo utensils people cook with and all of them are safe unless adultered.

i didnt realize i was being so outlandish. hn is known for what i described. and yes i do hope some people learn to prioritize the actual result instead of wanting to beat others down with rhetorical skill. we're talking about affecting people's lives here, while representing to others that we have a clue.

Re:How Plastics Are Poisoning Us by SapporoChris on Wednesday June 28, 2023 @11:35AM (#36508002)
https://news.ycombinator.com/newsguidelines.html Please respond to the strongest plausible interpretation of what someone says, not a weaker one that's easier to criticize. Assume good faith.
Re:How Plastics Are Poisoning Us by blueprint on Wednesday June 28, 2023 @12:59PM (#36509254)
please do that with me then - I said what I said for a valid reason not elsewhere addresssed
Re:How Plastics Are Poisoning Us by FooBarBizBazz on Wednesday June 28, 2023 @10:11AM (#36506770)
I'd have thought that fluorine, like oxygen, is a strong oxidizer (fluorine being even stronger), and so fluorides, like oxides (e.g. rust) would be extremely stable, among the most stable compounds possible. Unless I'm forgetting the other side: Maybe the other half of the compound is not a strong enough reducer? It's a hydrocarbon though, it burns well in oxygen...

That said, even oxides do break down when heated. Like, that's what smelting is...

Hm...

Re:How Plastics Are Poisoning Us by Retric on Wednesday June 28, 2023 @12:05PM (#36508478)
Carbon Florine bonds are some of the strongest you will find. Carbon tetrafluoride CF4 is almost as safe as nitrogen at room temperature. Tetrafluoroethylene C2F4 is actually explosive on the other hand because of it’s carbon carbon bond, the stuff is happy to spit out the carbon and get CF4.

https://en.wikipedia.org/wiki/Tetrafluoroethylene

Re:How Plastics Are Poisoning Us by __alexs on Wednesday June 28, 2023 @12:38PM (#36508961)
Carbon tetrafluoride and Carbon tetrachloride are the two "carbon tets" you never want to mix up.
Re:How Plastics Are Poisoning Us by marcosdumay on Wednesday June 28, 2023 @12:20PM (#36508676)
> Maybe the other half of the compound is not a strong enough reducer?

It's about as strong as most of the molecules on your body.

But I don't think that fluoride moving around is the problem. Looks like the problem is exactly the stability, and some long foreign molecules installing themselves in your body.

Re:How Plastics Are Poisoning Us by jader201 on Wednesday June 28, 2023 @10:20AM (#36506904)
Are you saying, then, that this claim [1] is false?

It states that PTFE is safe, whereas PFOA — what Teflon used to contain — was the component that made Teflon unsafe.

[1] https://www.webmd.com/food-recipes/is-teflon-coating-safe

Re:How Plastics Are Poisoning Us by brnt on Wednesday June 28, 2023 @10:54AM (#36507351)
PTFE is a PFAS, as is PFOA.

> Now, since PFOA belongs to a large group of chemicals called PFAS, consisting of 4,700 similar substances, it might be tempting to just switch to one of the other PFAS chemicals that hasn’t been restricted yet. But that wouldn´t solve the problem, it would only postpone and perpetuate it. [1]

[1] https://marketplace.chemsec.org/articles/news/2020/04/01/the...

I.e. there's a whole zoo of similar compounds, and all those type specific safety claims are all at room temperature. The whole point of their use is often on heated surfaces, getting near and over the safety limit.

Re:How Plastics Are Poisoning Us by kurthr on Wednesday June 28, 2023 @12:48PM (#36509092)
Sorry, but PTFE (polytetrafluoroethylene) may be a PFAS (per-and polyfluoroalkyl substances but not a Perfluorooctane Sulfonate PFOAS) however, it is definitely not a PFOA (perfluorooctanoic acid).

Your link does not contain a reference to PTFE and looking at the meaning of the acronyms should provide evidence fluorethylene is not a sulfonate or an octanoic acid.

The manufacture of PTFE may involve generating these as bio-hazardous byproducts and PTFE could be contaminated or even break down into them, but they are chemically not the same.

Re:How Plastics Are Poisoning Us by crznp on Wednesday June 28, 2023 @03:15PM (#36511191)
I think you misread: GP claimed that PTFE is a type of PFAS, and separately: PFOA is also a type of PFAS. And if PFAS is the problem, it wouldn't be useful to ban specific classes like PFOA if they are just replaced by different classes of PFAS.

I'm not sure about the last claim: it isn't clear that all PFAS are equally bad, so replacing PFOA with a different PFAS might be worthwhile. It seems hard to study, but with Europe banning PFOA, perhaps we'll get some more insight.

Re:How Plastics Are Poisoning Us by Retric on Wednesday June 28, 2023 @11:50AM (#36508251)
Here’s a direct quote from your link: “Health Risks of Teflon Coating

Teflon is generally safe, but heating it to above 300 degrees Celsius or 570 degrees Fahrenheit poses a danger to your health.”

Note they didn’t say Teflon was safe at 299C, the risk is chemical breakdown not a phase transition like water which boils at a specific temperature and pressure. When used properly pans shouldn’t get anywhere close to that temperature range but it’s very possible to get to a dangerous temperature if there isn’t food in the pan.

Re:How Plastics Are Poisoning Us by kurthr on Wednesday June 28, 2023 @12:29PM (#36508830)
All the carbohydrates will be coated with Acrylamide or burnt to a crisp. Acrylamide is believed to be a carcinogen (Acrylamide is converted to a compound called glycidamide , which causes mutations in and damage to DNA) and shown to be in animal models.

Once you're frying, roasting, and grilling things at this temperature you are increasing cancer risk completely unrelated to any cooking materials involved. That's true of french-fries, bread, steaks and a zillion other things. It's why they're tasty (see Malliard reaction).

I certainly consider cast iron relatively safe, but it's polymerized unsaturated oil is likely to leach acrylamide and associated chemicals. It's just that compared to the food you're eating it's not relevant.

Re:How Plastics Are Poisoning Us by caeril on Wednesday June 28, 2023 @02:12PM (#36510340)
Hate to be the raving "seed oils are going to kill you" guy, but Acrylamide can be greatly reduced by swapping your vegetable-based cooking oil with something like tallow, lard, or coconut oil: https://pubmed.ncbi.nlm.nih.gov/27374529/
Re:How Plastics Are Poisoning Us by bumby on Wednesday June 28, 2023 @12:56PM (#36509207)
I see online a lot of talk of the temperature and off-gassing relationship. I've also heard that it's slightly misleading because it's temperature and time dependent, where the temperature risk has to occur in such a short period of time that it doesn't reflect cooking use. However, I could not find the off-gassing studies; do you have links? It seems like the temp of 340C most often cited, apparently from a DuPont study.
Re:How Plastics Are Poisoning Us by brnt on Thursday June 29, 2023 @04:09AM (#36517735)
> When used properly pans shouldn’t get anywhere close to that temperature range

What frying pan when used properly doesn't get near 300 C? A pan surface temp of 200-250 C is nothing strange when frying a steak.

Re:How Plastics Are Poisoning Us by Retric on Thursday June 29, 2023 @07:25AM (#36518986)
250C is quite a long way from 300C.

It’s the same gap was walking outside into 25f and 115f Aka below freezing to punch you in the face hot.

[dead]
Re:How Plastics Are Poisoning Us by colordrops on Wednesday June 28, 2023 @12:29PM (#36508823)
Source?
Re:How Plastics Are Poisoning Us by vkou on Wednesday June 28, 2023 @01:57PM (#36510134)
> PS: Toothpaste which you should mostly spit out generally contains less than 0.5% fluoride compounds such as sodium fluoride NaF or tin fluoride SnF2, the F in both being Florine.

And table salt is made out of Sodium and Chlorine, one of which is explosive when mixed with water, and the other is used to gas soldiers in trenches if you're into committing war crimes.

What matters is what effect the particular chemical has when you put it through common household uses, not the effect of its constituent parts.

Re:How Plastics Are Poisoning Us by Retric on Wednesday June 28, 2023 @03:56PM (#36511728)
I added that because the first two responses seemed to be confused.

Anyway, uncommon household uses can also be a safety concern. People still do occasionally get poisoned by mixing ammonia and bleach even despite the repeated warnings.

Talking about the constituent parts is similarly relevant when you’re heating something to significant temperatures. Many reasonably safe substances really shouldn’t be tossed on a bond fire etc. For other things it’s not the substance itself that’s a concern but impurities from the manufacturing process. People often think of past recalls as companies doing something dumb, but I think we underestimate how difficult it is to get this stuff right.