Installing new GOG games from the GOG library isn't quite as easy as installing Steam games is, and you don't get the extra testing and verification for running games on Linux that you get on the Deck.
You do get all of the benefits from the Steam UI, though, like controller remapping and game specific performance profiles.
But, the Deck absolutely 100% works the way Valve intended: I find myself preferring to purchase games on Steam because it’s easy, even if it’s a couple bucks more or I have to wait for the Steam sale. It’s just a better experience.
My Steam account is possibly most oldest active account anyways and I have always preferred it, but if you primarily use another store it might be a bit annoying to have to do all the manual steps for the majority of your games
You just made me feel old. I think my Steam account is even older than my Gmail account. It has accompanied me through several phases of my life... I first created it using a very silly username, later I grew up and became extremely ashamed of it. I remember frequently checking if it was already possible to change the username, but they never allowed it. And now that I'm older I just laugh about it as a memory of my teen years.
(About half the games I play on Deck are from GoG.)