We figured out this doesn't work in the 19th century.
Reserves don't remove volatility, they just hides it. This is how banks work. And like a bank, a system of keeping "enormous capital" on the sidelines, ready to buy, works 90% of the time. When it doesn't, however, when people fear "enormous" is not enormous enough, they withdraw (i.e. sell), which prompts more selling, until eventually, since "enormous" isn't 100%, the buck breaks and the cards come crashing down.
Also people like to steal the "enormous capital," which is why we have regulations.
Could you give some pointers for further reading on the subject please?
For other history on synthetic assets, read Preston's posts and also Vitalik's posts such as https://blog.ethereum.org/2014/03/28/schellingcoin-a-minimal...
For ether, such overcollateralization isn't a problem, because you can package it as an ether derivative and have no counterparty risk... But for a gold collateral you would have a risk that cannot be mitigated in this way and the risk will need to increase the slippage of the asset.
If wanting to read from my parent comment: https://news.ycombinator.com/item?id=16851187
Want do you have in mind?
This is basically the BTC Tether model, except hopefully some anchors will step up that can actually complete an audit without breaking up with their auditors.
I'm not all that convinced that it will be possible to create a stable synthetic blockchain asset without either explicitly pegging to fiat (a la Stellar) or having a big and diverse enough slice of GDP flowing through the system so that speculative activities are a minority of transaction volume.
I think sustainable synthetic blockchain assets are possible, but they will always have complicated risk/reward profiles that won't fully mirror the underlying asset they are designed to model: The dream of a truly "synthetic dollar" will always remain a dream.
EDIT: I should clarify that I think DAI coin may still be a useful construct for some situations, but it's going to be an asset with very different properties compared to any target real-world asset.