As others have said, it's proprietary, and I don't want to see a private company becoming a gatekeeper to such an important function. Open standards are available. Google Maps provides Plus Codes, for example, and pretty much all Android users have that without having to install an additional app.
Now, this is only one anecdote, and maybe I just happened to get the one operator who had swallowed the what3words PR line- but at least some British emergency services are telling callers to use it.
(Not urgent enough to tie up a 999 operator, and it's faster to pull in somewhere and message, than ring and report via 101.)
They've been happy with location given by w3w.
I'm sure they would be. I'm not doubting that they'll be able to figure it out. Rather, I'm interested to know what they prefer.
If someone's coordinates don't come through automatically with the 911 call, the dispatcher or person running the search can walk them through finding their location if the person doesn't know how to do it.