I don't know what exactly environment reaching 35C/95F web bulb means, but considering 1) it indicates temperature of a thermometer cooled by evaporation, and 2) body temperature of a human is ~40C/100F, I think it means evaporative cooling aka sweating is becoming useless. It won't be a huge stretch to consider that unsurvivable.
One issue that people who haven't experienced extreme heat might not realize is a lot of people just pass out really quickly. While it takes a while to go past the point of no return and they theoretically could be egressed to somewhere they can cool off and recover, if they're alone, they're not going to.
This assumes there are no alternatives to evaporative cooling via sweat.
My legitimate comments get downvoted and crap like this does not...
People can jump into fountains, or other bodies of water, hide at home, airconned buildings.
In the end, people can try to brave it, and wait for the relatively cool evening.