You can assess approximate purity of the metal with very low-level technology (https://en.wikipedia.org/wiki/Touchstone_(assaying_tool)). Transactions thus have a lowered barrier of trust. Before gold and money, you could only transact in debt to labor (see debt: 5000 years) or socialized obligations, and to be sure the person would conduct that labor, you had to trust them, or trust society to honor the obligation.
More interestingly in particular, once gold came into being, two people could reliable transact over a very long social distances, (without necessarily knowing each other's reputation). You just had to trust an intermediary party to transport the gold. Nonetheless, that opened markets up considerably.
And especially items made with the use of gold can get really worthwhile - such as semiconductor chips...
So in a funny indirect way, Bitcoin is tied to gold. Both of which are tied to specific costs of labour. Bitcoin however requires a lot of expensive infrastructure to run to be worth anything. (Esp. networking, required to ensure no fake mined bitcoins are in circulation.)
Even printed cash is better at this.
It is fiat tied to used value not means to gain value.
On the other hand, you can manufacture useful things from metals, including precious metals. Heck, even old school non-precious metal coins have some of that value.