At current prices, my sense is that solar panels on vehicles are marketing, not materially contributing to the energy budget. Nothing wrong with that but I wouldn't like to spend my feature money on the option.
If you space them off the roof by about an inch, like the old Landrover "Safari" roof, it'll make a hell of a difference.
Assuming they are going to use roughly half that range or 34kWh per day a solar roof getting roughly 1/2 of an optimal 8 hours * 0.22kW/m^2 * ~11m2 ~= 9kWh per day, isn’t nothing but hardly enough on it’s own.
Where solar roofs might be beneficial is simply reducing the number of charge/discharge cycles on the battery. A hypothetical 25-50 fewer full charge discharge cycles per year could be a full battery replacement they avoid.
So you need to be going at the speed of 2km/h. Well, that's actually not that bad for a postal service. It's assuming absolute optimal conditions, but energy usage is for a typical electric car.
I doubt it would be financially net positive or carbon negative, but the idea is not as crazy as I thought assuming final delivery in medium density sunny urban areas.