You can start by reading "Starting Strength" by Mark Rippetoe. If you don't feel confident that your form is correct, you can join a forum like the one over at stronglifts.com. They will probably be happy to review a video of you doing the lifts to let you know if you're doing things right or wrong (and what to fix, if it's not right).
Although, if you can swing it, I'd recommend finding a trainer to start you off.
Having said that, spending 1 hour a day fixing your problem won't be enough when you're spending the other 23 hours undoing it. Sit up straight or do as I did and get a stand-up desk.
I would recommend this series of articles to understand the theory behind bad posture and how to fix it.
http://www.t-nation.com/free_online_article/sports_body_trai...
I would spend at least 2 months just improving your joint mobility (especially hip + ankle) before attempting deadlifts. And even then you should really have someone who knows how to do them correctly to coach you.
Else you'll seriously hurt yourself.
Enjoy the fact that you have a mechanical advantage in cycling when you're feeling lame for not going as deep.
worked for me.