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Re:Dutch brewery burns iron as a clean, recyclable fuel by bencollier49 on Thursday November 05, 2020 @02:52AM (#24996402)
Interesting - essentially the iron is oxidised to release energy, then deoxidised using renewable energy. So it's another way of buffering renewable energy, which doesn't require a large body of water to store it. I'd be interested to know the overall efficiency of the process, but it sounds great - on the surface.
Re:Dutch brewery burns iron as a clean, recyclable fuel by bisRepetita on Thursday November 05, 2020 @03:08AM (#24996467)
>I'd be interested to know the overall efficiency of the process,

From the article:

"High-efficiency electrolysis of iron oxide can store as much as 80 percent of your input energy in the iron fuel"

"Using this kind of cyclical process to generate electricity could approach a theoretical efficiency around 40 percent"

Re:Dutch brewery burns iron as a clean, recyclable fuel by jillesvangurp on Thursday November 05, 2020 @03:46AM (#24996623)
Not bad; of course there is also the energy cost related to moving the material around. Iron is kind of heavy. If you are doing the electrolysis on site that's probably not a big factor. But if we're talking about converting coal plants (which the article does), presumably the electrolysis would happen elsewhere; which means tons of iron needs to be moved back and forth.

Moving fuel around is also a problem with coal and oil. We're basically burning fossil fuels to move fossil fuels around. In the case of oil, we than also have to run it through energy intensive processes to turn it into more palatable fuels than bunker oil, which is what is typically used for shipping things around.

A typical oil tanker consumes a couple of hundreds of tons of bunker fuel per day to move a couple of thousands of tons of fuel around. So, that's a sizable percentage of its load that is lost just to get the raw product from A to B. I'm sure the math is similar for producing and moving coal around.

It only makes sense if you get to pollute at will without financial consequences; which happens to be the case with shipping, which mostly takes place in international waters without any constraints or regulations on the amount of crap put in our atmosphere.

Ships actually switch to cleaner fuels when they get close to populated areas because otherwise they'd end up killing some of the locals with their fumes. Bunker fuel is nasty. Even more so than coal.

So, if we are debating efficiencies, we'd do well to apply the same scrutiny to existing solutions as well. The efficiency of coal should also include digging it up using diesel burning heavy duty equipment, moving it around, etc. I'd bet that knocks some percentage points of even the most efficient plants or ICE cars.

Re:Dutch brewery burns iron as a clean, recyclable fuel by socialdemocrat on Thursday November 05, 2020 @10:45AM (#24999203)
It is easy to get too hung up on efficiency though. Overall cost matters more. If a solar plus metal powder solution gives the same reliable power as a solar plus battery solution at lower cost then that will often be a superior solution, even if it requires more solar panels.

Efficiency matters when you run out of space or resources. But you got vast areas like Sahara where solar power production could be combined with metal production. Wasting space in Sahara is a non-issue if it means you get the overall cost of system down.

Re:Dutch brewery burns iron as a clean, recyclable fuel by ximeng on Thursday November 05, 2020 @05:30AM (#24997084)
https://www.hellenicshippingnews.com/how-many-gallons-of-fue...

This article suggests at top speed Panamax tankers carry 1.5-2mn gallons of fuel while burning 63,000 gallons per day (i.e. around 3-4% of capacity) at top speed.

That is considerably less than the 10% (200 tons to move 2,000 tons) that you suggest.

Also the article notes that reducing speed by 10% can reduce fuel use by a third. The tankers travel at 19mph, significantly less than their top speed of 23-28mph so fuel consumption is likely closer to 1%.

Re:Dutch brewery burns iron as a clean, recyclable fuel by jillesvangurp on Thursday November 05, 2020 @07:32AM (#24997667)
I was talking about the whole journey. You don't get anywhere in this world in less than a few days/weeks with a big oil tanker.
Re:Dutch brewery burns iron as a clean, recyclable fuel by nkurz on Thursday November 05, 2020 @08:20AM (#24997970)
> A typical oil tanker consumes a couple of hundreds of tons of bunker fuel per day to move a couple of thousands of tons of fuel around.

While it certainly makes sense to calculate for the entire journey, if you were talking about the "whole journey" why did you specify "per day"? It's hard to blame 'ximeng' for relying on your written comment rather than what you intended to say. :)

Re:Dutch brewery burns iron as a clean, recyclable fuel by kybernetikos on Thursday November 05, 2020 @09:05AM (#24998279)
Rust is heavier than the equivalent amount of pure iron, so perhaps it would be possible to put the furnace at the top of a hill and the refiner stage at the bottom and let the weight difference do the heavy lifting.
Re:Dutch brewery burns iron as a clean, recyclable fuel by ajnin on Thursday November 05, 2020 @12:07PM (#24999868)
Interesting idea. I wonder how much height difference you would need so that gravity gives you enough energy to power the regenerator at the bottom? The actual energy would come from ... the gravity field of the Earth?
Re:Dutch brewery burns iron as a clean, recyclable fuel by bluGill on Thursday November 05, 2020 @12:44PM (#25000213)
The energy comes from the mass of oxygen that is released at the bottom and captured at the top.

But second law of thermo dynamics applies. If this works at all it is because you are capturing a little more of the energy that was put in at the top and would otherwise be lost. You stil need to put in external energy to keep this system running.

Re:Dutch brewery burns iron as a clean, recyclable fuel by cma on Thursday November 05, 2020 @01:05PM (#25000438)
Shouldn't the needed energy increase the more the height difference? Seems it must be made up for in some other place too, or less waste heat at some stage.
Re:Dutch brewery burns iron as a clean, recyclable fuel by bluGill on Thursday November 05, 2020 @02:52PM (#25001328)
The energy out increases by the height level as well.

If the process was 100% reversible, and friction free (probably a couple other loss factors I forgot about) it would be energy positive as the oxygen is making its way back up in the air is an external energy input. Of course in the real world both assumptions are wrong by more than enough that you can never get this to work.

Re:Dutch brewery burns iron as a clean, recyclable fuel by kingnothing on Thursday November 05, 2020 @01:55PM (#25000840)
Go ahead and stick a generator in between to capture some of the energy of the rust "flow" moving downhill for extra efficiency.
Re:Dutch brewery burns iron as a clean, recyclable fuel by socialdemocrat on Thursday November 05, 2020 @10:47AM (#24999213)
Haha, love that solution!
Re:Dutch brewery burns iron as a clean, recyclable fuel by akie on Thursday November 05, 2020 @03:57AM (#24996669)
> But if we're talking about converting coal plants (which the article does), presumably the electrolysis would happen elsewhere; which means tons of iron needs to be moved back and forth.

You could build the infrastructure to do the electrolysis immediately next to the coal plant to solve this problem. If this technology takes off that's most likely what will happen anyway.

Re:Dutch brewery burns iron as a clean, recyclable fuel by eptcyka on Thursday November 05, 2020 @04:05AM (#24996702)
Generating electricity with iron as fuel would be suboptimal, that's like using electricity to turn co2 back into coal, and then using said coal to generate electricity again. Using iron in coal power plants would only male sense if transporting it from somewhere where IRS more efficient to produce iron is economically viable - say use solar in Spain to regenerate iron and then use it further up north where solar isn't as good.
Re:Dutch brewery burns iron as a clean, recyclable fuel by Ensorceled on Thursday November 05, 2020 @04:21AM (#24996765)
The problem being solved is the bursty nature of green energy, we are trying to store solar energy generated during the day for usage at night or store excess wind energy for still days.

We are not trying to transfer green energy to less windy/less sunny places, the grid can take care of that.

Re:Dutch brewery burns iron as a clean, recyclable fuel by fastball on Thursday November 05, 2020 @11:22AM (#24999502)
Right, but in that case you'll get way better efficiency out of pretty much any other proposed solution: gravity, momentum, battery solutions are all more efficient than this for storing energy from renewables.
Re:Dutch brewery burns iron as a clean, recyclable fuel by chongli on Friday November 06, 2020 @06:12AM (#25006775)
Yeah, or in the article’s case (where you’re brewing beer), you might as well use a solar furnace to boil water directly with sunlight. You’ll have a hard time beating that efficiency with other methods. If you have huge water storage tanks anyway then keeping the water hot overnight is not a problem either.
Re:Dutch brewery burns iron as a clean, recyclable fuel by wcarron on Thursday November 05, 2020 @06:10PM (#25003114)
Batteries are expensive. Iron is abundant and cheap, and these seem much less difficult/costly to build than to create a dam, for example.

It also seems like it can make use of existing infrastructure and save money there.

Re:Dutch brewery burns iron as a clean, recyclable fuel by fastball on Thursday November 05, 2020 @08:11PM (#25003876)
I don’t think the expense of other solutions justifies the abject inefficiency of this one though.
Re:Dutch brewery burns iron as a clean, recyclable fuel by pjc50 on Thursday November 05, 2020 @04:58AM (#24996933)
Seasonality of solar is huge in northern latitudes. Using iron to store energy for months is an interesting prospect, although it needs to be kept dry so you can't just leave big heaps of it outdoors.

At first glance it seems reasonably transportable, but I'm worried about how you prevent it rusting in the air. Maybe it would be useful to blend it with biodiesel for that purpose.

Re:Dutch brewery burns iron as a clean, recyclable fuel by ClumsyPilot on Thursday November 05, 2020 @09:25AM (#24998465)
Well, firstly we do store grain and sand and many other things in massive quantities.

But secondly, wind power makes a lot more sence in northern latitudes.

Re:Dutch brewery burns iron as a clean, recyclable fuel by maxerickson on Thursday November 05, 2020 @05:27AM (#24997070)
Limit the air exposure.

I imagine methane synthesis will beat some thinglike this out. Pipeline infrastructure exists, is convenient, etc.

Re:Dutch brewery burns iron as a clean, recyclable fuel by rocqua on Thursday November 05, 2020 @08:18AM (#24997959)
The advantages I see of this process are: Ease of storage, re-use of the coal plants, ease of fuel generation.

Methane seems nice for the re-use of gas fired plants. I do think its gaseous nature has more downsides than upsides on the other two factors. There's also a gas-leak hazard with methane that doesn't exist here.

If the capital requirements are low enough, I could see a 40% efficient energy battery for smoothing out peaks being nicer than more complicated storage schemes.

Re:Dutch brewery burns iron as a clean, recyclable fuel by maxerickson on Thursday November 05, 2020 @08:29AM (#24998035)
Chemical batteries will likely eat the smoothing market.

For fuel that can be transported, methane is a winner. In addition to the distribution infrastructure, there's an awful lot of residential use, with lots of appliances that don't need replacement.

Re:Dutch brewery burns iron as a clean, recyclable fuel by BlueTemplar on Thursday November 05, 2020 @06:15AM (#24997288)
Or maybe add some oils ?
Re:Dutch brewery burns iron as a clean, recyclable fuel by socialdemocrat on Thursday November 05, 2020 @10:51AM (#24999258)
Iron is here used as an energy storage system. That is the whole point. You store excess energy from wind and solar power e.g. in iron to use later.

Yes for short term batteries are better but for say seasonal storage or when power is generated far away from where it is used then metal is better.

Re:Dutch brewery burns iron as a clean, recyclable fuel by fastball on Thursday November 05, 2020 @11:20AM (#24999488)
This is still going to be less efficient than an actual battery though, right? I'm all for alternative renewable energy storage solutions, but this one seems pretty poor.
Re:Dutch brewery burns iron as a clean, recyclable fuel by R0b0t1 on Thursday November 05, 2020 @01:55PM (#25000837)
The principle can be effective, I've not seen anyone seriously consider iron however.
Re:Dutch brewery burns iron as a clean, recyclable fuel by socialdemocrat on Thursday November 05, 2020 @10:48AM (#24999229)
Yes, exactly as with coal. What is the problem with that? Railroad and ships are really efficient at moving large chunks of cargo cheaply.
Re:Dutch brewery burns iron as a clean, recyclable fuel by pishpash on Thursday November 05, 2020 @03:06AM (#24996463)
Not even close. Second law of thermodynamics puts a limit on heat engine. Gravity storage is not subject to such limit.

But it is a great idea to burn any fuel whose oxidized product is not a gas. The only reason why burning hydrocarbons is problematic is because carbon dioxide is a gas, otherwise it could be captured and recycled like this.

Re:Dutch brewery burns iron as a clean, recyclable fuel by stkdump on Thursday November 05, 2020 @03:50AM (#24996647)
Seems about right. Pumped storage is at about 70% efficiency round-trip, this is 40%. Also, not producing greenhouse gases sounds like a good idea.
Re:Dutch brewery burns iron as a clean, recyclable fuel by knolax on Thursday November 05, 2020 @04:46AM (#24996872)
Well I think in this case the iron is feeding a furnace so it's not going through a heat engine, it's just giving off heat.
Re:Dutch brewery burns iron as a clean, recyclable fuel by ncmncm on Thursday November 05, 2020 @11:08PM (#25004800)
Right, conversion of iron to rust yielding heat is 100% efficient, less only the work needed to move the rust out of the way.

If you wanted to convert that heat back to electricity, there would be losses, but nowhere near as much as some people are saying. 1800 degrees minus ambient is a very big delta T. You are not bound to a closed cycle, so Carnot does not apply. So it is likely 80+% would be achievable, maybe over 65% round trip.

Re:Dutch brewery burns iron as a clean, recyclable fuel by socialdemocrat on Thursday November 05, 2020 @11:14AM (#24999440)
Yes and anyway you could use combined heath and power systems to get higher efficiency.
Re:Dutch brewery burns iron as a clean, recyclable fuel by fastball on Thursday November 05, 2020 @11:24AM (#24999518)
Not sure I follow.
Re:Dutch brewery burns iron as a clean, recyclable fuel by hinkley on Thursday November 05, 2020 @01:24PM (#25000576)
Cogeneration. It's common in cogeneration for heat to be a secondary output that makes the overall system profitable, but isn't the primary output.
Re:Dutch brewery burns iron as a clean, recyclable fuel by fastball on Friday November 06, 2020 @11:00AM (#25008558)
But in this case heat is the primary output.
Re:Dutch brewery burns iron as a clean, recyclable fuel by Ensorceled on Thursday November 05, 2020 @04:26AM (#24996790)
Gravity storage IS subject to the same law, why do you believe it isn’t?

Burning hydrocarbons is problematic for a host of reasons besides CO2 release: fracking, oil spills, release of other pollutants, political issues with the supplier countries, pipelines, ...

Re:Dutch brewery burns iron as a clean, recyclable fuel by mikewarot on Thursday November 05, 2020 @04:51AM (#24996901)
Gravity storage converts work to potential energy, and back, efficiencies can be 90-almost 100%... heat engines at room temperature generally top out in the 35%ish range. Using the "waste" heat improves that, but nowhere close to 90%.
Re:Dutch brewery burns iron as a clean, recyclable fuel by thereisnospork on Thursday November 05, 2020 @04:30AM (#24996807)
Gravity storage is not a heat engine, ergo Carnot's rule does not apply.
Re:Dutch brewery burns iron as a clean, recyclable fuel by Ensorceled on Thursday November 05, 2020 @04:36AM (#24996829)
But the second law of thermodynamics still does. Gravity wells are still a mechanical system, just not a heat engine.
Re:Dutch brewery burns iron as a clean, recyclable fuel by thereisnospork on Thursday November 05, 2020 @04:49AM (#24996888)
>Not even close. Second law of thermodynamics puts a limit on heat engine. Gravity storage is not subject to such limit.

Emphasis mine. Don't be a pedant.

Re:Dutch brewery burns iron as a clean, recyclable fuel by Ensorceled on Thursday November 05, 2020 @09:58PM (#25004453)
Well, my important point was that hydrocarbons are fucking terrible but keep focusing on the first part.
Re:Dutch brewery burns iron as a clean, recyclable fuel by ClumsyPilot on Thursday November 05, 2020 @09:27AM (#24998507)
Laws of thermodynamics apply to the entire universe, ergo i dont think anyone is claiming to break laws of physics
Re:Dutch brewery burns iron as a clean, recyclable fuel by ergwwrt on Thursday November 05, 2020 @10:40AM (#24999149)
2nd law of t only applies to mass. Gravity works via gravitons which are massless so the 2nd does not apply..
Re:Dutch brewery burns iron as a clean, recyclable fuel by hinkley on Thursday November 05, 2020 @01:27PM (#25000605)
Because the Carnot limit is particularly pessimistic.

70% vs 40% is a big difference, especially when you consider it from the losses column instead of the wins column. If I gave you a system that was losing 30% of a resource to replace a system that lost 60%, you've cut your losses in half.

If I told you a mechanical system could get that to 15%, you'd replace that again. Anyone who tells you they can get a heat engine down to 15% losses is a charlatan and should be reported for fraud.

Re:Dutch brewery burns iron as a clean, recyclable fuel by hinkley on Thursday November 05, 2020 @01:21PM (#25000552)
I've seen designs for renewable energy storage that use gravity. These are often with water, but I've also seen designs using cranes and regenerative braking. I've seen designs like this that use load shedding for generating some useful feedstock material.

What I haven't seen is many people doing both at the same time. I might have seen a desal unit powered by green energy, which tops up the water towers when power is cheap, but not much beyond that.