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Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Friday February 02, 2024 @06:12PM (#39235754)
> Are you aware of the usage of PFAS in textiles, food packaging, and waterproof-treated goods?

No, because that's not true. Teflon (the substance used widely in waterproof goods and food packaging) is not the same thing as PFAS [1] (which is actually not one thing, but a whole class of things). Teflon is PTFE [2], which is different.

The terminology being casually flung around this issue is misleading. Certain PFAS types were used in the manufacture of PTFE (specifically Perfluorooctanoic acid [3]) which is the actual answer to GPs question -- this is primarily an issue of industrial concern. PFOA is far more reactive than PTFE, which is one of the most inert substances known to man. You can't just group these chemicals together in the bucket of "things that have fluoride polymers" and panic about all of them.

We regularly put teflon parts in humans, because they don't react with anything. Proving harm here is an incredibly high bar.

[1] https://en.wikipedia.org/wiki/Per-_and_polyfluoroalkyl_subst... [2] https://en.wikipedia.org/wiki/Polytetrafluoroethylene [3] https://en.wikipedia.org/wiki/Perfluorooctanoic_acid

Re:The EPA is proposing that 'forever chemicals' be consider... by feedsmgmt on Friday February 02, 2024 @07:41PM (#39236472)
"CR found 'forever chemicals' in bowls, bags, plates, and wrappers, even from some companies that say they've phased them out"

https://www.consumerreports.org/health/food-contaminants/dan...

Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Sunday February 04, 2024 @02:38PM (#39253588)
No, they found organic fuorine in the products. FTA:

> CR tested products for their total organic fluorine content, which is considered the simplest way to assess a material’s total PFAS content."

Totally different, and so completely misleading that it's mind-boggling. Do you know how many things have organic fluorine that have nothing to do with PFAS? Here:

https://en.wikipedia.org/wiki/Organofluorine_chemistry

They repeatedly say in the article that it's basically impossible to reduce organic fluorine content to zero, because it's everywhere. You cannot leap to the conclusion that "finding organic fluorine" has any relationship to Teflon in food wrapping (especially at the 20ppm threshold they used), and you also can't jump to the conclusion that this means that there's a specific health risk.

They do test for a few specific PFAS compounds "in a subset" of the wrappers later in the article. This is more compelling -- but again, you don't know where it comes from.

Re:The EPA is proposing that 'forever chemicals' be consider... by feedsmgmt on Wednesday February 07, 2024 @12:18PM (#39291219)
Per the article there are few sources of that substance other than PFAS. What makes you believe that there are many sources for it?

"That’s because all PFAS contain organic fluorine, and there are few other sources of the compound, says Graham Peaslee, PhD, a professor of physics, chemistry, and biochemistry at the University of Notre Dame in Indiana, who has studied PFAS in food packaging.

Another complication: PFAS is used so widely—found in ink on food containers, recycled paper, machines that make packaging, and more—that it often shows up in products unintentionally."

Re:The EPA is proposing that 'forever chemicals' be consider... by feedsmgmt on Monday February 12, 2024 @12:24AM (#39341688)
Here is another study they did that is phthalate and they link a PDF of their methodology: https://www.consumerreports.org/health/food-contaminants/the...
Re:The EPA is proposing that 'forever chemicals' be consider... by birdiesanders on Friday February 02, 2024 @06:14PM (#39235773)
Gortex and similar waterproof/fireproof gear are loaded with pfas/pfoa cocktails.
Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Friday February 02, 2024 @06:31PM (#39235948)
No, they aren't. PFAS (and specifically PFOA) has a carboxyl group, making it much more polar than PTFE (it is an acid). PFOA is soluble in water. PFTE is not.

Even if there were lingering PFOA in Teflon, it would be quickly washed away.

Some people try to confuse the issue by grouping together anything with a poly-CF2 chain as "PFAS", but this is wrong.

Re:The EPA is proposing that 'forever chemicals' be consider... by coldbrewed on Friday February 02, 2024 @08:12PM (#39236672)
Firefighter turnouts both have PFAS right after manufacture, and continue to emit PFAS though wear and tear.

Source: https://www.nist.gov/news-events/news/2024/01/wear-and-tear-...

Re:The EPA is proposing that 'forever chemicals' be consider... by 1over137 on Friday February 02, 2024 @07:44PM (#39236496)
>…would be quickly washed away

There is no “away”. “away” is our waterways and soil.

Re:The EPA is proposing that 'forever chemicals' be consider... by paulmd on Saturday February 03, 2024 @12:23PM (#39242499)
It’s been washed outside the environment
Re:The EPA is proposing that 'forever chemicals' be consider... by TylerE on Saturday February 03, 2024 @07:44PM (#39246314)
Please let me know where your sink that drains directly into the sun is. It would prove rather handy for the large quantity of nuclear waste I need to dispose of.
Re:The EPA is proposing that 'forever chemicals' be consider... by paulmd on Sunday February 04, 2024 @02:51AM (#39248453)
(apologies but it's a goodie) https://www.youtube.com/watch?v=3m5qxZm_JqM
Re:The EPA is proposing that 'forever chemicals' be consider... by BoiledCabbage on Sunday February 04, 2024 @12:05PM (#39252025)
Can we please keep the reddit comments on reddit? There is an entire site of simple jokes and small puns - please post them there instead.

Yes I know it was just a joke. I do have a sense of humor. Yes I know downvote buttons exist. Those are the sugar additive of online comments. In blind taste tests people will often vote the sugary comment is prefered - and this is repeated until it's filled with sugary comments.

HN is one of the few places to have avoided this fate - I'd love to keep it this way.

Re:The EPA is proposing that 'forever chemicals' be consider... by themerone on Friday February 02, 2024 @08:36PM (#39236806)
PFAS are in the DWR coating on the outside of Gore-Tex fabric. The PTFE membrane is on the inside. The DWR finish definitely ends up going down the drain or wears off in use.

There are new PFAS free DWR finishes, but don't know if Gore-Tex is using them yet.

Gore does not consider PTFE to be environmentally friendly and is working on flourocarbon free fabrics.

Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Sunday February 04, 2024 @02:28PM (#39253510)
No, they aren't. PFAS are/were used [1] in the creation of Teflon, which is what defines GoreTex.

You're being confused by people who try to argue that Teflon is as PFAS.

[1] there are other ways of making Teflon, and the industry has been phasing out PFOA for a long time.

Re:The EPA is proposing that 'forever chemicals' be consider... by themerone on Sunday February 04, 2024 @11:34PM (#39257374)
No, you don't understand how Gore-Tex is made.

Gore-Tex is a PTFE membrane laminated one side of a fabric.

The other side of the fabric is coated with a DWR (durable water repellent) coating.

The DWR finish prevents the outer fabric from being saturated with water.

The DWR is not made from PTFE and historical has contained PFAS compounds.

It is not a permanent finish, so it definitely ends up in the environment.

Re:The EPA is proposing that 'forever chemicals' be consider... by hcurtiss on Friday February 02, 2024 @06:43PM (#39236059)
There is no science connecting Goretex -- even direct skin application of Goretex over long periods of time -- with any harm whatsoever. The shrill nature of the commentary around PFAS (which by some definitions doesn't even include PTFE) is wild to me.
Re:The EPA is proposing that 'forever chemicals' be consider... by shiandow on Friday February 02, 2024 @09:13PM (#39236992)
When it comes to CF bonds I'm more concerned with bioaccumulation than direct skin contact. Besides, polonium-210 is also harmless upon direct skin contact, it's not as if skin-contact is the most dangerous form of exposure.
Re:The EPA is proposing that 'forever chemicals' be consider... by colordrops on Friday February 02, 2024 @09:15PM (#39237003)
You are talking about GoreTex in the first sentence, then PFAS in general in the next, conflating the two. The EPA has absolutely found harm in humans from PFAS using science [1]. I don't know anything about GoreTex, but I do know they changed their formula to get rid of PFAS, at least for marketing reasons if not out of fear of liability as well, considering they are being sued.

[1] https://www.epa.gov/pfas/pfas-explained#:~:text=Scientific%2....

Re:The EPA is proposing that 'forever chemicals' be consider... by kccqzy on Friday February 02, 2024 @11:29PM (#39237538)
Goretex contains PTFE, which is inert enough to be used inside the human body. It can be used to patch for example a ruptured artery. https://web.archive.org/web/20160712144834/http://www.chemhe...

Also, PTFE is decidedly not among the nine proposed by the EPA to be classified as hazardous.

Re:The EPA is proposing that 'forever chemicals' be consider... by giantg2 on Saturday February 03, 2024 @12:27AM (#39237756)
And what chemicals are used to create PTFE? How pure is the PTFE that's manufactured? What does PTFE release/breakdown to under specific conditions? The answers might surprise you.
Re:The EPA is proposing that 'forever chemicals' be consider... by ruined on Friday February 02, 2024 @06:17PM (#39235812)
no. PTFE is a member of the class PFAS.

polytetrafluoroethylene is a polyfluoroalkyl substance.

Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Friday February 02, 2024 @06:32PM (#39235967)
PTFE is not a PFAS unless you define PFAS so broadly as to be meaningless.

They're common only in that they both contain polyfluorinated carbon chains.

Re:The EPA is proposing that 'forever chemicals' be consider... by StableAlkyne on Friday February 02, 2024 @08:24PM (#39236744)
Polytetrafluoroethylene is a polymer where the individual monomers are fluorinated alkanes.

I fail to see how a polymer made entirely of fluorinated alkyl substances is not a polyfluorinated alkyl substance. I'm not really sure how one could argue they're not if we ignore politics and just look at chemical nomenclature

Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Sunday February 04, 2024 @02:55PM (#39253741)
> I fail to see how a polymer made entirely of fluorinated alkyl substances is not a polyfluorinated alkyl substance.

It is a "polyfluorinated alkyl". The term is so broad as to be meaningless, and PFOA is wildly different, chemically and physically, than PTFE. One is a water-soluble acid. The other is an insoluble substance that is one of the most chemically inert things known to science.

It's like labeling something as "fluoride-containing" and panicking because your city water supply has it (which some people do, but I digress).

Re:The EPA is proposing that 'forever chemicals' be consider... by hcurtiss on Friday February 02, 2024 @06:45PM (#39236069)
As it turns out, the definition of PFAS is hotly contested, with those advocating for increased regulation often also advocating for a very broad definition. https://www.bu.edu/sph/news/articles/2022/is-there-a-right-d...
Re:The EPA is proposing that 'forever chemicals' be consider... by dataflow on Friday February 02, 2024 @09:22PM (#39237046)
https://chemsec.org/the-teflon-chemical-ptfe-is-often-touted...

"PTFE, or polytetrafluoroethylene, belongs to a subgroup of PFAS called fluorinated polymers"

Re:The EPA is proposing that 'forever chemicals' be consider... by giantg2 on Saturday February 03, 2024 @12:29AM (#39237771)
Then you should add some sources and correct Wikipedia.
Re:The EPA is proposing that 'forever chemicals' be consider... by Natsu on Friday February 02, 2024 @10:31PM (#39237299)
This is why I don't like the term "forever chemicals" because it's not clear what it covers and it feels like a marketing term.
Re:The EPA is proposing that 'forever chemicals' be consider... by theptip on Friday February 02, 2024 @10:34PM (#39237310)
Re:The EPA is proposing that 'forever chemicals' be consider... by User3456335 on Sunday February 04, 2024 @08:30AM (#39250037)
PTFE is literally the first example mentioned in the Sample chemicals section of the wiki of PFAS, which you linked. Regardless of your views on whether Teflon is harmful, your comment contains misinformation. Teflon/PTFE is PFAS according to the OECD definition and the Wiki page.

Your point regarding whether all PFAS is harmful may very well be interesting but cannot be taken seriously if it is accompanied by blatant misinformation.

Re:The EPA is proposing that 'forever chemicals' be consider... by timr on Sunday February 04, 2024 @02:20PM (#39253432)
They list it as a "perfluroalkyl substance", which is exactly what I'm saying is wrong -- Teflon is nothing like the other substances, if only in that it isn't water soluble (it's more than that, but just for starters). You can't just group everything together under that category and claim they're all the same. These are ontological games played by people who either don't understand chemistry, want to scare people, are themselves irrationally scared, or have some other motivation for drawing the broadest possible definition of "PFAS".

If you don't understand the argument someone is making and have to rely on the verbatim language in a wikipedia article, you should probably resist the urge the label things "misinformation". Instead, just say "I don't like/agree with what you're saying", which is really what you mean.

Re:The EPA is proposing that 'forever chemicals' be consider... by User3456335 on Monday February 05, 2024 @05:46AM (#39259660)
My only point is that you use the term PFAS for a different group of compounds than multiple different official sources define it as. I'm just pointing out that that looks strange to me as a layperson.