No need to limit things to POSIX compatibility, but merely achieving it is no mean feat — and POSIX is seriously C-oriented. Some people invent a new OS architecture, then implement POSIX on the top of it (see NT) — but this is an order of magnitude harder, I suppose.
When you implement a POSIX-compliant OS, you suddenly have a lot of ready-made open-source software that both serves its primary purpose and as an "integration test suite". For a new OS, you have to write most basic userland things yourself. This is again a lot of effort.
Given its open nature, there's no reason (except limits of time/skill) someone writing an OS in Rust couldn't also be advancing Rust and its libraries in the directions needed to support that effort, even if they are outside of Mozilla.
I won't mind to be a billionaire with superhuman abilities and unlimited lifespan, too! Unfortunately, we mere mortals often have to limit the scope of our endeavors somehow.
Was C ready when Ritchie & Thompson wrote Unix with it?
> For a POSIX-compatible operating system, more exotic choices are probably not available
Why limit to POSIX compatibility?