The problem is that most startups can't match, much less beat, established companies on salary, and they'll just turn you down. It's not even malice or greed on their part, it's just that they have a finite runway and a few tens of thousands of dollars a year on a single person can mean the difference between life and death.
No one wants to say it out loud, but I'm starting to think that the startup economy requires people to accept the gamble of shit salary for a chance at the equity lottery. I decided not to play along with that and only work for megacorps, but it's up to each individual.
Eh, lots of people say exactly this out loud. People who accept that gamble jsut like to pretend their chances are higher than they are and/or it's worth it for the work experience.
The feeling of working for a company that will make a dent in the world, so to speak, and that your effort will have tangibly supported creation of said dent is a powerful motivator.
If by, so to speak, you mean that some dents are bigger than others -- sure... contributing to a small startup that makes some people a decent amount of money and the rest practically nothing... sounds great. Turns out the bigger the exit the less the rest of the people make and the more a small group of people do. Of all the companies big and small that are started around the globe each day, how many have "made a dent in the world?"
It may as well be zero.
If you cannot be motivated internally you're not going to find it very satisfying to continue taking risks working for (or starting) startups. When the first one fails, and the next few, and you never end up making that dent... you're going to be very disappointed.
You can use that same internal motivation at a big-corp as you can working for a start up. Or anywhere else in life.
You ask for a megacorp salary and you'll be laughed out the door.
So if you go to work for a startup, you should demand substantially more money than with an established company.
It didn't used to be that way. It used to be that the first dozen or so employees of a successful startup did very well, and the first hundred or so did OK.