https://news.ycombinator.com/item?id=27782370 ("Passive radiative cooling below ambient airtemperature under direct sun")
Some work on surfaces of this kind have shown promising results, being able to fall below ambient temperature even in full sunlight.
However... that means they don't radiate well at night (they have low emissivity and are not well thermally coupled to the roof). Painting the roof white is ideal.
It tends to be newsworthy when it goes wrong, because the results can be things like buildings cooking nearby objects at certain times of day. Spicy stuff.
https://www.upi.com/Odd_News/2013/09/03/Skyscraper-melting-c...
"All will be simultaneously unveiled at 12 Midday tomorrow, citizens, so, ...take care out there!".
(shared link, readable even without a sub)
https://www.nytimes.com/2021/11/10/realestate/cool-roofs-cli...
It would be nice if the cells were highly reflective at a range of wavelengths between the range they can actually use and the range where they radiate waste heat.