http://aurora.wells.edu/~srs/Math151-Fall02/Litdigest.htm
is a spectacular historical example of a voluntary response poll that didn't give a correct picture of reality at all.
"The median poll selection of a HN visitor who clicked on a poll which was on the front page on the following weekdays (and national holidays in the following countries:...) was..." etc.
If the information content is sufficiently hard to extract usefully that it would be easier to redo the sample in a sensible way, then you could call the sample worthless. (A bit like uneconomic oil reserves).
Of course, you'd have to figure out how to define "regular HN users" and what would be a significant portion of them.
If this poll were to get that much response, it would also tell you something interesting: that HN users respond to polls in statistically significant numbers :)
So, voluntary response polls are not worthless if enough people voluntarily respond to them, but this is a tricky problem.
No. If 50% of HN visitors voted but 99% of those over 40 didn't (due to whatever confounding factor you like - say embarrasment), you'd still wouldn't be able to extrapolate from the sample to the category of "HN visitors".
eg: a gender survey in the general population that transgender respondees do not answer -- ends up with a 99% sample size (all but the transgenders) -- and thus gives a pretty significant bit of data on male:female ratios, etc..
Agreed in principle though.