Use company e-mail addresses to register for everything. Enforce it for your employees. This is in the interest of both the company and the employee. Yes, the summer intern gets a corp email too, which at minimum gets access to internal resources beyond the OT chatroom revoked when they are out.
(Your advise is not bad though: grant granular access as it's needed)
But yes, my point of not mixing accounts does go that far - if you don't have separate hardware, at least use separate browsers or browser profiles.
Don't put the cookies in the same jar.
Easier said than done, in my experience. Years ago I had to log into my Company's Play account on my computer for some specific reason, one time, and more than a year after that, my daughter purchased a game on my android phone and the CEO sent me a message saying "FYI, we just paid $3 for a princess coloring book app, please enjoy it with our compliments but please delete the Play Store login info from your devices." I still have zero idea how that could possibly have happened. That company will be shutting down and now I'm worried that my google account is somehow "linked" to it.
As mentioned in a sibling comment: Utilize browser profiles (Chromium-based/Firefox) or Multi-Account Containers (Firefox).
This is probably "best" practice, but Google has randomly closed accounts for our mobile test devices. They're only used to run our (non-shady) apps on a single device that is never used with other accounts.
Give access to as few employees as possible, and have all access to Google Play go through a designated, trusted release manager or "play account manager"? And don't log in to Google Play from random browsers and IP addresses which could create an association with other Google accounts?