Another example of how the system works - if you are working two jobs, both as a regular employee, HRMC will instruct your employer as to what your tax deduction should be for that paycheck to make sure that things are balanced. For <some large number>% of people, this will be correct, and if it's not, it will rectify itself over 2 or 3 pay periods. If that's _still_ not enough, a phone call to HMRC (usually taking less than 10 minuts for the two times in a decade I've had to do it) will resolve the issue in your next check.
(I forget the exact percentage.)
You can either:
* Gift that remaining amount to HMRC by doing nothing (it will not go to the charity)
* Claim it back (I don't know any other way to do this other than filing a self assessment)
If the donor donates that amount as well and we loop infinitely, the final amount received by the charity would be exactly 1.5625x the originally-donated amount (assuming that the HMRC allows arbitrary small fractions of a penny to be claimed).
Explanation: if you donate an amount x, the final amount would be the infinite series x + sigma(0.25*0.2^(k-1) + 0.2^k, k=1, k=inf), which is the sum of two separate geometric series, so for each one, we can use the formula a/(1-r), where 'a' is the first term (0.25 for the first series, 0.2 for the second) and 'r' is the ratio between each term (0.2 in both cases).
Half goes to the charity, and half to the donor.
Guess, I could claim that £6 per week for Covid work from home stuff. Wish you could claim the cost of repairing your bike, or public transport costs.