It also seems like a good way to divide people by their scale. You want a metric that means something to a customer, and one that they will bump into eventually.
What you could do to add value to the upper plans, is also offer hourly scans/on-demand scans/scans invokable by an API for the big customers.
Would you segment the number of pages differently? I think some sites with a lot of user generated content might actually have a ton of pages. But it is hard to get real numbers.
(I think he searches for mentions of his username, so the bat signal is officially turned on :-)
After I have ten customers, I will have much more information to base my prices and differentiators on.
Other ideas might be a service level guarantee for the high priced plans. And included email support for setup.
Most people probably don't have that many pages so I'm thinking the existing pricing tiers might not work well?
And maybe offer a free plan that only crawls your site 3x per year or something really slow like that.