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Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by ordinaryradical on Tuesday August 01, 2023 @02:26PM (#36960230)
My father and his colleague developed a scalable process to manufacture Teflon without the use of PFAS back in the previous century; they had both been recruited heavily by DuPont which made it relatively easy to sell the patents, at which point they immediately disappeared and were never acted upon.

One of the interesting side effects of free markets is that when there are no consequences for mass poisoning / polluting, you will ignore opportunities to manufacture without doing so because there is often zero or negative economic consequences to change your process.

In DuPont’s case, it was more valuable in the near term for the shareholders to ignore this manufacturing innovation and not disrupt supply than to reconfigure with a new process. No doubt there were massive risks involved in trying a new process that made it a “safer” and wiser decision economically to continue to use PFAS.

I think about this every time someone tells us on HN how a freer market will solve our problems.

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by tredre3 on Tuesday August 01, 2023 @02:32PM (#36960332)
> My father and his colleague developed a scalable process to manufacture Teflon without the use of PFAS back in the previous century

How is that possible? PTFE (teflon) is itself a PFAS, no? Did they "only" get rid of other PFAS used during the manufacturing of teflon?

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by ordinaryradical on Tuesday August 01, 2023 @03:37PM (#36961482)
I just asked him.

“Teflon is a high molecular weight polymer made using perfluoronated surfactants. Technically, PTFE is a fluorine-containing material but it is not the PFAS pollutants of recent concern. In the conventional synthesis, the real source of PFAS pollution is primarily those surfactants used in its manufacture. Our process made the use of those surfactants unnecessary.”

Why do you DuPont never acted on your patents?

“It was a cost of business decision because they had already invested so much capital in making Teflon with those surfactants.”

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by OtherShrezzing on Tuesday August 01, 2023 @03:49PM (#36961663)
Is your dad forbidden from recreating this technology with DuPont in control of those patents? There's probably a tonne of VC money out there for an environmentally friendly disruptor to teflon.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by ordinaryradical on Tuesday August 01, 2023 @04:06PM (#36961918)
I’m going to link to another reply on this and provide some additional color:

https://news.ycombinator.com/item?id=36961328

Getting a product like this stood up is a $100 million endeavor at minimum. That’s before customer #1 presses “buy.”

My father and the colleague I mentioned are both successful serial entrepreneurs (large exits, Sequioa backed unicorn, etc.). There is close to zero appetite from VCs in this.

VCs seem to be allergic to these CapEx intensive businesses and I don’t blame them—the risks are enormous when compared to something like a SaaS.

That said, if you know someone who’s dying to throw hundreds of millions at this problem, he’d probably take the intro. You can email me at super solenoid theory at gmail dot com.

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by TylerE on Tuesday August 01, 2023 @05:52PM (#36963651)
On the other hand, the capital intensive nature makes it a lot harder for a competitor to spin up their version overnight and eat your lunch.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by gottorf on Tuesday August 01, 2023 @06:13PM (#36963916)
As pg said, "do things that don't scale".
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by OtherShrezzing on Wednesday August 02, 2023 @08:46AM (#36970136)
I think Carbon13 and the other "climate emergency" accelerators would be interested in some capacity, at least as a starter. They've got a fairly strong network of Family Houses & trusts.

I think you'd get seed money, and a network large enough to raise some serious capital in future rounds.

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by at_a_remove on Tuesday August 01, 2023 @04:06PM (#36961921)
One of my patent reform ideas is that patents must be used. If left fallow (production under a certain amount) for too long, bam, it hits the public domain, or back to the originator.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by mrguyorama on Tuesday August 01, 2023 @05:06PM (#36962920)
Or just make it a couple years. If you can't profit handsomely off your idea in a couple years, then it's probably more efficient for society as a whole to be allowed to work on it.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by TylerE on Tuesday August 01, 2023 @07:50PM (#36964930)
Ig you remove the incentive, why would they pay to do the research in the first place?

There is a gulf of value between "literal cure for cancer" and, like, some basic consumer good. Most things do not exist at either extreme end. Not all things worth doing are wildly profitable.

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by markdown on Tuesday August 01, 2023 @08:49PM (#36965455)
Huh? The incentive hasn't been removed. You only lose it if you aren't producing the patented product for commercial sale.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by TylerE on Tuesday August 01, 2023 @08:58PM (#36965553)
I'm talking about a hypothetical world where the lifetime of a patent is only, say, 5 years. That's a much shorter window to recoup expenses, and thus many projects that are financially justifiable in the current environment would not be.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by refurb on Tuesday August 01, 2023 @08:12PM (#36965132)
I'm pretty sure Teflon is made with tetrafluoroethylene, a gas, not with surfactants?
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by amluto on Wednesday August 02, 2023 @12:11PM (#36972865)
As I understand it (and I don’t claim to understand it all that well), the processing involved in turning tetrafluoroethylene into a useful form of PTFE involves the use of fluorinated surfactants to get everything into a solution or emulsion.
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by mandmandam on Tuesday August 01, 2023 @02:38PM (#36960418)
This remind me of the recent story here, about how tobacco companies knew that radioactive polonium in their tobacco leaves was causing an insane rate of lung cancer, killing 130 out of ever 1,000 smokers over 25 years. [0]

They even had a process to remove the radioactivity, but, it made the nicotine a little less addictive so they didn't do it. Instead, they kept marketing to children with cartoon characters for another 20+ years until forced to stop.

These same companies are still marketing cigarettes to kids where they can get away with it.

At some point we need to start talking about self defense from this shitty system. And I feel like that point was the 60's.

0 - https://news.ycombinator.com/item?id=36925019

Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by hedora on Tuesday August 01, 2023 @02:46PM (#36960538)
It's been long enough for the patents to expire, so why not help a competitor commercialize the technology? Do you have a reference to the patent number?
Re:Could the world go PFAS-free? Proposal to ban ‘forever ch... by ordinaryradical on Tuesday August 01, 2023 @03:29PM (#36961328)
This is no doubt correct. I’m almost certain they’ve expired, though I’m not going to include links here and associate my real name with my HN acct.

But the reason they haven’t been acted upon (that I know of) is that economic difficulty of making a competing Teflon has to do chiefly with issues of manufacturing scale and large up front capital expenditure. This is true across the entire chemicals industry for any new product. Rule of thumb costs were, the last I heard, roughly 100 Million in development to get a single product into baseline commercial viability.

Why compete against an established and “tainted” product like Teflon? Can you guarantee the PFAS free process is cheaper at any of the initial commercial scales you’re likely to achieve? Is there a market for an off-brand substitute?

These kinds of risks delimit innovation in physical manufacturing far more than the possession of IP.