Straw man [1]. The Coast Guard would be expected to deter, ticket and, in the most extreme circumstances, disable craft.
MMH is not vented on landing. When it’s released, it’s because of a mistake. That’s why the approaching crew take the precautions they do, and don a gas mask when toying with the craft.
Nothing bad happened to these boaters. But they were downwind from a substance which, had it leaked, would have put every one of them in the hospital and taken decades off their lives.
Even though you're flip-flopping (in the same paragraph) about whether there was a dangerous condition, you do seem to concede that shooting people is not the way to rescue them. So, you're ahead of most USA national security experts.
Hanging out a bit longer meant staying inside the capsule longer instead of seeing a doctor sooner to avoid exposing themselves and more of the crew to those fumes. They were at 2.5ppm if I recall the radio chatter correctly.