The number of times I've tried to get friends to make orders on DNMs over the years with no success. If I'd just passed them a Telegram username and told them to download the app they'd have done it there and then.
I ask because… if this is something a lot of people do, then it must either be really simple or there are howtos on youtube/quora/… and I can't find any howto.
It's not complicated at all
You wrote that GP "heavily underestimate DN markets by service and volume". If those markets can't be found using mass-market search engines and don't accept payment using mass-market payment services, then I think they're either nïche or you need to explain how they reached large volume.
A crypto wallet, that connects to one of those multi Billion Dollar networks, very well could be viewed as 'mass market payment service'. I at least know more people using crypto than PayPal, most no 'hackers'.
I heavily doubt that and think you heavily underestimate DN markets by service and volume. We live in crazy times, that's sure.