Resulting in linked lists everywhere which have pretty terrible performance characteristics. You should be worried about those way before the occasional vector push reallocation cause you any problem. (And you can specify initial capacity so there is that)
Unchecked operations are acceptable if your code has a single hot loop, but if you have a hundred small functions, each taking 1% of the time, you probably won't carefully examine every stdlib function each of them uses and write code to "work around" every unnecessary thing the stdlib does.
Yes, that's a ton of micro-optimization, but micro-optimization can bring a ton of speedup, so I'll take whatever makes it simpler (or not needed in the case where you already know what will happen due to having written it)
But I seriously doubt that programs would benefit much from these micro-optimizations - there are rare and unfortunate cases where indeed there is no one single bottleneck for a program and thus there is no simple way to improve performance, but the vast majority of programs spend all their life in a tight hot loop, and anything else doesn’t matter in the slightest - hell, as mentioned C gets away with as many linked data structure as they want, but writing those in goddamn bash would suffice as well.
(I'd guesstimate that micro-optimizations would go a very long way in improving performance of nearly every program anywhere, but I don't have much data on that besides the couple projects where I've tried to care about performance, and having achieved pretty decent results)
C not having fancy built-in structures means programmers are more careful about choosing simple ones, which dramatically cuts down the amount of completely pointless generated code. -O3 can optimize registers and maybe memory reads/writes, but it can't remove reallocation from each call to a vector push, remove a reference count from a whole object type, or do pretty much anything with any moderately complex heap data structure. Sure, that comes at the cost of more advanced things being horrible to write, but it's a trade-off.
And I'll just disagree that UB must be unobvious. To me, it's one of the most useful optimization tools. You can check for it with sanitizers, and explicitly invoke it to convey information about hidden behavior to a compiler. It's not magic.