The decimal representation of a Real number has to be indexed by Natural numbers, i.e. every decimal digit[n] has a well-defined index n which is a Natural number. Infinity is not a Natural number, so 0.00...1 is not a Real number either.
I will say though that if your explanation of 0.999... = 1.0 requires that you explain the distinction between countable and uncountable infinities, that's a big ask for most lay people.
I'm no expert, but countability doesn't depend on how the set is ordered. It depends on whether the elements can be placed in 1:1 correspondence with the integers. 1,0,0,... has a countable number of elements, and so does 0,0,0,...,1. They can be put in 1:1 correspondence with each other. This definition of countability is described in your link.
I meant to ask, does "countable representation" some kind of detailed definition that I can look at?
The limit of lim n->inf 10^-n is exactly 0, it is not 0.00...1.
EDIT: The number above seems well defined. It's lim n->inf (10^-n). That's zero.