https://www.amazon.com/Kingston-HyperX-Predator-SHPM2280P2H-...
I would suggest this card, it should work, it is SATA based as opposed to NVMe. I have installed a few of these in on several older systems (x58 based and others) and saw a very large performance bump, even versus SSDs connected via aftermarket PCIE SATA-3 controller (running at 500-550mbs). YMMV if attempting to clone an existing drive - I have had this problem with add-in PCIE cards, older motherboards, and various operating systems - a fresh install to one of these drives will likely be easier.
I see that folks are putting nvme cards into their older mac pros:
https://forums.macrumors.com/threads/pcie-m-2-nvme-on-macpro...
Is there a recipe that allows one to boot from an nvme add-in card on an older mac pro ? (in my case, early 2009)