Re:An open-source flow battery kit
by danielfp248 on Wednesday August 14, 2024 @10:11AM
(#41246297)
I am the author of the blog (chemisting.com), working on the project with Kirk and Josh.
The Coulomb efficiency of a device with a microporous, non-selective membrane depends fundamentally on how fast you charge/discharge it, as the device self-discharges while it runs. The faster you charge/discharge, the higher the CE will be.
In the case of the photopaper device, it will be in the 85-90% range when charging to high SOC values at 20mA/cm2. The big advantage is that microporous membranes are really cheap and they still work even if dendrites pierce them. I must me clear that photopaper is meant as a DIY demonstration, a commercial unit would never use that but a polyethylene microporous separator - such as Daramic - with these memrbanes the CE and EE tend to be higher.
The Coulomb efficiency of a device with a microporous, non-selective membrane depends fundamentally on how fast you charge/discharge it, as the device self-discharges while it runs. The faster you charge/discharge, the higher the CE will be.
In the case of the photopaper device, it will be in the 85-90% range when charging to high SOC values at 20mA/cm2. The big advantage is that microporous membranes are really cheap and they still work even if dendrites pierce them. I must me clear that photopaper is meant as a DIY demonstration, a commercial unit would never use that but a polyethylene microporous separator - such as Daramic - with these memrbanes the CE and EE tend to be higher.