The docs you likely found on the wiki are dated, but MongoDB is definitely being used in Enterprise Engineering.
Source: I'm currently on the EE traffic team.
It's difficult to make accurate blanket assertions about large technical organizations, which Facebook certainly is.
I am amused by the downvotes that my previous comments received.
Thanks for the clarification.
As an example: would you consider the backend software stack that manages physical access to the campus 'mission critical'?
In much the same way I wouldn't say that my site is powered by Microsoft Excel; but you can be sure Microsoft Excel is used in my company.
Mission critical - essential for operating Facebook.com
Is is a company wide system? Its all fun and games until the cooling in a dc starts to have issues and the facilities team can't gain access because....mongo... ?
Disclosure: I worked at Facebook, but not in that department, or anywhere near any MongoDB.
Are you sure?