The first step towards becoming more emotional will be naming them. I remember reading a couple of years ago about that cleaning robot Roomba, and how people started naming them, and when they were giving them away for repairing, they demanded the same robot back, not a replacement.
http://www.msnbc.msn.com/id/21102202/ns/technology_and_scien...
http://gizmodo.com/5483750/peoples-emotional-attachment-to-r...
A few years ago I was reading sort of a joke, that by 2050, Massachusetts will be the first state that will allow human-to-robot marriages.
There's already this:
If some countries that have capital punishment don't get civilized by the time we have human-level AI, then yes, that would be logical. There is no difference between a mind run on a biological brain and a silicon brain. Killing either is murder.
http://lifeartificial.com/
I think a far more interesting question is: will a human ever be put to death for "killing" an artificial intelligence?