Speech is the process of communication ideas. Porn is the process of sexually arousing someone remotely. Criminalizing the latter is not criminalizing the former.
A HD-DVD master key is one thing, a huge binary file is another. HD-DVD master key requires specific "numberness" to work, while a binary file can still convey similar information yet be a completely different set of numbers. if I take two pictures in rapid succession of a still life, the two pictures' jpeg data and checksum hashes aren't going to be even close to matching.
However, that’s a very narrowly scoped restriction (and it’s also not clear that such distribution is a type of “speech”). A more appropriate question would be: would Chomsky support free speech for an advocacy group such as NAMBLA, or for creating mangas that depict drawings similar to CP? Those are exactly the type of speech/expression that are clearly vile, yet should still be protected from interference by state violence, from the civil-libertarian perspective.