According to Wikipedia [1], "in spherical geometry, angles are defined between great circles". Meridians are great circles, but parallels are not. Possibly the angle is simply not defined for circles that are not great circles?
Here's an example: https://www.desmos.com/calculator/is7mush1ma
The red and blue circles are both perpendicular to the green circle at the origin.
However, parallels, while smooth, are not straight, they "curl" toward the nearest pole (i.e., non-zero second derivative, relative to the earth's surface). This accounts for the non-"rectangular" shape of quadrangles and can be replicated on a 2D plane.
Take the lines tangent to the meridian & parallel at the point of intersection. Observe these lines are perpendicular. Hence the meridian & parallel meet at a right angle.
They certainly are. Parallels and meridians always meet at 90 degrees.
https://www.geogebra.org/m/kNtNZzsS