Having entire days off is so much more freedom than having two extra hours in the evening. Three day weekend every weekend means me and my girlfriend could go on little escapes more frequently.
Yeah, as a programmer I often don't program 8 hours a day and when I do it is wildly exhausting. I still absolutely work for 8 hours a day, most days.
In most jobs, you don't have to work all the time while you're on the job - and most people take copious advantage of that.
* long commute
* kids, depending on their age: shorter work days to be around when they're not at school, or shorter work week to spend one more day with your baby instead of leaving it at day care
* whether you count your working time: 4-day workweek means nobody expects you to be there one day per week, expectations are less clear with a reduced-time 5-day workweek
* what you do in your free-time, compare hiking weekends vs going to bars and restaurants
Obviously, the best alternative is to be able to choose depending on your personal plans for the week!