I use 2 x 4TB disks in my homeserver, but I keep one online and have a script that brings up the other one periodically and rsyncs everything. This gives me a local backup, something RAID lacks, so I'm protected from fat fingering or accidentally deleting stuff. I also have very minimal downtime, because I can mount that drive in the place of the primary drive in just afew seconds.
I run xfs on the primary drive, and btrfs on the mirror, so I can take snapshots after I rsync and maintain differentials easily.
My point is, you should consider getting rid of RAID and just use the bare drive or LVS Volume.
tkaiser of the armbian project has a lot to say about this stuff. I find his posts in the cnx-software.com comments and armbian forums very helpful.
https://forum.armbian.com/topic/8097-nanopi-m4-performance-a...
When using this setup as a NAS, isn't your bottleneck the gigabit network from machine to machine? You'll saturate the 1 Gigabit link ( or even 2 Gigabit duplex ) before you can reach 5 Gigabits ( USB3 ) or 6 Gigabits ( PCIe )