With Postgres, you can always just have a JSONB column for data whose shape you're unsure of. Personally, I'd rather start with Postgres and dump data into there and retain the powers of RDBMS for the future, rather than the other way around and end up finding out that I really would like to have features that come out of the box with relational databases.

I think a valid reason for not choosing a relational database is if your business plan requires that you grow to be a $100B+ company with hundreds of millions of users. Otherwise, you will probably be fine with RDBMS, even if it will require some optimizing in the future.