It seems important to note the difference because I don't find it hard to imagine how a person whose motivation is to help the public good might not be passionate about a job which doesn't inherently do "good".
I suspect that as far as Bill Gates is concerned, he considers it all a game and just wants to win. For the first half of his life, the game was maximizing the money he makes. For the second half of his life, the game was maximizing the money he donates. This is all just suspicion, though.
Plenty of rich people, after spending their lives in business, eventually switch to philanthropy. Presumably because they discover, like the OP, that they value doing something more meaningful than stacking up money. But that's entirely different than somebody who has that realization young and does corporate stuff as a way of extracting cash, which is what alwaysdoit was suggesting.
I also know a number of folks at Google who are very charitably active despite working big-corp jobs. Usually they compartmentalize very drastically, though, so I never heard about their charitable activities at work and only learned about them second-hand, through chance encounters with mutual acquaintances.