"a la carte access either to HBO Go or to individual episodes of GoT as they're released" and
"access to episodes of GoT as they're released only via a subscription to a pay TV service with HBO".
The latter business strategy demonstrably works for HBO today. The former strategy is not only unproven, but based on the math, unlikely to succeed.
Due to historical circumstance, the content providers are stuck on the bundling strategy. Consumers seem to prefer a la carte. Any startup that tries to deliver what consumers want, given established providers and the economic theory, is going to fail.
A la carte providers just can't compete in the exclusive bidding war yet and the value of exclusivity is worth more than the incremental revenue of a la carte sales. There will be a point at which cable penetration could be small enough that these effects change but it has a long way to fall before it gets there. In the UK Sky has massive amounts of top class exclusive content on under 50% household penetration and they are still growing and strengthening their position.
This depends on how risk averse one is. I personally would be afraid of getting on hit list for the movie association (can't remember the acronym now).