It depends. It was common case for years in games to just cast your networked data to an array and send over the network. Nowadays it's much more in fashion to pick a serialization library to sit in between, as PCs are faster. But one might choose not to depending on the problem space. Embedded devices might not have the spare cycles or the space for a full serialization library.

So...you're not wrong, but it's basically the same reason people use C over something with more ergonomics.

Edit: the last time I wrote a networking library, I also just cast to raw structures, mainly because it was less work (didn't want to integrate a serialization library on both sides of the link). This was fine for a while (and very fast), but also hid some bugs in the protocol, and made sending arrays of data very ugly. Eventually we put protobuf on top, and things ended up much nicer.