Also, FB for Work has the biggest advantage from an Enterprise Software ever: they've already pre-trained 2 billion of the world's population on how to use it via the consumer version. Why not take advantage of that?
To further your point, I think Facebook's timeline dynamic complements Slack quite nicely. Slack is great for broad, real-time communication, whereas Facebook posts can be much more hyper-focused and the conversation can revolve around the specific topic over a long period of time.
For example, we have a development channel in our Slack. I can go back and browse through the chat log, but it's awkward to contribute a suggestion or thought to a conversation that happened yesterday. Everyone has moved on. Not the case on FB.
Slack _could_ try to tackle this, but I feel like it would need to be a different format than the chat room and it would be moving away from their strength.
I imagine Facebook for Work would happily fill a very similar role to Yammer, sitting comfortably alongside chat. Of course, they'll probably have a much easier time with distribution given the brand recognition.
I'm curious though, what aspects of it do you usually hear people complaining about?