https://www.executivetraveller.com/here-s-where-qantas-pilot...
Critical parts of the flight (such as take off and landing) will have the two most senior pilots in command, but less demanding parts in cruise, one of the second officers will be backing up one of the senior crew while the other 2 crew members have mandated rest.
Because these are 'hot bunks', you only need 2 available for the flight crew at any time. I assume the cabin crew have a similar rotation system.
This only happens when departure and arrival are both in the Northern Hemisphere, if that's the case, great circle routes appear as curved towards the North when plotted on a 2D map.
But here we are going from Northern to Southern hemisphere, so the great circle route will appear S-shaped, and the middle section will not be very far away from a straight line drawn on a 2D map.
This is the great circle route SFO-SYD, Honolulu is pretty close as you can see http://www.gcmap.com/mapui?P=sfo-syd
I just don't see how you could reasonably stop in Russia or China while flying from the US to Sydney.
But yeah, I don't think there exists a NA<->AU route with practical stops in China or Russia https://i.succ.in/6myR8ZFQ.png