So you need to be going at the speed of 2km/h. Well, that's actually not that bad for a postal service. It's assuming absolute optimal conditions, but energy usage is for a typical electric car.
I doubt it would be financially net positive or carbon negative, but the idea is not as crazy as I thought assuming final delivery in medium density sunny urban areas.
At current prices, my sense is that solar panels on vehicles are marketing, not materially contributing to the energy budget. Nothing wrong with that but I wouldn't like to spend my feature money on the option.
If you space them off the roof by about an inch, like the old Landrover "Safari" roof, it'll make a hell of a difference.
Assuming they are going to use roughly half that range or 34kWh per day a solar roof getting roughly 1/2 of an optimal 8 hours * 0.22kW/m^2 * ~11m2 ~= 9kWh per day, isn’t nothing but hardly enough on it’s own.
Where solar roofs might be beneficial is simply reducing the number of charge/discharge cycles on the battery. A hypothetical 25-50 fewer full charge discharge cycles per year could be a full battery replacement they avoid.