The problem with Qt not using std::string is when you (gasp!) want to integrate with non-Qt libraries that do use std::string. It has nothing to do with what std::string offers or does not offer compared to any other string implementation. std::string was the string implementation for C++ since before Qt began, and by not using it for their strings, they delivered a significant message about their desire to integrate easily with non-Qt libraries.
But I looked at using Qt in 1999 and easily decided against it, in part for this reason. Those of us coming from a *nix background got the UTF-8 thing much earlier than people affected by the Microsoft worldview.
Thankfully having a *nix background helped Sun getting Java design regarding UTF just right.
Meanwhile std::string still doesn't provide everything that compiler specific frameworks have been doing since mid-90's.