A linear regression on the volatility line is clearly going down:
http://btcmag.9wizards.netdna-cdn.com/wp-content/uploads/201...
(Tried Chaikin Volatility, Donchian Channel, ATR, and Bollinger Band)
Chaikin Volatility goes down imho. I do not really know what the others mean. Are they adjusted for volume?
The others largely measure average price spread using slightly different means from each other.
By tweaking some settings, the network could easily be scaled to many times that.
If it ever became an issue (read: the network started to consistently max out the TPS limit), the ceiling would be lifted. If that wasn't sufficient, effort would be put into making the network more efficient. If that wasn't enough, more creative solutions would come into play (offline transaction systems, systems built to manage BTC outside of the blockchain [see CoinKite], etc).
Volatility IS DECREASING over time, as the economy and volume/market depth on exchanges are increasing. This has been explained many times on HN.