The other big example is the rapid extinction of all that tasty, tasty megafauna.
https://news.utexas.edu/2015/09/03/clues-from-ancient-maya-r...
So saying "their practices were relatively scalable, since they were at a small scale" sounds wrong, which is why I think you are being downvoted.
Same way "I use gas to drive my truck" isn't sustainable, even if I'm the only one with a truck. The practice isn't sustainable, even if emissions from one person might not have a large impact.
Maybe if it was more like "if everyone in similar circumstances lived this kind of lifestyle".
If a forest can safely supply 1000 trees a year, and a certain lifestyle has 300 people depend on that forest and each use two trees per year, then that's sustainable. It doesn't matter that 3000 people per forest wouldn't work. And if a million people all live this way, then they're splitting three thousand forests, so that's fine too.
It's not reasonable to worry about infinite population density, because then nothing is sustainable. And prehistoric practices weren't using up fossil fuels; trees grow back if you let them.
Though even the sustainability of gas is more complicated than "it's not". As far as CO2 goes, there is an amount that could be safely released per year. And if we were at that level, oil reserves would last a long time.
First, on a regional level, civilizations could heavily deforest their surrounding ecosystem to the point of devastating it and themselves with long-term consequences. A couple examples are the Romans, pre-modern Britain and of course, the Maya.
Secondly, the productive practices of pre-modern times were far less efficient in many ways than they are today, meaning not only heavy dependence on forest or at least wood resources, but also a much more impactful destruction of forest land for needs that in many societies today are handled without resotrting to wood.
Increase in efficiency directly leads to increased consumption: