I was employee #1 in this new role and have since made a lot of really awesome things such as a company directory (mobile app), dashboards for our fabrication department, license management software for our IT folks, visitor check-in/out kiosks, interactive surgical simulators for our R&D/Sales teams, to name a few.
I hold a BS degree in Art. While in college, I took some web development courses and that is when I first started noticing my interest in programming. Despite having ~10 years of programming experience (~4 being as a professional software dev) I am not the most confident developer and the horror of software dev interviews scares me. Maybe it is time to go for it - worst they can say is no, right?
There's a huge salary penalty if you're not constantly looking for the best offers out there (do some Googling to convince yourself this is true). Don't worry about your imposter syndrome -- let others determine if you can get the job or not.
Elite software companies have ridiculous interviews, it's true, and you have to spend at least tens of hours practicing them. But everyone else is pretty reasonable, I've found. There are lots of enterprise shops that don't care about that nonsense.