You still have to apply for and buy an STC for your specific airframe's serial number and engine's serial number. Then you have to add some paperwork to the logbook and POH and add placards to the fuel fillers and cockpit.
In theory you should be able to automatically get it for anything which was approved from the factory to use 100LL, but the STC application form (here: https://stc.g100ul.com/aircraft/) does not allow you to select most mid-century large radials (which were usually originally certified on 130) or the airplanes they were installed on.
To be clear, this is a great thing, but you can't legally just fill G100UL in any random airplane.
I don't think it needs to work in every conceivable 100LL aircraft: just almost all. Every is a high bar.
Airports don’t always have the space for a second avgas tank (if this is the in between option), and if they did don’t necessarily want to spend money on setting up that infrastructure. So the current catch-all is to provide leaded which is cheaper and guaranteed to work in everything.
I think it’s great we are getting this forced through - it will make the approval process streamlined (like loda was) and removes a major reason people used to push airport shutdowns.
Lots of airports are owned or regulated by local governments which might want to move that single tank to just unleaded. E.g. Santa Clara County banned 100LL at local airports.
Forklift upgrades suck, too. You get some of the way along and then forklift. Arguably we're reaching that point.
The TC says you must run 100LL. The STC says you can freely mix G100UL in any ratio. The legal/certification problem is solved.