I hate it to say it, but for CS beginners python.org isn't a good resource: it's simply too technical. Even for motivated students it will take them at least a few months of learning from a more beginner-friendly resource before the official docs on python.org make sense.

That's not to mention the multitude of other materials on python.org other than the docs, like PEPs, pypi (third party libraries), bug reports, etc. Can you imagine a student searching for how to use a Python feature, but found a PEP illustrating the design of that language feature?