Because she's being billed as a socialist boogieman by the media? She's extremely visible and vocal on the national stage that this whole HQ2 debacle has played out on. People in Seattle and DC don't know NYC's lower level politicians by name, and this is being billed as a national story because so many spurned cities and their populations have a viewing interest.
Had this been done differently, it would be a much smaller story covered by some segments of the tech media and local NYC publications with limited national coverage. In that reality, it likely would have been local community organizers and district pols being named in articles and scapegoated.
For the same reason the purple-haired woman screaming into Logic Man's face fuels millions of "SJW cringe" video views.
AOC for many people is a symbol of "snowflake socialist millennials who want the world to be handed to them". This is a narrative that persists even when it is Amazon that pays no federal tax and demands extra concessions despite already being highly profitable.
I also don't really understand why AOC is being scapegoated for this — this wasn't her district and she's not a state or city politician anyway.