Such as,
Dune Pro: https://www.dunecase.com/ InWin lines: https://www.in-win.com/en/gaming-chassis/z-tower/ Lian Li, Cases that are desks, and other high end designs: http://www.lian-li.com/
If you have money, you will find people looking to sell you high end cases.
I personally use Fractal Design cases, they look good, made of thick steel, and are cheap enough I can replace them more often without feeling bad.
The on button is just two copper wires that need to make contact in order to boot the computer. You can use any old button from a store or make one yourself, or use a wireless one if your computer is really far away. The USB hub's case can be removed, and if you use the motherboard's internal audio chip you can find ready to use AUX extending cables for nothing.
Of course if you don't want to make a custom IO box you can just use a regular USB hub and a remote.
Or the ECC RAM? Or the insane I/O with four thunderbolt 3 ports?
I find that people often don't compare Macs spec for spec. They just pick and choose the specs that they care about which isn't a great comparison. However this also speaks to the freedom of PC building - you can pay for only what you need.
I find people often hold one thing from the iMac that's not really relevant as justifying a whole laundry list of failings.
I'm including my screen in the price of my build, I have ECC ram and two GPUs and I'm still a fraction of the base model price and outperforming it.
Got a shockingly powerful machine for the price it cost me, still less than if I'd got an iMac Pro and dual GPUs for Octane Render and 2TB SSD.
What I'm really itching for is a high quality case, there seems to be a ton of premium options for SFF builds but close to zero in ATX or mATX my preferred factor[1]. I'm currently running in a Fractal Define Mini-C which does look ok but still a bit plasticy if I'm going to have a large box in my house I'd honestly by happy paying upwards of $500+ for a premium case if I liked the look of it and it was all quality and looked sophisticated.
Probably sounds crazy saying that to most PC builders but at the sort of size a PC is at it's almost a piece of furniture so I'd like it to look good.
[0]: It was clear the Mac Pro was dead at that point and todays Mac Pro was only a response to the markets response to the iMac Pro. [1]: Only one I can name is the Cerberus https://www.sliger.com/products/cases/cerberus_x/ which looks great but has niche build requirements.