XO Vasily Arkhipov, who had also been XO on the infamous K-19, was the only officer to oppose launching the sub's nuclear payload, and since launch required positive agreement from the Captain, XO and political officer, Arkhipov literally stopped World War Three by himself.
There's a quote from The Last Sentry[1] regarding this:
"On major combatant vessels, the political officer was third in command, following the captain and his starpom (short for stariy pomoshnik, or senior assistant), who was the equivalent of an executive officer in the U.S. Navy. The zampolit was required to qualify as an underway watch officer like any other officer on the ship and so had to have some operational competence."
I'm pretty sure that training and working with the regular crew would weaken the dedication to "The Party" over time.
[1]: https://books.google.com.au/books?id=pThlAgAAQBAJ&lpg=PT15&o...
[1]: http://en.wikipedia.org/wiki/Stanislav_Petrov [2]: http://en.wikipedia.org/wiki/1983_Soviet_nuclear_false_alarm...
Some years after the incident, Petrov told he believed that the system at his station was showing a false alarm and wanted to wait for a confirmation from other stations. He is cited with not wanting to sting a bee-hive.
After being introduced the information present at the other stations (most if not all were seeing the same false-alarm) he told the interviewer that if he would have had this "information" at the time of the incident he'd probably decided otherwise.
There must be a mountain of research into false positives of launches and more false positives than we know. After the fall of the USSR we found that that this happened practically regularly. I believe the Soviets saw the Able Archer exercises in 1983 as a potential attack and even detected missile launches. We also found out that Castro was ready to start nuclear war until his Soviet masters explained to him what that really means.
This is also why nuclear launch approval tends to be from the head of state only, instead of an automated process or via lower level delegates.
edit - point being that, at least in this case, in 1983, it contradicts the claim in the article that these "systems aren't centralized", and "requires a lot more activity, spread out across a vast geographical area". I'm sure it's better in current times.
*edit - oh, I thought he had the power to launch himself - I guess it changes slightly if his job was only "to report" up the chain of command.