Near Earth asteroids are rich in experience.
Just as with scientific research, asteroid mining will be the domain of robots. There's no economic case for sending humans for that job, and AI is improving year on year. So sadly no Belters, whatever the value of mining space rocks.
Even a completely useless piece of rock is already a piece of rock in space. It can be used for shielding, counterweight for a spinning habitat, melted into simple shapes to support your habitats, etc.. You can even use it for propulsion - fling it away with a mass driver or vaporize with an arc-jet through a thruster nozzle!
I more easily believe in mining rocks on Moon as cool souvenirs. (And as a first step in developing the technology.)