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Re:Why Is Desalination So Difficult? by dfxm12 on Wednesday July 05, 2023 @02:31PM (#36604920)
It takes less energy but produces a concentrated liquid waste stream that must be disposed of.

I've heard that this brine is toxic. Does this make disposal an issue? Is the toxicity true or hyperbole? I mean, do we know how bad it is, and if we can do anything safely with it? It seems like "salt" is useful in a lot of contexts, including industrial, so can we do something with the brine besides disposing it somewhere?

Re:Why Is Desalination So Difficult? by xenadu02 on Wednesday July 05, 2023 @02:41PM (#36605117)
No, fresh water just enters the water cycle. It will eventually evaporate or end up in a river and back into the ocean where it will be reunited with the salt. The overall salt concentration of the ocean would not be changed unless we sequestered the fresh water permanently. Even then it would take a tremendous effort to make even the tiniest difference in salinity.
Re:Why Is Desalination So Difficult? by rtkwe on Wednesday July 05, 2023 @03:35PM (#36605917)
It will change the salinity on the short term though at the release location and the amount a large plant will be discharging is enough to alter the local salinity so long as the plant remains operational which will negatively affect sea life in that area.
Re:Why Is Desalination So Difficult? by Robotbeat on Wednesday July 05, 2023 @04:45PM (#36606843)
Only if the discharge is not diluted sufficiently.

There is nothing about reverse osmosis that is fundamentally more toxic or harmful than the typical evaporation that takes place naturally in the ocean. And it’s pretty dishonest to claim otherwise. If there’s a problem with too high salinity of discharge, that’s an engineering problem that should be fixed with greater dilution.

Re:Why Is Desalination So Difficult? by strken on Wednesday July 05, 2023 @06:12PM (#36607909)
If you're drawing water from a bay and not putting all that water back in, then the salinity of the bay must depend on the rate it mixes with the outside ocean, since you're removing water from the system.

I assume that in practice the amount of water taken by a desal plan is tiny and most bays have high tidal inflow and outflow, but it's obvious that more than just dilution should be considered.

Re:Why Is Desalination So Difficult? by 8n4vidtmkvmk on Wednesday July 05, 2023 @06:23PM (#36608038)
What would you dilute it with? Surely not the water we just extracted?
Re:Why Is Desalination So Difficult? by Robotbeat on Wednesday July 05, 2023 @10:12PM (#36610146)
You dilute it with more seawater. The salinity of the ocean changes significantly just due to evaporation. The band of variability is roughly 30 to 40 grams of salts per liter for sea surface salinity. So if your discharge is within that band, it's not going to be a significant ecological problem (especially if the discharge is at the right location). It's no more a "mass ecological problem" than surface evaporation of seawater is.
Re:Why Is Desalination So Difficult? by rtkwe on Wednesday July 05, 2023 @11:52PM (#36610971)
Mass dilution is going to be fairly expensive because you have to move a significant multiple of the water you actually process. The brine waste water is roughly double the salinity of normal sea water at 70 ppt so to get back to the 33-37 ppt that's the real average band you're looking at moving a lot of sea water to dilute the output. If you run the numbers you're looking at 15:1 of volume to get 70ppt to 37ppt using 35ppt water all while ensuring you're at a place with enough natural mixing that your inputs and outputs don't start feeding back into each other.
Re:Why Is Desalination So Difficult? by rtkwe on Wednesday July 05, 2023 @11:43PM (#36610878)
Of course but read the comment I was replying to, to my reading they're saying the regular water cycle would take care of the excess salinity which is drastically wrong in the human scale and a complete misread of the issue. The problem isn't that we'll over salinate the whole ocean but that locally the released brine will kill some, potentially large, area of underwater life before it diffuses back down to the rough background levels.
Re:Why Is Desalination So Difficult? by xenadu02 on Monday July 10, 2023 @01:13PM (#36669413)
I almost addressed this point in my original post... you need a diffusion system that runs the brine out into the ocean and mixes it with seawater to a certain concentration... as long as it isn't super concentrated or at a very different temperature it won't create a brine pool and the salt will diffuse harmlessly.
Re:Why Is Desalination So Difficult? by function_seven on Wednesday July 05, 2023 @02:37PM (#36605037)
It’s toxic only because of concentration. AKAIK, there aren’t any compounds in the brine that weren’t present in the seawater to begin with. The solution is dilution, but I’m sure it’s easier for me to type that than it is to achieve in a desalination plant.

But, why not really-long-pipe-with-small-holes-along-the-length? That seems to me like a simple mechanism to send the brine back into the ocean without causing a local disaster on the sea floor. Is there maintenance required that makes it more expensive than I realize?

Re:Why Is Desalination So Difficult? by Timshel on Wednesday July 05, 2023 @02:39PM (#36605076)
I believe I had read just dilute it until concentration is ok then release. But might be more tricky than that ^^ : https://www.sciencedirect.com/science/article/abs/pii/S00489...
Re:Why Is Desalination So Difficult? by dylan604 on Wednesday July 05, 2023 @03:01PM (#36605427)
dilute it with what? the clean water you just removed the salt from?
Re:Why Is Desalination So Difficult? by function_seven on Wednesday July 05, 2023 @03:14PM (#36605607)
No, the salt water you're about to discharge it into.

Have a pump that draws in 10L of ocean water for every 1L of brine you need to dispose of, mix 'em up, and discharge the 11L of only-slightly-saltier water back into the sea.

Not sure when it makes more sense to do that vs. having a leach-field type of brine discharge. They both ultimately do the same thing, but one requires more mechanicals, the other requires more piping and "passive" infrastructure.

Re:Why Is Desalination So Difficult? by VintageCool on Wednesday July 05, 2023 @03:12PM (#36605584)
Or a large amount of regular saltwater.
Re:Why Is Desalination So Difficult? by toast0 on Wednesday July 05, 2023 @03:46PM (#36606068)
Sewage treatment outflows maybe? Wouldn't be enough in a community where all the freshwater is coming from desalination, because not all of the freshwater goes into the sewage system, but it might be workable in communities where desalination is augmenting other sources of freshwater.
Re:Why Is Desalination So Difficult? by kibwen on Wednesday July 05, 2023 @03:07PM (#36605510)
> But, why not really-long-pipe-with-small-holes-along-the-length?

The OP mentions that this is common in practice, although it's easier to tell in the video that this is what is being described.

Re:Why Is Desalination So Difficult? by emodendroket on Wednesday July 05, 2023 @02:43PM (#36605145)
It’s full of contaminants from the process that make it unsuitable for a lot of uses, as I understand.
Re:Why Is Desalination So Difficult? by tivert on Wednesday July 05, 2023 @02:46PM (#36605186)
> I've heard that this brine is toxic. Does this make disposal an issue? Is the toxicity true or hyperbole? I mean, do we know how bad it is, and if we can do anything safely with it? It seems like "salt" is useful in a lot of contexts, including industrial, so can we do something with the brine besides disposing it somewhere?

Too much salt can kill stuff (e.g. people, plants), so I suppose that makes it "toxic." Maybe there's a tiny amount old industrial pollution from anywhere an everywhere that concentrated in there, too.

However, if you're desalinating seawater, what's the problem with just dumping the brine back in the sea? Unless you introduced new stuff into it during the desalination process, you wouldn't be making anything worse.

Re:Why Is Desalination So Difficult? by jerf on Wednesday July 05, 2023 @02:52PM (#36605301)
There are several practical problems dumping the brine back in the sea.

If you dump it on a living ecosystem you tend to kill it. Living ecosystems are, unfortunately, concentrated right where we are desalinating and is cheap to dump.

Compounding this problem is that water mixes much more slowly than your intuition suggests. It can stay a coherent mass of high-salt water way longer than you'd think, killing as it goes. This is one of the more surprising things I've learned in the past few years, honestly. Your kitchen-scale-based intuition of how long it takes for liquids of different characteristics to blend together turns out to be way off.

Trying to pipe it away to somewhere where it is less of a problem is expensive.

In the long term just dropping it back into the ocean is not a big deal, but that short term is surprisingly destructive. You'd think you could just drop it in and maybe a few hundred feet from the outlet it would be all dissipated and harmless, but unfortunately the physics don't work out that way.

Re:Why Is Desalination So Difficult? by scythe on Wednesday July 05, 2023 @03:24PM (#36605765)
The "clever" version I've seen in some papers is to use reverse electrodialysis to recover energy as you dilute the waste brine with seawater. AFAIK, this has not been incorporated into any existing installations.
Re:Why Is Desalination So Difficult? by margalabargala on Wednesday July 05, 2023 @04:14PM (#36606422)
> water mixes much more slowly than your intuition suggests

As a visceral example of this in the other direction, the freshwater plume of the Amazon River extends more than 60km into the ocean. [0]

I would love to see these plants placed in areas where there's a nearby dry below-sea-level basin, into which the brine may be discharged. The Salton Sea in CA is one example, there's another similar location in Egypt I'm aware of. The advantage of such locations is they are usually extremely hot and arid, which means there's generally not much of a local ecosystem or human population, and there is ample solar power availability.

[0] https://eos.org/science-updates/the-amazon-rivers-ecosystem-...

Re:Why Is Desalination So Difficult? by AnimalMuppet on Wednesday July 05, 2023 @05:04PM (#36607096)
The Salton Sea is over a hundred miles from the ocean, though, with at least one mountain range in the way. It might be a good dumping ground (or maybe not - there at least were fish in it, if there still are, this would almost certainly kill them). But it would definitely take a lot of energy to pump the water there.
Re:Why Is Desalination So Difficult? by cyanydeez on Wednesday July 05, 2023 @06:09PM (#36607870)
Great movie: Salton Sea
Re:Why Is Desalination So Difficult? by margalabargala on Thursday July 06, 2023 @01:54AM (#36611837)
It would take one mildly expensive tunnel. As a bonus, you might be able to put hydro turbines on it, if they can handle the salt.

The Salton Sea's salinity is already well over that of the ocean (44g per liter compared to 35), and is getting saltier. Considering that the very existence of the Salton Sea is already an ecological disaster, I don't really see dumping salt into it to be another one.

The Salton Sea is 70 miles from the Pacific Ocean. If this were built, it would be only the third longest water tunnel in the world, and second in the US.

Re:Why Is Desalination So Difficult? by avar on Thursday July 06, 2023 @11:40AM (#36617722)
> the freshwater plume of the Amazon River extends more than 60km into the ocean.

It really doesn't, or perhaps only in the most pedantic sense.

That "ocean" is still the mouth of the Amazon itself, and most of it's less than 10 meters deep. It's really the estuary of the river itself. See: https://www.frontiersin.org/articles/10.3389/fmars.2017.0002...

Re:Why Is Desalination So Difficult? by bjelkeman-again on Wednesday July 05, 2023 @04:17PM (#36606460)
The extreme volumes produced in the Arabian Gulf is subject to a lot of studies (some plants produce one million m2 per day). This does cause issues. An in-depth look at possible futures can be found here.

http://essay.utwente.nl/79579/1/Dols%2C%20F.J.%201862227%20_...

Re:Why Is Desalination So Difficult? by Robotbeat on Wednesday July 05, 2023 @04:49PM (#36606882)
> If you dump it on a living ecosystem you tend to kill it.

This is false and somewhat dishonest. This is simply a choice of not diluting it enough. There is nothing about the discharge from reverse osmosis that is any more fundamentally toxic than the natural process of evaporation.

Proper dilution is essential, and treating the discharge as fundamentally toxic actually undermines the engineering to do this proper dilution because people will figure “oh well, I guess there’s nothing we can do as it’s going to tend to kill no matter what.”

People need to stop misleading about discharge toxicity.

Re:Why Is Desalination So Difficult? by schiffern on Wednesday July 05, 2023 @05:32PM (#36607464)
>This is simply a choice of not diluting it enough.

If that choice were up to engineers, it's fine.

In practice that choice is actually made by MBA types, a field where harmful short-termism is almost a religion.

Re:Why Is Desalination So Difficult? by cyanydeez on Wednesday July 05, 2023 @06:13PM (#36607921)
It's made by practical money and people who don't want to consume local resources.
Re:Why Is Desalination So Difficult? by cyanydeez on Wednesday July 05, 2023 @06:12PM (#36607913)
This is dishonest: toxicity, dosage are fundamental properties.

You can't just wave a word at it like dilution and think you're solving an engineering problem.

If you got 1 gallon out of sea water, what do you think you need to dilute it to be safe? Typically, it's 99%∆.

Re:Why Is Desalination So Difficult? by xyzzyz on Wednesday July 05, 2023 @09:17PM (#36609645)
You don’t need to dilute a gallon of sea water at all, it is perfectly safe to dump it back into sea as is.
Re:Why Is Desalination So Difficult? by cyanydeez on Wednesday July 05, 2023 @10:01PM (#36610039)
For you, locally, sure.

It'll kill however, plenty of things.

Re:Why Is Desalination So Difficult? by Robotbeat on Wednesday July 05, 2023 @10:04PM (#36610072)
It won't kill anything. The surface of the ocean has natural fluctuations of salinity all the time due to evaporation, and it doesn't cause mass die offs. It's literally a necessary part of the ecosystem (and in fact discharging freshwater can cause problems to the ecosystem). But if your discharged water is within the natural 30 to 40 grams of salt per liter range, there's no ecological problem here.
Re:Why Is Desalination So Difficult? by Robotbeat on Wednesday July 05, 2023 @10:08PM (#36610112)
It's not waving a word around. There's natural variations of salinity of oceanwater, roughly 30 to 40 grams of salt per liter. So diluting the discharged brine so it's within that natural evaporation-driven band would be perfectly safe as it's in the natural variation of salinity.
Re:Why Is Desalination So Difficult? by grogenaut on Wednesday July 05, 2023 @02:50PM (#36605240)
Because the brine is hyper-salty compared to ocean water and takes a while to mix back in, essentially creating a new ecosystem, brackish, where the outlets are.

What's wrong with pumping 10% CO2 into your office constantly from a compressed gas plant extracting oxygen and argon next door?

Re:Why Is Desalination So Difficult? by tivert on Wednesday July 05, 2023 @02:55PM (#36605336)
> Because the brine is hyper-salty compared to ocean water and takes a while to mix back in, essentially creating a new ecosystem, brackish, where the outlets are.

How large would those brackish areas near the outlets be? It seems to be that would be a big problem in an enclosed bay, but much less so on a shore facing open ocean.

Could they run pipes out a few kilometers with small, regular holes (maybe some modification of oil pipeline technology) to spread the discharge out and mitigate the concentration problem?

Could they make the waste output less concentrated? Maybe by either running the desalination process less (would that also increase energy efficiency?) or by pre-mixing the waste with some un-desalinated intake water?

Re:Why Is Desalination So Difficult? by rtkwe on Wednesday July 05, 2023 @03:37PM (#36605954)
The pipe with many holes is one of the solutions used today it's just imperfect and requires a lot of pipe to make sure the waste output isn't too concentrated in a single area.
Re:Why Is Desalination So Difficult? by mr_toad on Wednesday July 05, 2023 @07:37PM (#36608782)
Even normal seawater has toxic concentrations of salt:

“seawater's sodium concentration is above the kidney's maximum concentrating ability. Eventually the blood's sodium concentration rises to toxic levels, removing water from cells and interfering with nerve conduction, ultimately producing a fatal seizure and cardiac arrhythmia.”

https://en.wikipedia.org/wiki/Salt_poisoning