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Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @11:23AM (#25544329)
As it stands, I don't see how hydrogen proponents in either vehicles or energy distribution can recoup the head start of pure electric. The best electrolysis + fuel cell cycles commercially available are maybe 35-40% efficient (electric-electric). Maybe someday, 20 years from now, some quantum catalyst gizmo will push that to 90%. For vehicles you then need another step of compression to force the hydrogen inside a very high pressure tank - by the laws of thermodynamics this can only cost you energy regardless of any technological advancement.

Meanwhile, electric batteries today are over 90% eficient on the whole charge-delivery cycle, the industry is rapidly gaining momentum, charge networks are built, the cost of components only goes down. Compared to hydrogen, battery electrics are today where internal combustion cars were compared with electrics 100 years ago: the market has spoken and the massive economies of scale of the winner will relegate the competitor to very specialized niches.

And once you lose the hydrogen vehicles, the whole distribution network becomes a very dubious business proposition. Why build H2 pipes that need expensive and inefficient electric conversion endpoints, when you can rely on and extend the existing electric distribution networks? Indeed, you can store hydrogen, but what advantage do you have by storing it closer to the consumption point, instead of a grid connected hydrogen battery that generates, stores and consumes hydrogen as requested by the smart grid? In that scenario, hydrogen becomes just one of multiple competing energy storage technologies, together with pumped storage, grid connected batteries etc., all together helping to regulate intermittent renewables.

Re:Photocatalyst splits water into H and O2 at quantum effic... by exabrial on Saturday December 26, 2020 @11:36AM (#25544432)
Real Engineering did a video about this and committed the same fallacy. Engineers nearly always overlook practicality and chase perfection.

Heres the thing: It's not about efficiency, it's about convenience. Transferring 2700 megajoules of energy to an f150 via gasoline in a few minutes is very convenient, something that would take a Tesla a few hours. If consumers were concerned with efficiency the same way engineers were, we'd all be driving electric hummers and cybertrucks.

Hydrogen isn't aiming to be as efficient as batteries. It's assuming to be as convenient as gasoline, but with little environmental impact.

Re:Photocatalyst splits water into H and O2 at quantum effic... by cmrdporcupine on Saturday December 26, 2020 @11:59AM (#25544631)
Except that as we keep trying to point out, 90% of EV charging occurs overnight at home, or at work during the day. Yes, that does not cover all cases for all people, but it covers a large part and the scenario people keep bringing up is the exception to the rule that would only take place if people were on road trips or there was no charging at their residence or work.

Obsessively talking about charging times is a frame of reference influenced by decades of driving ICE vehicles. And frankly the hydrogen vehicle thing also seems like it is heavily influenced by this mindset as well.

I can't make or fill gasoline (or hydrogen) at home. After years of "refueling" my Volt this way, I'd have a hard time giving up my "gas butler" that gives me a full "tank" every time I leave my house, and having to return to going to gas stations sounds highly unpleasant and very inconvenient.

Re:Photocatalyst splits water into H and O2 at quantum effic... by creddit on Saturday December 26, 2020 @12:15PM (#25544754)
> Except that as we keep trying to point out, 90% of EV charging occurs overnight at home, or at work during the day.

This isn't a good comparison at all. You're looking at the set of people who looked at the operational requirements for EVs and said "yes, this works for my needs" and then looking at how those needs are met. What you would really want to do is compare the operational requirements for EVs and the general usage of motor vehicles to see what proportion of the general usage of motor vehicles can be replaced by EVs and their operational requirements.

EDIT: Even further, you would really want to know about the value of different modes of usage as well. So, for example, it is possible that users value edge case usage (such as very long trips) much, much higher than they do day-to-day usage and so still you could meet 90% of general motor vehicle usage with EVs at the same convenience but if the remaining 10% was far more valuable to end users and the inconvenience too high, it might still not be reasonable.

Re:Photocatalyst splits water into H and O2 at quantum effic... by jklinger410 on Saturday December 26, 2020 @12:59PM (#25545089)
People don't know what they want. The fact is, the infrastructure for renting gas vehicles for long drives is already in place, and 99% of driving is short and local.

Thinking about "how much users value x" based on the CURRENT PARADIGM is a constraint to progress, and doesn't help predict very much at all. Consumer habits change.

Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @02:45PM (#25545889)
> The fact is, the infrastructure for renting gas vehicles for long drives is already in place, and 99% of driving is short and local.

Exactly.

If you are going on a long trip, renting or renting plus flying is likely best. If you are traveling 1200 miles, do you really want to drive for 20 hours solid? I've done it and it mostly sucks.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Hypx on Saturday December 26, 2020 @06:16PM (#25547250)
Except now your back to using fossil fuels again.

This is the big problem pro-BEV people are missing. If your goal is to reach 100% green transportation, batteries will never get you there.

Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Sunday December 27, 2020 @01:43AM (#25549349)
> If your goal is to reach 100% green transportation, batteries will never get you there.

When you pose every problem as an absolute, it's impossible to come up with a solution for anything.

I'm not one to make perfect be the enemy of good. If 99% of driving is EV and 1% is ICE then we have a much smaller problem to deal with.

Not long ago, people predicted EVs would never get to the point they are now. The picture will be entirely different in 10 more years. By the time we've replaced the first 90% of ICE vehicles, the solutions to the last 10% will become more obvious than they are now.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Hypx on Sunday December 27, 2020 @03:14PM (#25553884)
The problem is that fuel cell cars really can take you to 100% green transportation. This is a problem that can be avoided entirely.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ncmncm on Saturday December 26, 2020 @08:11PM (#25547911)
Nobody seriously expects to get to 100% green anything. Getting to 95% provides all the benefit anyone rationally hopes for. Squeezing out the remaining few percent is not worth the extra cost, much as getting the last bit of toothpaste out of the tube is not worth the bother (unless you are indulging obsessiveness).
Re:Photocatalyst splits water into H and O2 at quantum effic... by Hypx on Sunday December 27, 2020 @03:15PM (#25553891)
People seriously expect fuel cell cars to allow for 100% green transport. Only from a BEV context do you talk about figuring out the last 10% or whatever.
Re:Photocatalyst splits water into H and O2 at quantum effic... by richardw on Sunday December 27, 2020 @12:06AM (#25549014)
I’m significantly more interested in saving the planet for my child than I am in driving a car with a specific powertrain. I’m pro-BEV because it seems to be a good way to move in the right direction. I drive an ICE VW but will move as soon as it makes sense to.

When I need a 4x4, I rent one.

Re:Photocatalyst splits water into H and O2 at quantum effic... by m4x on Saturday December 26, 2020 @10:10PM (#25548472)
Are pro-BEV people actually missing this? At least for now, the goal is only to remove some of the more significant sources of pollution. Vehicles for personal transport are a reasonable place to start. Obsessing about perfection is only going to hold us back.
Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @12:42PM (#25544952)
I think the point made here is that those very requirements are tailored around a ICE world. If, say, your city bus network is designed so that each driver can make a 5 minute stop at terminus and fill up when required, of course pushing an electric bus into that will create 1-2h gaps in service and be "not fit to operational requirements". But it's a simple exercise to shift things around so that all recharging is done in low demand periods and all your fleet is online during rush hour.

The bottom line: electrics are quickly overcoming the 1000Km/charge barrier, in the next 10 years it will probably become the norm. That's a charge level that can last you a full day in almost any conceivable usage mode, so it can cover 99% of real world tasks.

Sure, there will still be very specialized tasks where 2 hours of downtime per day is unacceptable, or some fresh produce delivery route that requires 36 hours non stop driving by a shift of truckers. But that would be negligible in the grand scheme of things.

Re:Photocatalyst splits water into H and O2 at quantum effic... by elihu on Saturday December 26, 2020 @03:32PM (#25546241)
The other possible option to work around range issues with electric vehicles is to electrify our major highways so that battery capacity is no longer a concern. That would require expensive infrastructure upgrades and new standards for how to charge a moving vehicle, but it would mean vehicles could be substantially lighter and less expensive.
Re:Photocatalyst splits water into H and O2 at quantum effic... by bumby on Saturday December 26, 2020 @01:11PM (#25545179)
>36 hours non stop driving by a shift of truckers. But that would be negligible in the grand scheme of things.

Can you elaborate on why you’d consider trucking to be a negligible edge case? What I could find online shows it’s over 40% of commercial miles and over 60% of transport for delivered goods.

Re:Photocatalyst splits water into H and O2 at quantum effic... by adwn on Saturday December 26, 2020 @01:48PM (#25545433)
You left out this important qualifier in your quote: "[...] some fresh produce delivery route that requires 36 hours [...]". yholio was talking about a particular niche case, not about trucking in general.
Re:Photocatalyst splits water into H and O2 at quantum effic... by bumby on Saturday December 26, 2020 @03:00PM (#25545993)
Ahh, ok, I read it as two separate cases (produce delivery and long haul trucking). Thank you for clarifying
Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @02:42PM (#25545867)
Trucking is 40% of commercial miles. Most trucks are parked for hours/ day so the driver can sleep. It'll be interesting seeing how this changes as autonomous driving becomes more common.
Re:Photocatalyst splits water into H and O2 at quantum effic... by bumby on Saturday December 26, 2020 @03:02PM (#25546013)
Some trucking companies are using a “local” model where a driver will drive 4 hours one way, drop off the trailer to another driver for the next leg, and pick up a trailer to drive back home to be more efficient
Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @02:39PM (#25545849)
> So, for example, it is possible that users value edge case usage (such as very long trips) much, much higher than they do day-to-day usage and so still you could meet 90% of general motor vehicle usage with EVs at the same convenience but if the remaining 10% was far more valuable to end users and the inconvenience too high, it might still not be reasonable.

How much do you weigh the inconvenience of being 10 minutes late for an appointment because you had to make an unplanned fuel stop?

How much do you value 100s of unneeded fuel stops interrupting your life?

Fortunately, it's not necessarily an either/ or. You can buy an EV for 99% of driving and just rent an ICE car when you need to road-trip.

Re:Photocatalyst splits water into H and O2 at quantum effic... by creddit on Saturday December 26, 2020 @03:46PM (#25546336)
Totally. I’m not taking a side here. I think it’s a really complicated issue. I’m excited for EVs and optimistic about their future but we have to be real about trade offs when considering other possibilities.
Re:Photocatalyst splits water into H and O2 at quantum effic... by iso1210 on Saturday December 26, 2020 @01:51PM (#25545463)
> This isn't a good comparison at all. You're looking at the set of people who looked at the operational requirements for EVs and said "yes, this works for my needs" and then looking at how those needs are met. What you would really want to do is compare the operational requirements for EVs and the general usage of motor vehicles to see what proportion of the general usage of motor vehicles can be replaced by EVs and their operational requirements.

The vast majority of journeys and days overnight charging of a tesla style car is fine. The average driver

1) Spends 55 minutes a day behind the wheel

2) Drives 29 miles a day

https://solarjourneyusa.com/EVdistanceAnalysis7.php

"93% of all vehicle-days show a total distance below 100 miles. It is important to note that only vehicle-days are included where the cars were used that day"

A car with a 300 mile range covers almost all drivers for almost all uses.

So you're down to whether the downsides of owning and operating a gas-fueled car outweighs the downsides of an electric car (having to hire a gas one for occasional long trips)

As more and more people move to electric, there are fewer and fewer customers for gas stations, reducing the number around, and reducing the utility of a gas car even more. The costs of repair become higher, and the cost of the car in the first place will increase as economies of scale tip the other way.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Beldin on Sunday December 27, 2020 @06:16PM (#25555089)
> A car with a 300 mile range covers almost all drivers for almost all uses.

Depends on charging options. If you can charge overnight at home or at the office, then yes. If your only option is spending a long time at a charging station away from home / office, an EV suddenly requires planning.

Thankfully there's more and more public chargers in or near residential areas around here.

Re:Photocatalyst splits water into H and O2 at quantum effic... by vmception on Saturday December 26, 2020 @12:36PM (#25544903)
> What you would really want to do is compare the operational requirements for EVs and the general usage of motor vehicles to see what proportion of the general usage of motor vehicles can be replaced by EVs and their operational requirements.

Okay, has this been done by anyone? Something that shows current limitations of the infrastructure and projected mitigation of those?

Re:Photocatalyst splits water into H and O2 at quantum effic... by toomuchtodo on Saturday December 26, 2020 @12:50PM (#25545030)
A quick Google search doesn’t find anything official from NREL or similar DoE labs, but I’m mobile so my search is quick and not comprehensive.

The average American round trip commute is under 40 miles. Longer commutes can be accommodated with financial incentives and legal requirements for employers to provider EV chargers on prem (with pass through billing for the power, or providing it for free). Anything beyond that (high daily mileage outliers) are served by long range EVs and Fast DC charge networks.

Re:Photocatalyst splits water into H and O2 at quantum effic... by hakfoo on Saturday December 26, 2020 @04:49PM (#25546706)
I could see an interesting appeal in focusing on getting to a 1-hour or 30-minute charge time. because that allows for some structural changes to an entrenched business model.

The current gas-station/convenience-mart ecosystem is designed around a 5-minute or so petrol fueling cycle. There's nothing they offer that will keep you productively occupied for a hours-long charge cycle.

A 30-minute or hour charge cycle, in contrast, is long enough to perform errands-- I could see a large number of supermarkets, strip malls, big-box shops, and restaurants interested in offering 1-hour charging stations. You can offer cross-promotions (spend $100 in store and your charge is free) and you have captive customers who are likely to wander the aisles a bit longer/order an extra coffee or dessert if they know they need to wait another 10 minutes for their charge to complete. Maybe the no-garage apartment dweller does his charging when he goes for his weekly grocery run.

Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Sunday December 27, 2020 @01:22PM (#25553045)
Love it. The same for motels, roadside attractions etc. Once a sizable fraction of motorists require it, businesses will bend over backwards to provide it subsidized, to acquire customers for their main cash vector.

And electric is intrinsically democratic, if you have civilization you have electric power around. Some upgrades will be required but from a single business' point of view, the investment is much lower than building underground fuel storage tanks, obtaining the necessary environmental and zoning permits etc. Literally anyone can enter the charging market.

Re:Photocatalyst splits water into H and O2 at quantum effic... by koolk3ychain on Saturday December 26, 2020 @03:05PM (#25546042)
Fast charging is also arguably the least environmentally concious way to charge any electric vehicle.

A) fast charging causes battery degradation at least 3-5x as fast as charging at or below the nominal "C" rating of a given cell or amortized individual cell rating. This means, in the next 10 years, more batteries have to be produced, more lithium has to be mined and more Tesla parts have to be shipped on diesel powered vehicles. [0][1]

B) it uses more power and places more demand on the grid, hence you're burning more coal in order to meet the demand curve and incur a larger transitional period in production which means more fossil fuels burned, more energy lost to conversion and at the end of the day more Co2 in the air. [2]

0 - https://cleantechnica.com/2017/07/09/tesla-limiting-supercha...

1 - https://cleantechnica.com/2020/01/12/is-it-true-that-a-tesla...

2 - https://afdc.energy.gov/files/u/publication/ev_emissions_imp...

Re:Photocatalyst splits water into H and O2 at quantum effic... by BobbyJo on Saturday December 26, 2020 @12:58PM (#25545079)
Yes, EVs are a great 99% solution. The problem is people aren't willing to own a second car to take care of the other 1%, so they need their car to be a 100% solution. Most of my friends take weekend road trips to camp or visit friends in other cities, and EVs just aren't capable of those use cases yet.
Re:Photocatalyst splits water into H and O2 at quantum effic... by Finnucane on Saturday December 26, 2020 @01:17PM (#25545238)
No car ever made is a 100% solution, and many people do own multiple cars already.
Re:Photocatalyst splits water into H and O2 at quantum effic... by DennisP on Saturday December 26, 2020 @07:22PM (#25547612)
Most people with two cars actually drive both cars every weekday. If one of them is gasoline, then you're replacing half of their gasoline consumption instead of all of it.

What those people will not do is buy two electric cars plus a gasoline car for their 1% needs. Many people also would rather not hassle with rentals on a regular basis.

But in fairness, it'd be great progress just to get to the point where most two-car families choose electric for one of them, and by the time that happens, batteries will probably be a lot better anyway.

Re:Photocatalyst splits water into H and O2 at quantum effic... by kbelder on Monday December 28, 2020 @03:08PM (#25562689)
Yeah, I think EV adoption will stall out for a long time at around 50%. Families will have one EV and one gas vehicle. That covers all their needs; two EVs won't. And the gas-burner will get used just as much, since both parents need a vehicle.

The idea that people will rent vehicles for those longer trips is a bit untethered from reality.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Finnucane on Saturday December 26, 2020 @07:32PM (#25547675)
By your reasoning they only need the rental 1 percent of the time. A lot of people use Uber more than that.

My own car is only a 20 percent solution. The rest is walking, biking, and public transit.

Re:Photocatalyst splits water into H and O2 at quantum effic... by DennisP on Sunday December 27, 2020 @12:35PM (#25552620)
Uber is very convenient. Going down to the Enterprise office and filling out paperwork to take a drive out of state, not so much.

Obviously I'm not actually claiming any particular percentage, since that varies by person.

Re:Photocatalyst splits water into H and O2 at quantum effic... by hakfoo on Saturday December 26, 2020 @04:56PM (#25546748)
I'm surprised nobody does a product that's an EV lease plus some prepaid credit every month for a rental service, so for the one day a month you need a conventional petrol car, it's already budgeted for.

Hell, you could generalize it to small petrol cars too. I suspect most of us "overbuy" larger and more capable vehicles for the one day a month we need something bigger than a Mirage.

Re:Photocatalyst splits water into H and O2 at quantum effic... by bananabreakfast on Saturday December 26, 2020 @01:25PM (#25545295)
This is 100% false and hasn't been true for a long time.

A Tesla can easily take a road trip the same as any ICE vehicle. I've personally driven one across the country. Supercharging along the way now takes the same amount of time as any normal stop for gas.

EVs are already better than a 100% solution because electricity is far cheaper than gas and you can fill up at home.

Re:Photocatalyst splits water into H and O2 at quantum effic... by drewg123 on Saturday December 26, 2020 @06:41PM (#25547415)
Maybe a Tesla can make a trip in the same time as an ICE, but only if you normally stop frequently. I'm a "drive straight thru" kind of person, and road trips in my Telsa frustrate me.

A few times a year, I make a ~950mi drive in my 2017 MX 100D (~295mi rated, ~220 maybe at 75 mph). In an ICE car its 13.5 hours of driving, and about 4.5 hours of charging. I frequently find myself wishing I owned an ICE car when I'm on the trip. Especially when the weather is cold, and I'm debating the range impact of turning the heat on vs 12 more hours of not being able to feel my toes. Or when the supercharger is busy and it ends up taking 2x as long to get from 5% to 45% because I'm sharing... or the anxiety of trying to make it one more charger to be able to save time by charging 2% -> 55% rather than 12% -> 65% (to avoid charging past the taper..)

I'm hoping the new models coming with 500 or 600 miles of range improve this. I'd probably only need to charge 3 times.

Re:Photocatalyst splits water into H and O2 at quantum effic... by ncmncm on Saturday December 26, 2020 @08:21PM (#25547961)
You need to develop a relationship with a car rental agency. And maybe an airline or rail carrier. You are putting a lot of miles on your car, reducing its value unnecessarily.
Re:Photocatalyst splits water into H and O2 at quantum effic... by hansvm on Sunday December 27, 2020 @12:31AM (#25549102)
That seems unlikely to work out in their favor, if for no other reason than that car rentals turn a profit on top of depreciation and a ton of other overhead, and the cheapest rental cars are only a few times less expensive new than their Tesla.

As a ballpark estimate, each such trip would cost at least $50 after taxes and fees for a budget car rental (ignoring gas vs supercharging or any other fees that would be incurred in both situations, assuming there aren't one-way fees, etc). After 100 such trips you'd have paid $50k in rental fees, vs simply having a Tesla with an extra 100k miles. Resale value is a nonlinear function of a lot of variables, but linearizing a few portions of the parameter space for the current market an extra 100k miles would only devalue the car by at most $16k (less if they intended to hold on to it for a few extra years instead of selling it immediately while the mileage depreciation matters the most).

Re:Photocatalyst splits water into H and O2 at quantum effic... by ncmncm on Sunday December 27, 2020 @01:22PM (#25553041)
What they said was "a few times a year". Rounding up, that would be 25 years. In a few years, there will be plenty of electric rental cars and charger stations, and the batteries will be much better.

Right now, the most expensive wear in a Tesla is battery cycles.

Re:Photocatalyst splits water into H and O2 at quantum effic... by hansvm on Sunday December 27, 2020 @02:00PM (#25553347)
The point wasn't that it works out in their favor if they make a ton of trips but not if they make a smaller number. Those figures were approximately a best-case cost for the rental and worst-case cost for mileage-induced depreciation at any point in the depreciation parameter space. If they only added 10k miles then they'd incur $5k or more in rental fees and $1.7k or less in mileage-induced depreciation by the above math.

I did misplace a zero though for what it's worth. A budget rental would only cost $500 or so over 10k miles, not $5k, if they're making the entire trip in a single day and returning it to the same place they picked it up. If that's the case the budget rental would probably be worth it financially (unless they were planning to hold the Tesla for awhile so that it hits a more favorable point in the depreciation curve), and if not then the extra rental fees are likely such that especially counting gas vs supercharging it's approximately a wash one way or the other.

Re:Photocatalyst splits water into H and O2 at quantum effic... by new_realist on Saturday December 26, 2020 @01:32PM (#25545339)
I’ve owned three Teslas and I can tell you that road tripping isn’t at all as convenient in a Tesla as an ICE.
Re:Photocatalyst splits water into H and O2 at quantum effic... by rootusrootus on Saturday December 26, 2020 @03:03PM (#25546022)
I agree, though I'd concede that we enjoy taking the Tesla on road trips because our kids are young. Stopping at the McDonalds next to the supercharger for a restroom break, sometimes lunch, or a romp in the play area for half an hour works really well for us. If our definition of roadtripping was drive-pee-drive-pee-drive-pee-drive with no real rest stops, it would definitely be faster to take our pickup (the only gas vehicle we have left).
Re:Photocatalyst splits water into H and O2 at quantum effic... by BobbyJo on Saturday December 26, 2020 @04:54PM (#25546738)
I can tell you quite definitively that a tesla with the maximum range possible will still not be able to get you to and from a great deal of small cities and camp grounds in the US, especially if you live outside California.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @02:47PM (#25545904)
If you can afford a Tesla, renting a car for 1 week a year isn't a big burden.
Re:Photocatalyst splits water into H and O2 at quantum effic... by BobbyJo on Saturday December 26, 2020 @04:48PM (#25546696)
Yet another reason EVs aren't the dominant market yet.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @05:02PM (#25546786)
Likely the single biggest reason.
Re:Photocatalyst splits water into H and O2 at quantum effic... by mypalmike on Saturday December 26, 2020 @07:26PM (#25547635)
I'd suspect the fact that not everyone has a convenient place to plug in overnight would be a pretty major factor. A good percentage of city dwellers in particular park their cars on the street, away from their home.
Re:Photocatalyst splits water into H and O2 at quantum effic... by pathseeker on Saturday December 26, 2020 @01:12PM (#25545183)
>Except that as we keep trying to point out, 90% of EV charging occurs overnight at home

Most people don't buy vehicles for 90% of the use-cases. They buy something that does everything they normally expect a car to do, which includes a long road trip every year or so. Maybe driving to a favorite campground 200 miles away, etc.

The reason people keep bringing these scenarios up is due to the fact that electric cars are terrible for these cases. Nobody is suggesting they can't be used for daily commutes.

Right now electric cars are for people who can afford to also own an ICE or rent an ICE for road trips (or who don't like road trips at all).

Re:Photocatalyst splits water into H and O2 at quantum effic... by hinkley on Saturday December 26, 2020 @01:26PM (#25545306)
Just look at the number of pickup trucks there are, with empty (even pristine) beds. Nobody is hauling stuff most of the time, but they got a vehicle that can.
Re:Photocatalyst splits water into H and O2 at quantum effic... by rootusrootus on Saturday December 26, 2020 @03:06PM (#25546051)
I think EVs make a great second car. I drive a Tesla, my wife drives a Bolt, and we have an F250 for towing the travel trailer, hauling household stuff around, or going somewhere that charging infrastructure is going to be inadequate (haven't really run into that yet, but the pickup is our catch-all). I can't see going back to ICE cars as daily drivers, but it'll be quite a while before we don't have at least one in our household. Especially as long as we continue to own the RV.
Re:Photocatalyst splits water into H and O2 at quantum effic... by carrolldunham on Saturday December 26, 2020 @03:48PM (#25546346)
so, to save the environment, everyone get two cars.
Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @04:02PM (#25546439)
Or, rather: a small enthusiast minority gets two cars, generates the critical mass required to build charging infrastructure etc., then everybody can switch directly to an electric when it becomes convenient for them.
Re:Photocatalyst splits water into H and O2 at quantum effic... by rootusrootus on Saturday December 26, 2020 @05:14PM (#25546855)
I would use a lot more fossil fuel if I used the pickup as a daily driver. Getting an EV as a second car is the sensible choice.
Re:Photocatalyst splits water into H and O2 at quantum effic... by iso1210 on Saturday December 26, 2020 @02:15PM (#25545640)
It's an emotional decision, but even with that - well under 20% of vehicles sold in the US in 2019 are trucks

https://www.goodcarbadcar.net/2019-us-vehicle-sales-figures-...

Re:Photocatalyst splits water into H and O2 at quantum effic... by cmrdporcupine on Saturday December 26, 2020 @05:38PM (#25546992)
Yep, well, this is why I drive a Volt and not a Tesla. The EV portion of it covers 90% of my use cases, and then I have the ICE to fall back on if I need it, which I do once in a while, mostly for ski or camping trips to places that will probably only ever get charging infrastructure in like... 20 yeras.

Too bad GM killed it from their line-up.

Re:Photocatalyst splits water into H and O2 at quantum effic... by gundmc on Sunday December 27, 2020 @11:08AM (#25551930)
The Honda Clarity plugs the hole left by the Volt pretty nicely. And last I checked it's still eligible for the full federal phev rebate.
Re:Photocatalyst splits water into H and O2 at quantum effic... by lodovic on Saturday December 26, 2020 @01:16PM (#25545221)
But there are a few caveats:

- The power to charge the EV is drawn from the grid

- Batteries are heavy, so you cannot scale up batteries for range

- These batteries require a lot of lithium mining

Given these, I would definitely prefer the hydrogen solution.

Re:Photocatalyst splits water into H and O2 at quantum effic... by cmrdporcupine on Saturday December 26, 2020 @05:46PM (#25547044)
- The grid where I am is 90% non-CO2 emitting; nuclear and hydroelectricity with natural gas supplimenting it. We phased out the last of the coal plants 15 years ago. More places should, the air quality in the whole province improved markedly after.

- I drive a car with a small 14kWh battery, and a backup ICE for when I need it. 90% of my miles are electric. I don't understand why this model isn't more popular. I see no need to drag around a 60kWh battery "just in case" I need that extra range.

- Lithium isn't the huge environment/social problem really. Basically big evaporation ponds in desert areas. There's even some work being done to pull lithium out of abandoned oil wells in some locations. Some of the other components are a problem, such as Cobalt in some formulations. But all these formulations can be played with. And they are one-time for the whole vehicle, rather than requiring continual extraction. And can be recycled. Can't recycle petroleum or hydrogen.

Meanwhile the only practical sources for producing hydrogen require fossil fuels, typically natural gas, and end up emitting CO2. Emitting CO2 is not necessary for EV usage. But most practical sources of hydrogen do. And the efficiency is far lower.

Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @04:13PM (#25546497)
There is no fundamental physics reason to use lithium, it's just the current best technological node. There are many technologies that are very promising in the lab, like carbon nanotubes, iron and sodium ion, aluminum-air etc. There is massive research in this area and if none of these technologies turn out to be economically superior to Li-ion in the near future, then they will certainly be available if, for environmental reasons, lithium becomes expensive.

https://www.pocket-lint.com/gadgets/news/130380-future-batte...

Re:Photocatalyst splits water into H and O2 at quantum effic... by Hypx on Sunday December 27, 2020 @03:19PM (#25553911)
It’s times like these that people should realize that fuel cells are a type of battery. You can call them hydrogen-air batteries.
Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Sunday December 27, 2020 @10:54PM (#25556530)
That's not really accurate since the "electrolyte" changes phase requiring external storage (H2O -> gaseous H2) and the re-oxygenation step cannot be performed (yet) in the same device as the electrolysis.

It's not an electrochemical battery but I can agree with seeing it in a general sense as the an energy storage device, in the same way a dam is a "gravitational battery".

Re:Photocatalyst splits water into H and O2 at quantum effic... by Hypx on Monday December 28, 2020 @01:25AM (#25557199)
You can perform both steps in the same device. It's just more efficiency to have a dedicated electrolyzer doing that elsewhere.
Re:Photocatalyst splits water into H and O2 at quantum effic... by linuxftw on Saturday December 26, 2020 @12:32PM (#25544867)
Problem 1) Many people don't live in houses. Problem 2) Free charging at work or elsewhere ends once a significant share of people utilize it Problem 3) electric grid can't handle the amount of capacity needed, not by a long shot.

If petroleum didn't already exist we'd be trying to create it.

Re:Photocatalyst splits water into H and O2 at quantum effic... by hinkley on Saturday December 26, 2020 @01:31PM (#25545332)
There are quite a few urban areas with single occupant houses but without driveways. Most people wouldn’t want to install a charger out in their parking strip, on general principle - too exposed. Running high current wires out into the front yard and under the sidewalk would also be a mess.

And that’s all ignoring the fact that the city owns the parking strip, not you, and I don’t think they’re going to be interested in having that kind of equipment in their space.

Re:Photocatalyst splits water into H and O2 at quantum effic... by rootusrootus on Saturday December 26, 2020 @03:07PM (#25546069)
> I don’t think they’re going to be interested in having that kind of equipment in their space.

Aren't some cities (LA comes to mind) installing level 2 chargers along the street?

Re:Photocatalyst splits water into H and O2 at quantum effic... by hinkley on Tuesday December 29, 2020 @12:51PM (#25572493)
That's a good point. I think it's qualitatively different for a city to decide to build charging stations on 'their' property versus a private citizen.

There's also no guarantee they'll put it in front of my house. Or if long-term that's what I want (now I get home from work late and some other EV is parked in front of my house? How do I feel about that if I have an early meeting tomorrow?)

Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @02:53PM (#25545940)
> If petroleum didn't already exist we'd be trying to create it.

You are forgetting about the power of NIMBY!

If gasoline weren't already a vital piece of infrastructure, nobody would allow a gas station to be built in their neighborhood. Any time someone tried to build one, the pile of litigation would bury the prospective builder. This is already an issue and our society has largely taken the risks of having (literal) toxic waste at the end of their block.

Re:Photocatalyst splits water into H and O2 at quantum effic... by viraptor on Saturday December 26, 2020 @07:17PM (#25547586)
NIMBY like that is only a problem in a specific environment. My gas station is 5min drive away, which in practice means out of town. Even bigger cities around here have more industrial/commercial areas. It have the gas stations attached to shopping centres. So I don't think NIMBY would affect the introduction of petrol.
Re:Photocatalyst splits water into H and O2 at quantum effic... by DarmokJalad1701 on Saturday December 26, 2020 @12:03PM (#25544659)
> that would take a Tesla a few hours

Even with "version 2" superchargers, this is not true. With 250kW (v3) charging, you can get to a sufficiently high state of charge (>80%) in under 30 minutes. And the thing is, given how efficient an EV is, you don't need 2700 mega-joules (20 gallons of gas or 750 kWh) to go ~500 miles. The Cybertruck will do that range to with ~100-150 kWh of battery and charge up in under an hour. This will probably get faster over the coming year as charging rates go up.

And like another comment pointed out, majority of charging happens overnight or during the day when the car sits idle. I own a Model 3 myself and I have not been to a supercharger in several months.

Re:Photocatalyst splits water into H and O2 at quantum effic... by huntertwo on Saturday December 26, 2020 @01:47PM (#25545432)
20 gallons of gas still only takes 5 minutes to fill. If I can get 125 KwH in 30 minutes with your v3 charging that's still a 6x multiplier, not really something you can ignore.

Now you need bigger charging stations because people are spending longer at the pump or else you'll have longer lines. Adding to that, I sure as hell am not spending half an hour at a pump on an already long road trip.

The lack of population density in the US, especially in the middle of the country, makes electric vehicles not a great choice for many people. I'm guessing this is why we see higher adoption in Europe on a consumer and infrastructure level.

Re:Photocatalyst splits water into H and O2 at quantum effic... by DarmokJalad1701 on Saturday December 26, 2020 @02:06PM (#25545563)
I live in Iowa. It's about as "middle-of-the-country" as it gets. Lines at charger stations are really a California problem as of now. I have never encountered it driving throughout the midwest and I have gone on some long road-trips.

As for taking 30 minutes to charge, what people usually do is to make sure their charging stops line up with food/bathroom breaks. Realistically, if I drive 10-12 hours in a day, I would stop about 3-4 times for food/bathroom breaks, if not more. This lines up perfectly with the range in my Model 3 AWD. In many cases, I have ended up having to get up and go get my car to avoid idle-rates because it finished charging while we were still eating.

On these trips, I usually pick a hotel/B&B with destination charging so that I can get going in the morning the next day with a full battery.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Dylan16807 on Saturday December 26, 2020 @11:57PM (#25548974)
The "6x" is a number to ignore, because it's focused on one tiny part of the trip. If you can drive all day long with 1 stop, then the extra 25 minutes only makes you a few percent slower.
Re:Photocatalyst splits water into H and O2 at quantum effic... by bananabreakfast on Saturday December 26, 2020 @01:32PM (#25545338)
This is a point that needs to driven home.

Yes, filling up gasoline delivers energy at an insanely high rate due to its density but the vast majority of that is wasted and not converted to miles driven.

The real comparison is miles of range delivered per minute of fueling. And a Tesla supercharger is already competitive with gasoline by this metric. If hydrogen takes longer than gas to fill up a tank for a similar range then its already behind just charging directly.

Re:Photocatalyst splits water into H and O2 at quantum effic... by pdonis on Saturday December 26, 2020 @03:45PM (#25546328)
> Hydrogen isn't aiming to be as efficient as batteries. It's assuming to be as convenient as gasoline

And it won't be. H2 is terrible for convenience of handling compared to gasoline. Handling liquid H2 is a nonstarter, it liquefies at 21 K at atmospheric pressure; cryogenics like that are not convenient at all. Gaseous H2 will escape through every tiny gap in whatever containment setup you choose, plus it's highly flammable, much easier to ignite inadvertently than gasoline.

And to top it all off, at the end of the day, its available chemical energy per unit mass is only two to three times that of liquid hydrocarbons. That's simply not enough of an advantage to overcome all the downsides.

What H2 can be used for is to make liquid hydrocarbons, through various chemical processes.

Re:Photocatalyst splits water into H and O2 at quantum effic... by m4rtink on Saturday December 26, 2020 @03:57PM (#25546412)
Hydrogen is also notoriously low density, even in liquid form. It embritles metals on contact. Hydrogen fires are invisible during the day (if you see rocket engineers walking around with broom pointed forward in front of them, that's why).

Personally I count on hydrogen for high energy space propulsion (either chemical with oxygen or alone in a NERVA for NTR) as otherwise it's IMHO too much of a headache to work with in practice.

Re:Photocatalyst splits water into H and O2 at quantum effic... by aqme28 on Saturday December 26, 2020 @08:03PM (#25547859)
It doesn't just escape through tiny gaps. It's small enough to permeate through any material we use to contain it.
Re:Photocatalyst splits water into H and O2 at quantum effic... by aquadrop on Saturday December 26, 2020 @12:09PM (#25544697)
Using electricity usually is even more convenient, since you can do that at home, and very few of us have gas station in the garage.
Re:Photocatalyst splits water into H and O2 at quantum effic... by manmal on Saturday December 26, 2020 @12:20PM (#25544787)
I charge my electric Hyundai with a normal power outlet, and every once in a while I fast-charge it. 99% of the time that‘s good enough already. If we‘re going by convenience, plugging in at home is probably more comfortable than driving to a gas station, waiting 5 minutes, paying, and driving back.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ogre_codes on Saturday December 26, 2020 @02:26PM (#25545739)
> Heres the thing: It's not about efficiency, it's about convenience. Transferring 2700 megajoules of energy to an f150 via gasoline in a few minutes is very convenient, something that would take a Tesla a few hours. If consumers were concerned with efficiency the same way engineers were, we'd all be driving electric hummers and cybertrucks.

There are 2 types of convenience.

- Being able to fuel up quickly on a long trip

- Having your fuel tank full at the beginning of every single trip.

Hydrogen fuel cells (and combustion engines in general) are better only for the former case. Since most people drive less than 300 miles most of the time, it's hard to argue a car optimized for longer trips is more convenient for most drivers.

Re:Photocatalyst splits water into H and O2 at quantum effic... by lowercase1 on Saturday December 26, 2020 @11:44AM (#25544506)
75 kWh doesn't take a few hours with a supercharger. Doing similar with hydrogen is probably a similar level of infrastructure.
Re:Photocatalyst splits water into H and O2 at quantum effic... by deeviant on Saturday December 26, 2020 @01:13PM (#25545197)
> Transferring 2700 megajoules of energy to an f150 via gasoline in a few minutes is very convenient, something that would take a Tesla a few hours.

A 75% charge can happen in ~20 minutes on something like a 250kw Telsa super charger. Battery tech and battery charging tech will only get better/faster. Also the vast majority miles driven on the road aren't "road trip" miles in which you would see the drive-to-fuel/energy exhaustion over and over for days on end scenario. When a Tesla plugs in at home and charges over night, that's actually more convenient than having to go to a gas station.

Re:Photocatalyst splits water into H and O2 at quantum effic... by TheRealPomax on Saturday December 26, 2020 @12:41PM (#25544943)
and economics. If I can make an H2 vehicle for less than it cost me to make a gas or electric vehicle, it's worth my time and money to push into or even create a market that'll buy them.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ericd on Saturday December 26, 2020 @08:31PM (#25548022)
>Heres the thing: It's not about efficiency, it's about convenience.

>Hydrogen isn't aiming to be as efficient as batteries. It's assuming to be as convenient as gasoline, but with little environmental impact.

Energy conversion efficiency is pretty important for that "little environmental impact" part.

Re:Photocatalyst splits water into H and O2 at quantum effic... by ttul on Saturday December 26, 2020 @11:39AM (#25544463)
Also, it’s not just an option for passenger vehicles. Natural gas can be replaced with hydrogen in the existing pipeline network, providing distribution of heating gas at extremely low cost and with a very minimal investment in retooling of existing furnaces.
Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @11:48AM (#25544543)
Aside from blending small amounts on hydrogen in existing methane feeds, no one will do this. Pure hydrogen is a dangerous gas that burns much hotter than methane, can seep trough the tiniest of cracks that methane/propane cannot and can even penetrate the crystal lattice of common metals such as steel, leading to embrittlement and catastrophic failure under normal use. By the time you upgrade the methane infrastructure to handle it, you will build a whole network all together.

And there is also an economic argument: methane/propane work because they are pure energy coming from the ground, you can only burn them to recover it. To produce Hidrogen, you need electric energy, or some very hot source that could be turn to electricity at a high efficiency. It makes zero sense to generate hidrogen in order to burn it for domestic heating, when the equivalent electric energy could give 3-5 more heat using electric heat pumps.

Re:Photocatalyst splits water into H and O2 at quantum effic... by zbrozek on Saturday December 26, 2020 @12:22PM (#25544801)
It looks like you can blend something in the neighborhood of 10-15% hydrogen into the existing natural gas infrastructure without negative consequence. That's not game changing, but it's a significant environmental improvement if you're using renewables to produce it. It's a fine way to utilize daily or even seasonal renewables overproduction in a useful way without blowing up tons of existing infrastructure. Many diverse steps - some small, some large - are needed to get ourselves to a carbon negative lifestyle.
Re:Photocatalyst splits water into H and O2 at quantum effic... by iso1210 on Saturday December 26, 2020 @02:36PM (#25545833)
> Aside from blending small amounts on hydrogen in existing methane feeds

What's "small"?

20% hydrogen on existing grid in place now: https://www.theguardian.com/environment/2020/jan/24/hydrogen...

100% hydrogen trial over next few years: https://www.msn.com/en-us/news/technology/scottish-homes-wil...

Hydrogen has suddenly skyrocketed up the agenda in Europe this year. There is a pressure group called Hydrogen Europe (which oddly doesn't even have a wikipedia page) which comprises companies like BP, Shell, Total, Equinor, Repsol, Engie, OMV, PKN Orlen, Hellenic Petroleum, and many more. At the same time almost 100% of hydrogen used in europe comes from oil.

It concerns me how much government subsidy (both cash and regulations) is being pushed into hydrogen.

https://www.thisismoney.co.uk/money/markets/article-8970377/...

"Hydrogen companies were given a boost this week after the Prime Minister vowed to inject £500million to 'turn water into energy' as part of a 10-point plan for Britain's green recovery.

However, critics say the targets are nowhere near enough compared to Germany's and France's respective plans to invest €9billion and €7billion in hydrogen."

Re:Photocatalyst splits water into H and O2 at quantum effic... by bumbada on Saturday December 26, 2020 @06:34PM (#25547355)
Everything has gotten subsidies in the past. Coal got it in Germany, Spain, Rusia,Poland, Norway and of course England. Places like current Bangladesh supported coal mines in England.

Certainly oil got it later, but few places in Europe had it compared to coal. Refineries grew costing lots of billions.

Then natural gas got it with the investment of big gasoducts.

Then it was renewables. Hydrogen is just the next step, because it is the cornerstone of the chemical synthesis process, not just transportation.

Hydrogen and electricity are just "vectors". They let you use coal,gas,nuclear, hydro or Eolic power to power your cars and trucks with much less dependency on US controlled oil for industry and transportation.

Re:Photocatalyst splits water into H and O2 at quantum effic... by ttul on Saturday December 26, 2020 @11:20PM (#25548789)
> Aside from blending small amounts on hydrogen in existing methane feeds, no one will do this.

The province of Alberta, Canada has put hydrogen at the core of its energy development strategy. The idea is to use existing natural gas pipelines to transfer hydrogen.

It’s true that a small fraction of hydrogen will permeate the pipes and leak; however, that leakage is not economically significant:

“... this theoretical distribution main leakage rate (43 million ft3/yr) would be 0.0002% of the 24.13 trillion cubic feet of natural gas consumed in 2010.” [1]

Hydrogen can be blended with natural gas (the above calculation was made assuming a 20% blend) or it can be sent down the line exclusively. As for how the hydrogen is produced, there are several ways:

1. It can be cracked from natural gas, after which the carbon is captured and stored back underground. Or,

2. It can be produced from electrolysis of water using energy from a renewable source such as wind or solar, effectively storing the energy for later use.

Either way, the point is that hydrogen is a useful fuel that can be transported over existing infrastructure and then used in a variety of ways that may help with the transition to a zero carbon system. Just to give one example, hydrogen can be combined with carbon dioxide to create jet fuel. [2]

[1] https://www.energy.gov/sites/prod/files/2014/03/f11/blending...

[2] https://www.nature.com/articles/s41467-020-20214-z

Re:Photocatalyst splits water into H and O2 at quantum effic... by mojomark on Saturday December 26, 2020 @12:37PM (#25544915)
>>To produce Hidrogen, you need electric energy, or some very hot source that could be turn to electricity at a high efficiency.

This is not a true statement... Aluminum alloys readily liberate H2 from H20 at room temperarure (an exothermic reaction generating roughly equal parts thermal and chemical potential energy - both of which of course can be used for work) [1].

The oxidized aluminum is environmentally benign and can be recycled by applying more energy to deoxydize the product. The 'purification' process is ultimately where the useful energy comes from. The energy to power the purification can come from any number of sources - but as good stewards, we opt for clean energy sources. Al smelting historically produced a lot of carbon, but thanks to R&D by Apple, there are new carbon-free alternatives for this process [2].

At my company we are researching application of this energy infrastructure loop for powering ships (where source water is abundant). Essentalially, the Al+ is your fuel (battery), and from a volumetric energy density perspective (important for ships), you can store about 2X as much as gasoline/diesel - and way better than liquified or compressed H2 storage. However, on a mass energy density perspective (important for automobiles), it is a bit worse (heavier) than hydrocarbon fuels. Again though, each application has it's own constraints when considering an energy storage medium.

The automotive or civil sectors aren't the only use-cases for hydrogen fuel cells. One needs to take a look at all sectors to really grasp the global impact. A large part of my job is to explore this big-picutre aspect, because we need to understand the long term infrastructure stability/availability of potential "clean" energy supply chains, and it's VERY complex when you consider process efficiencies over the entire supply chain, raw material abundance and regeneration potential/economics/environmental impacts/speed, geopolitical forces affecting supply chains, the list goes on and on (and on).

H2 is an interesting "energy storage" option and it will certainly continue to be researched and applied broadly.

1. PDF - https://www.google.com/url?sa=t&source=web&rct=j&url=https:/...

2. https://www.apple.com/newsroom/2018/05/apple-paves-the-way-f...

Re:Photocatalyst splits water into H and O2 at quantum effic... by rini17 on Saturday December 26, 2020 @02:13PM (#25545622)
100% of aluminium is made with electrical energy...
Re:Photocatalyst splits water into H and O2 at quantum effic... by mojomark on Wednesday December 30, 2020 @10:28AM (#25582447)
Actually, Al+ is purified by smelting, which is powered by applying thermal energy to a sample. As I alluded in my comment above, you can generate the thermal energy by any number of modes of energy transmission (electrical, chemical, RF radiation such as concentrated solar, nuclear, etc.).

The primary point of the above comment was that you need electrical energy to produce H2. That's a false statement. Al+ can generate H2 without electricity.

The important point is that the energy efficiency of any cyclic energy carrier system (batteries/chemical, mechanical, intertial, etc.) is only one, albeit important, factor. Other factors include mass and volumetric energy density, motion/environmental stability, cost, and so forth. The importance of each of these factors is weighted differently based on the application (e.g. automobiles, ships, trains, aircraft, domestic use, etc.).

Re:Photocatalyst splits water into H and O2 at quantum effic... by exabrial on Saturday December 26, 2020 @11:44AM (#25544509)
Hydrogen pipelines with probably never be a thing. It's safer and more convenient to just produce h2 at the distribution point. The oil refinery/pipeline model exists because of the difficulty in synthesizing hydrocarbons, whereas h2 is (relatively speaking) far easier to create.
Re:Photocatalyst splits water into H and O2 at quantum effic... by _jahh on Saturday December 26, 2020 @11:49AM (#25544554)
I believe OP is thinking more municipal pipes that feed individual buildings rather than a distribution pipeline like Keystone XL.
Re:Photocatalyst splits water into H and O2 at quantum effic... by lowercase1 on Saturday December 26, 2020 @11:41AM (#25544484)
1. Hydrogen distribution might be able to use/share natural gas infrastructure (not high yield so embridlement isn't as big an issue)

2. Hydrogen is used for chemical processes (refining/ammonia) that can serve as a first step even if use for energy storage never becomes feasible.

3.Hydrogen is cheaper to store (<$10) per kWh than basically anything else (>$50).

But it basically won't be relevant until we have 12 hours of storage and zero marginal cost electricity 50+% of the year. Then it may be cheaper than overbuilding renewables or capturing gas emissions to cover the last 10-20 percent

Re:Photocatalyst splits water into H and O2 at quantum effic... by neaanopri on Saturday December 26, 2020 @12:02PM (#25544649)
If there's abundant pure hydrogen, synthesizing methane gets a lot easier, and we can use natural gas infra with no modifications.

One of the cases I think about for Hydrogen is moving energy around globally. The Sahara has tons of energy potential, but nobody lives there. How can we move that energy around efficiently, even across continents? Definitely not "batteries on boats"

Re:Photocatalyst splits water into H and O2 at quantum effic... by sunstone on Saturday December 26, 2020 @01:44PM (#25545412)
A project has been announced to move energy from the Australian outback to Singapore, a distance of over 3000km mostly underwater.
Re:Photocatalyst splits water into H and O2 at quantum effic... by eggy on Saturday December 26, 2020 @11:32AM (#25544402)
I would like to see a cost comparison from true start to finish. What is the manufacturing/resource cost of making batteries? What is the efficiency or cost of producing the electricity to charge the batteries? How does this compare to making the photocatalyst and compressing and/or distributing the hydrogen compare? I remember seeing a breakdown of making batteries, distributing them, and charging them, compared with oil resource procurement, refining, and distribution. I'll take a look again, but does anyone have such a table reference? Thanks!
Re:Photocatalyst splits water into H and O2 at quantum effic... by zbrozek on Saturday December 26, 2020 @12:10PM (#25544704)
I think we're going to see a diversification in energy storage and power delivery systems for different applications. There's lots of uses for hydrogen beyond running your passenger car. It's a feedstock into a lot of chemistry (hydrogenating food, making fertilizer, reducing ores) as well as various high temperature processes.

It looks like you can blend it at some modest proportion into existing natural gas infrastructure to lighten its environmental burden somewhat.

Closer to my personal sphere, I'd be interested in using it for longer-term energy storage. It'd be amazing to be able to have some onsite high pressure or even cryogenic storage of hydrogen to be able to store a summer solar surplus for use in the winter. And yes, that's in addition to batteries to handle short term (hours up to maybe a week) of generation/load mismatches. I'd probably want to turn some back into electricity, but I'd be happy to simply burn a bunch too.

Re:Photocatalyst splits water into H and O2 at quantum effic... by smegger001 on Saturday December 26, 2020 @12:44PM (#25544963)
>Closer to my personal sphere, I'd be interested in using it for longer-term energy storage. It'd be amazing to be able to have some onsite high pressure or even cryogenic storage of hydrogen to be able to store a summer solar surplus for use in the winter.

Hydrogen really doesn't like to be stored though. It also ruins any storage vessel it is kept in long term.

You see Hydrogen is the smallest atom, small enough to fit between atoms of other materiel. and it will work its way through materials and sometimes bonding with the material sometimes just escaping, this creates a spoilage of the materiel the holding vessel is made of resulting in hydrogen embrittlement, creation of cracks and voids inside the metal,

About the only materiel we believe to be immune are carbon fullerenes and graphene. Which we have had problems producing at scale.

as for cryonic storing it you are just adding another energy cost to they system because you are spending more energy still to chill the hydrogen

>It looks like you can blend it at some modest proportion into existing natural gas infrastructure to lighten its environmental burden somewhat.

and this makes less since.

You have to spend more energy to make the H_2 by splitting the H2O than you get out of burning the H_2, so adding it to natural gas to make it more environmentally efficient doesn't make since as you are increasing the net energy cost of the system than just burning the natural gas.

Re:Photocatalyst splits water into H and O2 at quantum effic... by zbrozek on Saturday December 26, 2020 @04:39PM (#25546642)
> Hydrogen really doesn't like to be stored though. It also ruins any storage vessel it is kept in long term.

It's true that it's the smallest atom, but it's not the smallest molecule. Helium is more prone to escapement since it's not diatomic. Doing a bit of research it looks like aluminum is actually a fine container for pressurized hydrogen (low permeation rates, low embrittlement). You do need to reinforce it (e.g., composite wrapping) if you want to go to high pressures.

>and this makes less since.

FYI, s/since/sense

I think you're over-indexing on efficiency. That's not the only metric that influences success. Suppose that we have an overabundance of intermittent sources of electricity (e.g., wind and solar). Right now there's not much you can do to store it. Batteries are great for smoothing demand over hours or days, but they're quite far from smoothing demand over weeks or months.

So if you're able to cheaply overproduce electricity, it doesn't really matter if your storage process is not particularly efficient. Even at fairly low efficiencies, it's more useful than throwing it away so long as the capital cost of the conversion equipment is low enough to tolerate the intermittency.

As for the cryogenic storage adding an additional efficiency hit - yes, correct. But there's an intercept of marginal cost, storage density, and efficiency where it will be economical to do it. The technology question is if we can deliver that intercept at a lower total cost than other alternatives.

One thing that's really attractive about hydrogen is that the costs are not the processed media. Batteries are full of expensive to mine and refine materials and their storage capacity is more-or-less directly tied to the quantities of used materials. With hydrogen production the media are water and space, both of which are almost free in many contexts. Vehicles aren't really one of them because volume is precious, but for stationary applications it's a completely different story.

Re:Photocatalyst splits water into H and O2 at quantum effic... by imtringued on Saturday December 26, 2020 @05:42PM (#25547016)
>and this makes less since.

>You have to spend more energy to make the H_2 by splitting the H2O than you get out of burning the H_2, so adding it to natural gas to make it more environmentally efficient doesn't make since as you are increasing the net energy cost of the system than just burning the natural gas.

I think you are missing something or are lacking in creativity. By this logic we shouldn't use batteries either because the energy you get out of the batteries is always less than the energy you put in. Also, where are you introducing additional natural gas? It's merely meant to be used as a temporary storage technology to allow a greater renewable share.

To be more blunt. Investments into storage technologies allow more renewables to be introduced into an electric grid. Nobody cares about the efficiency because that was never the goal in the first place. The goal is reducing the usage of fossil fuels to an absolute minimum and that means using less natural gas, despite the inefficiency.

Re:Photocatalyst splits water into H and O2 at quantum effic... by TheRealPomax on Saturday December 26, 2020 @12:40PM (#25544929)
So, you don't see how EV could take over from gasoline? Because you're describing the exact same "the infra's not there, and the tech's not good enough" situation as before.

If hydrogen extraction can be be made efficient enough to economically make more sense than batteries, that's the only necessary criterium. If it can, the rest is a matter of time. If even with this approach it can't, then it won't happen. It's really just economics.

Re:Photocatalyst splits water into H and O2 at quantum effic... by _fizz_buzz_ on Saturday December 26, 2020 @05:42PM (#25547015)
1.) There is already a 240 km hydrogen pipeline network in Germany (and probably in other countries as well) [1]. It connects chemical plants in the rhein-ruhr region. So there is already a huge market for hydrogen. These chemical plants will need hydrogen in the future. If we want to get away from using oil and gas and become CO2 neutral, we need a solution for those industries.

2.) I don't see air travel happening with batteries (except really short distances or really small planes). Weight is just too much of a factor in air travel and the energy density is just too far off with batteries. Hydrogen would maybe be a solution or some fuel that is synthesised from hydrogen.

[1] https://industrie.airliquide.de/wasserstoffanlagen

Re:Photocatalyst splits water into H and O2 at quantum effic... by ashtonkem on Saturday December 26, 2020 @02:02PM (#25545542)
There are some applications where energy density is far more important than energy efficiency. Airplanes come to mind. You would accept the pumping losses when it comes to filling a 737 with hydrogen, because you literally can’t make that plane work with batteries at this point in time.
Re:Photocatalyst splits water into H and O2 at quantum effic... by kjaftaedi on Saturday December 26, 2020 @03:21PM (#25546177)
Glad to find this in the responses.

Air transport is quite possibly the best use case for hydrogen fuel that I can think of, and likely the only way we'll get sustainable air travel in the near future.

Re:Photocatalyst splits water into H and O2 at quantum effic... by rootusrootus on Saturday December 26, 2020 @03:40PM (#25546290)
Wouldn't it be easier to just work on efficient synthesis of jet fuel? Then we could just keep the rest of the infrastructure the same.

Sometimes I wonder if that would end up being a solution for cars, too. It would certainly solve a few difficult edge cases that electrification will have a hard time overcoming.

Re:Photocatalyst splits water into H and O2 at quantum effic... by mr_toad on Saturday December 26, 2020 @05:05PM (#25546804)
> Wouldn't it be easier to just work on efficient synthesis of jet fuel?

Some synthetic fuel production processes require hydrogen, so a cheap hydrogen source would still be useful.

Re:Photocatalyst splits water into H and O2 at quantum effic... by rootusrootus on Saturday December 26, 2020 @03:37PM (#25546279)
> when it comes to filling a 737

That brings up an interesting point. I wonder how much of a factor fuel is in dictating the preferred size for an airliner. Maybe if the fuel economics and physics change, we'll see an evolution towards larger numbers of smaller point-to-point airliners.

Re:Photocatalyst splits water into H and O2 at quantum effic... by konschubert on Saturday December 26, 2020 @12:46PM (#25544982)
The efficiency argument is brought up a lot, but it ignores that

Energy is cheap, Storage is expensive.

If storing a KWh of power costs 50 Cent in a battery and 5 Cent in a fuel cell, then it doesn’t matter if you pay 10 or 20 Cent per KWh of fuel.

Of course this is an example with made up numbers, but the point is valid.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Aerroon on Saturday December 26, 2020 @12:07PM (#25544677)
The problem with electric is the specific energy of batteries (how much energy per weight). Current batteries used in cars top out at around 300 Wh/kg. That's 1.08 MJ/kg. Gasoline has a specific energy of 46.4 MJ/kg. Hydrogen has even higher specific energy, but with hydrogen you need a lot of weight for safety reasons. Hydrogen probably isn't going to give you much note than gasoline in specific energy. That's still 40 times better than batteries though.

As an aside, body fat has a specific energy of 38 MJ/kg.

Re:Photocatalyst splits water into H and O2 at quantum effic... by bananabreakfast on Saturday December 26, 2020 @01:55PM (#25545490)
This is a disingenuous comparison.

The specific energy of gasoline does not matter unless put into context with the efficiency of the mechanism extracting it into useful work.

The mechanism in this case is an internal combustion engine and its efficiency is around 10%.

The mechanism for extracting useful work from a battery is an electric motor, and it achieves ~98% efficiency.

Which means gas is only ~4X more dense in terms of actual useful energy. So a battery pack weighing 4x more than full gas tank to get the same range is not unreasonable at all and is basically what a Tesla is.

Re:Photocatalyst splits water into H and O2 at quantum effic... by deadc0de on Saturday December 26, 2020 @03:31PM (#25546238)
Also ICE engines themselves are pretty heavy compared to electric motors and require heavy gearboxes and shafts.
Re:Photocatalyst splits water into H and O2 at quantum effic... by Gibbon1 on Saturday December 26, 2020 @03:57PM (#25546415)
My back of the envelope calcs say that if batteries energy density increases by 30-50% the weight penalty for electric cars disappears. It's a fuzzy line because it depends on the cars range.

Difference between electric and gasoline cars. With a gas car the marginal cost of extra range is low. With electric it's high. With gas cars the marginal cost of extra HP is high where with electric it's low.

Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @12:18PM (#25544772)
For hydrogen, the mass of the gas itself is negligible compared to the weight of the tank used to store it in compressed form:

  Therefore, an advanced composite container holding 5.7 kg of CH, would provide a range of 300 miles in a hydrogen vehicle, but will require a storage space of 260 liters (69 gallons) and weigh about 230 lb (104 kg). This will then be about nine times bulkier and three times heavier than a typical 7.5-gallon gasoline tank. (https://www.fsec.ucf.edu/en/consumer/hydrogen/basics/documents/task2_gaseous_h2.pdf )
So what you get overall is on par with the best batteries that are becoming available - which however have much better volumetric energy density. This is especially important at higher speeds: the energy required to accelerate a large mass can by recovered with a high efficiency using regenerative braking, while the friction of a bulky vehicle with air is lost (alternatively, passengers will drive a larger vehicle than required since the internal space is insuficient).
Re:Photocatalyst splits water into H and O2 at quantum effic... by theshrike79 on Saturday December 26, 2020 @12:19PM (#25544778)
Electric engines convert those Megajoules to actual motion much more efficiently than combustion engines.
Re:Photocatalyst splits water into H and O2 at quantum effic... by laumars on Saturday December 26, 2020 @11:45AM (#25544515)
I’m not going to pretend to be as well researched on this point as yourself but one thing you hadn’t mentioned is the environmental impact of disposing batteries. Isn’t that the biggest complaint against electric cars (in much the same way that fission reactors are criticised for the radioactive matter that needs to be disposed of — albeit the timescales involved are different by orders of magnitude).
Re:Photocatalyst splits water into H and O2 at quantum effic... by DarmokJalad1701 on Saturday December 26, 2020 @12:10PM (#25544709)
> the environmental impact of disposing batteries

Why would anyone want to discard these batteries with precious minerals?

1. Their lifetime is measured in decades (first in EVs and then in grid-storage) as compared to single-use for gas.

2. They (at least the various types of Li-Ion cells) are 100% recyclable. Battery production will probably switch to "urban mining" once enough has been manufactured to supply the global fleet.

Tesla recently mentioned during their battery day presentation that they plan to do exactly this. Re-manufacturing batteries will be far cheaper than mining fresh raw materials once enough EoL batteries are available.

Re:Photocatalyst splits water into H and O2 at quantum effic... by laumars on Saturday December 26, 2020 @12:17PM (#25544770)
That’s interesting. I wasn’t aware that was now possible with battery tech.

Thanks for the explanation.

Re:Photocatalyst splits water into H and O2 at quantum effic... by bananabreakfast on Saturday December 26, 2020 @01:49PM (#25545444)
check out https://www.redwoodmaterials.com/

All EV batteries are 100% recyclable and this company was founded by the original CTO of Tesla to do just that.

Re:Photocatalyst splits water into H and O2 at quantum effic... by _jahh on Saturday December 26, 2020 @11:48AM (#25544540)
if anything it's the environmental and social impact of the mining of the minerals vs the disposal.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ZeroGravitas on Saturday December 26, 2020 @01:55PM (#25545494)
I think you're correct as far as you go, but hydrogen has other uses, as an input to chemicals such as Ammonia that are currently produced and/or used in ways that release CO2.

Just Ammonia for fertilizer alone generates 2% of annual CO2 emmisions, so that alone is a market worth targetting in both environmental and business sense. As soon as the inevitable policy response kicks in there will be a massive market for green ammonia (and therefore hydrogen).

Ammonia has a decent shot at being a shipping or aviation fuel too, but many of its alternatives need the same input of green hydrogen anyway so can share costs and scale with Ammonia production.

As for intermittent renewables, we're approaching the point where we shift from mostly underproduced and only occasionally overprovisioned to them being near permanently overprovisioned and needing to find uses for that electricity that can be rarely halted to help the grid a few times a year.

Hydrogen production fits the cost profile for long-term/seasonal storage that no lithium battery can hit, even if they drop in price even more than currebtly predicted.

Re:Photocatalyst splits water into H and O2 at quantum effic... by gpapilion on Saturday December 26, 2020 @11:36AM (#25544431)
Electric still has some major disadvantages particularly around refuel times. That’s the one major area I see, and the distribution story is better for electric but also still evolving. For example the 6 chargers at the mall aren’t really enough, and scaling to a few hundred isn’t easy or viable.
Re:Photocatalyst splits water into H and O2 at quantum effic... by newacct583 on Saturday December 26, 2020 @12:45PM (#25544977)
> scaling to a few hundred isn’t easy or viable

That seems wrong to me. I mean, objectively I'd expect the construction expense of a gasoline fueling station to be much higher than just running more electrical distribution lines to a major shopping area.

I think you're making the mistake of comparing the "cost" of new construction to the sunk cost of existing infrastructure. Those gas stations don't last forever and the cost to disassemble and rebuild them needs to be part of your analysis.

Re:Photocatalyst splits water into H and O2 at quantum effic... by smegger001 on Saturday December 26, 2020 @01:01PM (#25545108)
It scales faster than building out a whole new infrastructure especially since it gets to piggyback off of existing electrical distribution networks, and any one with a driveway/garage can charge there own vehicle by plugging it into the wall albeit slower than at a purpose built charger. many of those will have a personal charger though so even that will be faster. also batteries are less prone to explosive decompression in a accident than storage tanks of highly compressed explosive gas.
Re:Photocatalyst splits water into H and O2 at quantum effic... by benlivengood on Saturday December 26, 2020 @01:09PM (#25545163)
Hydrogen may be cheaper as energy storage for meeting peak load on a mostly-renewable electrical grid. In the short term (20 years) the loss of thermodynamic efficiency isn't much compared to the ability to re-use existing steam turbines from natural gas plants. Water and carbon fiber is much more widely available than the precursors to batteries and so the working medium is more accessible world-wide.

If there's a place for hydrogen in the electrical grid then there will be cheap hydrogen available for other potential uses and the market will likely find some niches. Long-haul transport is a big one; instead of electrifying all freight rails in a country use locomotives with hydrogen fuel cells.

Re:Photocatalyst splits water into H and O2 at quantum effic... by bumby on Saturday December 26, 2020 @01:07PM (#25545148)
Yours is a very good post, I’m just curious of you could elaborate on

>electric batteries today are over 90% eficient on the whole charge-delivery cycle

Isn’t the most common electrical delivery via natural gas power plants which are generally 40%-50% efficient? Meaning the 90% is a downstream measure from the source and not really “whole cycle”? It would be interesting to see comparisons of the true life-cycle efficiency of different modes of energy delivery and storage.

Re:Photocatalyst splits water into H and O2 at quantum effic... by dghughes on Saturday December 26, 2020 @02:12PM (#25545605)
Transportation aside hydrogen storage is great for its energy density. Storing it locally probably as a hydride.

I'm picturing home use replacing oil or gas with hydrogen combined with a fuel cell.

It would be great for high demand situations where solar plus a battery setup capacity was too low. For example winter little sun (low on the horizon too) and a long cold spell.

Re:Photocatalyst splits water into H and O2 at quantum effic... by Hypx on Saturday December 26, 2020 @06:40PM (#25547412)
It should be pointed out that stationary systems can easily exceed 40% if we really wanted to. By combining heat and power generation you could push net efficiency out to 60% or higher. You also don't need to worry about compression or mobile storage saving you some more efficiency there too.
Re:Photocatalyst splits water into H and O2 at quantum effic... by rarefied_tomato on Saturday December 26, 2020 @11:40AM (#25544477)
Simple counterargument: you can't make a large electric plane. The energy density of a battery is too low.
Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @12:25PM (#25544826)
Nor can you make a hydrogen plane with current (compressed hidrogen) technology, its tanks would be much too bulky and heavy. Unless you are proposing to transform planes into some sort of foam-covered Space Shuttle external tanks storing liquid hidrogen, our best bet for carbon neutral flight is some sort of fuel synth or biofuel.
Re:Photocatalyst splits water into H and O2 at quantum effic... by ed_balls on Saturday December 26, 2020 @01:02PM (#25545111)
Electric cars are at the sweet spot. If you look at larger vehicles e.g. Semi-trailer truck, battery doesn't make sense. To have a good range you would need 5 tons of batteries which limits your cargo and it's not economic. Then you have electric ships and planes.
Re:Photocatalyst splits water into H and O2 at quantum effic... by phkahler on Saturday December 26, 2020 @01:41PM (#25545397)
I don't think hydrogen powered vehicles are viable. But what if solar-splitting of water followed by electricity generation with a fuel cell turned out the be more efficient than the best solar cells? I doubt it, but it seems like a maybe.
Re:Photocatalyst splits water into H and O2 at quantum effic... by adamcstephens on Saturday December 26, 2020 @12:25PM (#25544821)
How should we obtain enough electric generation to offset the lost of hydrocarbons?
Re:Photocatalyst splits water into H and O2 at quantum effic... by samstave on Saturday December 26, 2020 @12:16PM (#25544762)
Less pollution in the future and less need for lithium?

So maybe that’s a better trade off for the planet.

Re:Photocatalyst splits water into H and O2 at quantum effic... by qPM9l3XJrF on Sunday December 27, 2020 @08:06PM (#25555756)
How about e.g. aeronautical applications where energy density is valuable?
Re:Photocatalyst splits water into H and O2 at quantum effic... by dmead on Saturday December 26, 2020 @01:42PM (#25545404)
most of the universe is hydrogen. it's easier for a base on some other planet to find hydrogen than set up a battery factory.
Re:Photocatalyst splits water into H and O2 at quantum effic... by mr_toad on Saturday December 26, 2020 @05:18PM (#25546876)
Hydrogen is abundant in gas clouds, in Stars, and gas giants.

But unbound molecular hydrogen (H2) is basically nonexistent on terrestrial planets since their gravity is insufficient to hold onto it.

Re:Photocatalyst splits water into H and O2 at quantum effic... by ed25519FUUU on Saturday December 26, 2020 @12:31PM (#25544862)
Hydrogen has an energy density of 120 MJ/kg. Gasoline has an energy density of 46.4 MJ/kg. Lithium ion batteries at 2.5. They’re not even in the same ballpark.
Re:Photocatalyst splits water into H and O2 at quantum effic... by yholio on Saturday December 26, 2020 @01:03PM (#25545124)
> Hydrogen has an energy density of 120 MJ/kg.

Divide that by 15 to get real world densities of compressed hydrogen composite storage tanks, you need a 104 Kg tank to store 7.5 Kg of hydrogen, for a total of 111.5 kg when full.

Re:Photocatalyst splits water into H and O2 at quantum effic... by newacct583 on Saturday December 26, 2020 @12:46PM (#25544985)
Only aircraft care, though. Fuel weight in other applications is basically a non-issue except for really niche gadgets.
Re:Photocatalyst splits water into H and O2 at quantum effic... by atlgator on Saturday December 26, 2020 @01:24PM (#25545281)
As long as we have coal plants powering our electrical grid we should seek alternatives that would replace or reduce reliance on them.
Re:Photocatalyst splits water into H and O2 at quantum effic... by bananabreakfast on Saturday December 26, 2020 @01:38PM (#25545377)
This is entirely false. It's called the long tailpipe theory.

Every study that suggests this conclusion was published by Oil companies in the 90s to shut down California's effort to switch to electric cars by the year 2000.

No actual study has ever found this conclusion and in fact all find the opposite. Even with the worse polluting power generating plants, charging an EV directly off of the massive grid power generation is far more efficient in terms of pollution than burning gas inside your car.